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The crystal structures of Ag + Cu 2 (OH)(SO 4 ) 2 ∙ H 2 O and Me + Cu 2 (OH)(SeO 4 ) 2 ∙H 2 O [Me + = Ag, Tl, NH4], four new representatives of the natrochalcite type, with a note on natural natrochalcite

G. Giester1989-08-01Zeitschrift für Kristallographie - Crystalline Materials

Article The crystal structures of Ag+Cu2(OH)(SO4)2 ∙ H2O and Me+Cu2(OH)(SeO4)2∙H2O [Me+ = Ag, Tl, NH4], four new representatives of the natrochalcite type, with a note on natural natrochalcite was published on August 1, 1989 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 187, issue 1-4…

Crystal structures of chemical compoundsCrystal Structures and PropertiesLanthanide and Transition Metal Complexes

Brillouin scattering study of surface effect on the ferroelastic phase transition of KD3(SeO3)2

Akira Sakai、T. Yagi1989-08-01Ferroelectrics

A soft acoustic mode in a ferroelastic KD3(SeO3)2 crystal have been observed as a function of depth from the surface by the use of a microprobe Brillouin scattering system. Just above the phase transition temperature, the Brillouin frequency shift v, which is related to the hyper sound velocity, becomes hard as the ob…

Photorefractive and Nonlinear OpticsSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Thermodynamic Benefit of Abnormal Grain Growth in Pore Elimination During Sintering

Liang Xue1989-08-01Journal of the American Ceramic Society

Free‐energy analyses performed on closed particle‐pore arrays show that the presence of an abnormal grain thermodynamically favors the shrinkage of large pores to which is is adjacent. This gives an explanation to the experimentally observed phenomenon of abnormal‐grain‐growth‐promoted densification in barium titanate.

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisIntermetallics and Advanced Alloy Properties

Phase transition studies in 50CB and 80CB

P. Venkatacharyulu、A. V. N. Gupta、Jiguang Rao 等 5 位作者1989-08-01Crystal Research and Technology

Abstract Investigations on the temperature variation of specific volume and ultrasonic velocity are carried out to study the phase transitions in the liquid crystals 4′‐n‐Pentyloxy‐4‐Cyanobiphenyl (50CB) and 4′‐n‐Octyloxy‐4‐Cyanobiphenyl (80CB). From these studies various parameters like the adiabatic compressibility…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Reaction of Zirconium Fluoride Monohydrate and Ammonium Bifluoride: Its Effect on Fluoride Glass Preparation and Quality

Kenneth J. Ewing、Jasbinder S. Sanghera、Robert Miklos 等 7 位作者1989-08-01Journal of the American Ceramic Society

The products obtained from the roomtemperature reaction of ammonium bifluoride and zirconium fluoride monohydrate are ammonium heptafluorozirconate ((NH 4 ) 3 ZrF 2 ), liquid water, and hydrogen fluoride. Ammonium bifluoride and zirconium fluoride monohydrate were reacted prior to glass batching, producing dry ammoniu…

Glass properties and applications

Visual Observation of a Pressure-Driven Crystal Growth

Kaoru Takano、Satoshi Nishida、Masao Wakatsuki1989-08-01Japanese Journal of Applied Physics

Visual observation of crystal growth at high pressure was realized by the use of a diamond anvil cell. With a eutectic system of meta- and para-xylenes, phase equilibrium pressures were determined at various compositions and temperatures. Stepwise changes in pressure were applied to drive and observe even rapid growth…

Phase Equilibria and ThermodynamicsCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Induced Smectic Phases and Demixing in Mixtures of Alkanes and Other Nonmesogenic Compounds with Alkyloxy‐ and Alkyl‐cyanobiphenyls

Henning Heuer、H. Kneppe、F. Schneider1989-08-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract Demixing / Liquid Crystals / Phase Diagrams / Smectic Phases n‐Heptyloxy‐ and n‐heptylcyanobiphenyl show induced smectic phases in mixtures with n‐alkanes, n‐alcohols, and n‐alkylbenzenes. Alkyloxycyanobiphenyls with shorter alkyl chains (hexyl and pentyl homologues) show miscibility gaps with an upper consol…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Zur Komplexchemie der Alkalimetalle: Kristallstruktur von RbLiS / On the Complex Chemistry of the Alkali Metals: The Crystal Structure of RbLiS

Horst Sabrowsky、K. HIPPLER、Rolf-Dieter Hitzbleck 等 7 位作者1989-08-01Zeitschrift für Naturforschung B

The colourless compound RbLiS has been prepared as described earlier (H. Sabrowsky, A. Thimm, and P. Vogt-Mertens, Z. Naturforsch. 40b, 1759 (1985)) and its crystal structure determined by X-ray diffraction. Very hygroscopic RbLiS crystallizes in the tetragonal space group P4/nmm (Z = 2) with the cell parameters a = 4…

Crystal Structures and PropertiesInorganic and Organometallic ChemistrySolid-state spectroscopy and crystallography

