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Schottky barrier inhomogeneities at the interface of few layer epitaxial graphene and silicon carbide

Shriram Shivaraman、Lihong H. Herman、Farhan Rana 等 5 位作者2012-04-30Applied Physics Letters

In this work, we study electron transport across the heterojunction interface of epitaxial few-layer graphene grown on silicon carbide and the underlying substrate. The observed Schottky barrier is characterized using current-voltage, capacitance-voltage and photocurrent spectroscopy techniques. It is found that the g…

Graphene research and applicationsAdvancements in Semiconductor Devices and Circuit DesignSemiconductor materials and interfaces

Gate-Controlled Spin Injection atLaAlO3/SrTiO3Interfaces

Nicolas Reyren、Manuel Bibès、Edouard Lesne 等 8 位作者2012-04-30Physical Review Letters

We report results of electrical spin injection at the high-mobility quasi-two-dimensional electron system (2-DES) that forms at the LaAlO3/SrTiO3 interface. In a nonlocal, three-terminal measurement geometry, we analyze the voltage variation associated with the precession of the injected spin accumulation driven by pe…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Cytotoxicity and cellular uptake of tri-block copolymer nanoparticles with different size and surface characteristics

Sourav Bhattacharjee、Dmitry Ershov、Kleanthis Fytianos 等 8 位作者2012-04-30Particle and Fibre Toxicology

BACKGROUND: Polymer nanoparticles (PNP) are becoming increasingly important in nanomedicine and food-based applications. Size and surface characteristics are often considered to be important factors in the cellular interactions of these PNP, although systematic investigations on the role of surface properties on cellu…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationRNA Interference and Gene Delivery

Protein Discrimination Using Fluorescent Gold Nanoparticles on Plasmonic Substrates

Hao Kong、Yuexiang Lu、He Wang 等 6 位作者2012-04-30Analytical Chemistry

Fluorescent gold nanoparticle (GNP) is an easily synthesized and biocompatible optical platform for sensing and imaging with tunable near-infrared (NIR) emission. However, the relatively low fluorescence (FL) quantum yield limits the further improvement of sensitivity and application. Here, we find that, on plasmonic…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Highly Concentrated and Conductive Reduced Graphene Oxide Nanosheets by Monovalent Cation–π Interaction: Toward Printed Electronics

Seung Yol Jeong、Sung Hun Kim、Joong Tark Han 等 6 位作者2012-04-30Advanced Functional Materials

Abstract A novel route to preparing highly concentrated and conductive reduced graphene oxide (RGO) in various solvents by monovalent cation– π interaction. Previously, the hydrophobic properties of high‐quality RGO containing few defects and oxygen moieties have precluded the formation of stable dispersion in various…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Chiral J‐Aggregates of Atropo‐Enantiomeric Perylene Bisimides and Their Self‐Sorting Behavior

Zengqi Xie、Vladimir Stepanenko、Krzysztof Radacki 等 4 位作者2012-04-30Chemistry - A European Journal

Herein we report on structural, morphological, and optical properties of homochiral and heterochiral J-aggregates that were created by nucleation-elongation assembly of atropo-enantiomerically pure and racemic perylene bisimides (PBIs), respectively. Our detailed studies with conformationally stable biphenoxy-bridged…

Lipid Membrane Structure and BehaviorPorphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in Materials

Multilength Scale Studies of the Confined Crystallization in Poly(l-lactide)-block-Poly(ethylene glycol) Copolymer

Jingjing Yang、Yongri Liang、Jun Luo 等 5 位作者2012-04-30Macromolecules

In this work, we investigated the structure and morphology formation in crystalline–crystalline diblock copolymer of poly( l -lactide)- block -poly(ethylene glycol) (PLLA- b -PEG) on different length scales with optical microscopy (OM), atomic force microscopy (AFM), synchrotron time-resolved small-angle X-ray scatter…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Long-Circulating 15 nm Micelles Based on Amphiphilic 3-Helix Peptide–PEG Conjugates

He Dong、Nikhil Dube、Jessica Y. Shu 等 7 位作者2012-04-30ACS Nano

Generating stable, multifunctional organic nanocarriers will have a significant impact on drug formulation. However, it remains a significant challenge to generate organic nanocarriers with a long circulation half-life, effective tumor penetration, and efficient clearance of metabolites. We have advanced this goal by…

Nanoparticle-Based Drug DeliverySupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers

Controlled release of nonionic compounds from poly(lactic acid)/cellulose nanocrystal nanocomposite fibers

Chunhui Xiang、Alan G. Taylor、Juan P. Hinestroza 等 4 位作者2012-04-30Journal of Applied Polymer Science

Abstract Poly(lactic acid)(PLA)/cellulose nanocrystal nanocomposite fibers were prepared by electrospinning at elevated temperature. Columbia Blue, a nonionic hydrophobic dye with a molecular weight and partition coefficient that mimics a systemic agrichemical, was incorporated into the fibers as a model compound. The…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Mechanically Durable and Highly Conductive Elastomeric Composites from Long Single-Walled Carbon Nanotubes Mimicking the Chain Structure of Polymers

Seisuke Ata、Kazufumi Kobashi、Motoo Yumura 等 4 位作者2012-04-30Nano Letters

By using long single-walled carbon nanotubes (SWNTs) as a filler possessing the highest aspect ratio and small diameter, we mimicked the chain structure of polymers in the matrix and realized a highly conductive elastomeric composite (30 S/cm) with an excellent mechanical durability (4500 strain cycles until failure),…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Design of a Voltage‐Controlled Magnetic Random Access Memory Based on Anisotropic Magnetoresistance in a Single Magnetic Layer

Jia‐Mian Hu、Zheng Li、Long‐Qing Chen 等 4 位作者2012-04-30Advanced Materials

A simple and fully gate-voltage-controlled magnetic random access memory is designed based on anisotropic magnetoresistance. This multiferroic memory device consists of just a single magnetic film grown on a ferroelectric layer with bistable in-plane anisotropic ferroelastic or piezo strains induced by out-of-plane vo…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

B12H n and B12F n : planar vs icosahedral structures

Nevill Gonzalez Szwacki、C. J. Tymczak2012-04-30Nanoscale Research Letters

Using density functional theory and quantum Monte Carlo calculations, we show that B12Hn and B12Fn (n = 0 to 4) quasi-planar structures are energetically more favorable than the corresponding icosahedral clusters. Moreover, we show that the fully planar B12F6 cluster is more stable than the three-dimensional counterpa…

Boron and Carbon Nanomaterials ResearchMXene and MAX Phase MaterialsBoron Compounds in Chemistry

Impacts of Atomistic Coating on Thermal Conductivity of Germanium Nanowires

Jie Chen、Gang Zhang、Baowen Li2012-04-30Nano Letters

By using nonequilibrium molecular dynamics simulations, we demonstrated that thermal conductivity of germanium nanowires can be reduced more than 25% at room temperature by atomistic coating. There is a critical coating thickness beyond which thermal conductivity of the coated nanowire is larger than that of the host…

Advanced Thermoelectric Materials and DevicesNanowire Synthesis and ApplicationsThermal properties of materials

Flexoelectricity induced increase of critical thickness in epitaxial ferroelectric thin films

Hao Zhou、Jiawang Hong、Yihui Zhang 等 6 位作者2012-04-30arXiv

Flexoelectricity describes the coupling between polarization and strain/stress gradients in insulating crystals. In this paper, using the Landau-Ginsburg-Devonshire phenomenological approach, we found that flexoelectricity could increase the theoretical critical thickness in epitaxial BaTiO3 thin films, below which th…

Materials Science

The application of Graphene as a sample support in Transmission Electron Microscopy

R. S. Pantelic、J. C. Meyer、U. Kaiser 等 4 位作者2012-04-30arXiv

Transmission electron microscopy has witnessed rampant development and surging point resolution over the past few years. The improved imaging performance of modern electron microscopes shifts the bottleneck for image contrast and resolution to sample preparation. Hence, it is increasingly being realized that the full…

Materials Sciencephysics.bio-ph

Ag and N acceptors in ZnO: Anab initiostudy of acceptor pairing, doping efficiency, and the role of hydrogen

O. Volniańska、P. Bogusławski、E. Kamińska2012-04-30Physical Review B

Efficiency of ZnO doping with Ag and N shallow acceptors, which substitute, respectively, cations and anions, was investigated. First principles calculations indicate a strong tendency towards formation of nearest-neighbor Ag-N pairs and N-Ag-N triangles. Binding of acceptors stems from the formation of quasimolecular…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Calcium doped graphane as a hydrogen storage material

Tanveer Hussain、Biswarup Pathak、Muhammad Ramzan 等 5 位作者2012-04-30Applied Physics Letters

On the basis of first principle density functional theory, we have studied the stability, electronic structure, and hydrogen storage capacity of a monolayer calcium doped graphane (CHCa). The stability of CHCa was further investigated using the ab initio molecular dynamics study. The binding energy of Ca on graphane s…

Advancements in Battery MaterialsGraphene research and applicationsHydrogen Storage and Materials

Band bending and surface defects in β-Ga2O3

T.C. Lovejoy、Renyu Chen、Xiantong Zheng 等 12 位作者2012-04-30Applied Physics Letters

Surface band bending and surface defects on the UV-transparent conducting oxide β-Ga2O3 (100) are studied with hard x-ray photoemission spectroscopy and scanning tunneling microscopy. Highly doped β-Ga2O3 shows flat bands near the surface, while the bands on nominally undoped (but still n-type), air-cleaved β-Ga2O3 ar…

Advanced Photocatalysis TechniquesZnO doping and propertiesGa2O3 and related materials

Detecting and Destroying Cancer Cells in More than One Way with Noble Metals and Different Confinement Properties on the Nanoscale

Erik C. Dreaden、Mostafa A. El‐Sayed2012-04-30Accounts of Chemical Research

Today, 1 in 2 males and 1 in 3 females in the United States will develop cancer at some point during their lifetimes, and 1 in 4 males and 1 in 5 females in the United States will die from the disease. New methods for detection and treatment have dramatically improved cancer care in the United States. However, as impr…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniques

Validity of the rigid band approximation in the study of the thermopower of narrow band gap semiconductors

Mal‐Soon Lee、S. D. Mahanti2012-04-30Physical Review B

Theoretical studies of thermoelectric properties using ab initio electronic structure calculations help not only to understand existing experimental data but also to predict new materials which can be potentially good thermoelectrics. However, in these studies it is inevitable to employ some approximations. It is ther…

Advanced Thermoelectric Materials and DevicesMachine Learning in Materials ScienceHeusler alloys: electronic and magnetic properties