Study of Reactive Ion Etching of the Si3 N 4 / GaAs Interface in CF 4 Plasmas by X‐Ray Photoelectron Spectroscopy and X‐Ray Photoelectron Diffraction

P. Alnot、J. Olivier、F. Wyczisk 等 4 位作者1989-08-01Journal of The Electrochemical Society

The etching mechanism of the interface in plasmas is studied by two complementary spectroscopies, x‐ray photoelectron spectroscopy (XPS) and x‐ray photoelectron diffraction (XPD). Following the removal of the layer, the etching reaction is shown to be rate‐limited by the formation of a highly fluorinated gallium layer…

Semiconductor materials and devicesPlasma Diagnostics and ApplicationsElectron and X-Ray Spectroscopy Techniques

A Method for Determination of Elastic Constants K1, K2, K3 of a Nematic Liquid Crystal Only Using a Homogeneously Aligned Cell

Kazuo Koyama、Masahiro Kawaida、Tadashi Akahane1989-08-01Japanese Journal of Applied Physics

It is shown that three Frank elastic constants K 1 , K 2 and K 3 of a nematic liquid crystal can be determined by measuring the capacitance change with a magnetic field of a homogeneously aligned cell. The splay elastic constant K 1 is determined from the threshold magnetic field strength H c1 when the magnetic field…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

New oil‐gelling agents for cosmetics: formation mechanism of oil gels

Jun‐ichi Fukasawa、Hisao Tsutsumi、Atsuo ISHIDA1989-08-01International Journal of Cosmetic Science

Summary New oil-gelling agents have been developed composed of a long-chain dialkyl phosphate (DP) surfactant and aluminium ion or multinuclear aluminum ion (MAI) which provide good oil-gel systems. One such gelling agent is the aluminum salt of DP (DP-Al) prepared as a precipitate by mixing DP with aluminum chloride…

Surface Modification and SuperhydrophobicitySurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Growth and Superconductivity of a New Ternary Intermetallic Compound, Ta5Ga2Sn

Toetsu Shishido、Jinhua Ye、N. Toyota 等 7 位作者1989-08-01Japanese Journal of Applied Physics

A new ternary intermetallic compound, Ta 5 Ga 2 Sn, has been synthesized by the self-flux method using molten tin as a solvent. The crystal structure is tetragonal (space group D 4h 18 /I4 mcm). The lattice parameters are a =10.342(2) Å, c =5.174(2) Å, V =555.3 Å 3 , Z =4, and the X-ray density D x is 13.91 Mgm -3 at…

Rare-earth and actinide compoundsMagnetic Properties of AlloysMetallurgical and Alloy Processes

Structure and Bonding of Two Modifications of CsSnI3 by Means of Powder X-Ray Diffraction, 127I NQR, and DTA

Koji Yamada、Tomoko Tsuritani、Tsutomu Okuda 等 4 位作者1989-08-01Chemistry Letters

Abstract A first-order phase transition accompanied by a color change from green to black was observed for CsSnI3 at about 425 K. These two modifications showed quite different 127I NQR spectra suggesting drastic structural change. High temperature modification has a perovskite structure with semi-metallic electric co…

Nuclear materials and radiation effectsInorganic Chemistry and MaterialsX-ray Diffraction in Crystallography

Polymers with a High Refractive Index and Low Optical Dispersion

Hans‐U. Simmrock、A. Mathy、Ligia J. Domínguez 等 5 位作者1989-08-01Angewandte Chemie International Edition in English

Communication: Organic Polyelectrolytes (I–VII) known as Ionenes, with unique combinations of high refractive index (ND) and high Abbe number (VD, see figure) now compete with inorganic glasses for application in optics. Variation of the counterions allows the tuning of their chemical and optical properties.

Semiconductor Lasers and Optical DevicesSynthesis and properties of polymers

Aging of Pyrotechnik Compositions. The investigation of chemical changes by IR spectroscopy and x‐ray diffraction

D. Barišin、Ines Batinic̈‐Haberle1989-08-01Propellants Explosives Pyrotechnics

Abstract The aging of tracers, containing different amounts of Mg, Sr(NO 3 ) 2 , KClO 4 , Al‐Mg alloy and organic binder, was conducted under the conditions of 50.0% and 98.5% relative humidities at 75 °C, and of 98.5% relative humidity at 25 °C. IR spectroscopy and X‐ray diffraction were used for investigation of che…

Energetic Materials and CombustionThermal and Kinetic AnalysisMagnesium Oxide Properties and Applications

Electric-controlled intrinsic optical bistability in nematic liquid crystals

Jiin-Chuan Wu、Shu-Hsia Chen1989-08-01Journal of Applied Physics

The properties of intrinsic optical bistability in nematic liquid crystals were studied. This kind of optical bistability is without resonant optical cavity and electric feedback. We find that the nematic ROTN-200 film can exhibit bistability when applying a constant ac electric field (≊560 kHz) that is greater than a…

Liquid Crystal Research AdvancementsLaser-Matter Interactions and ApplicationsNonlinear Dynamics and Pattern Formation

Development of new adhesion agents for asphalt cement

Carlo Giavarini、G. Rinaldi1989-08-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDevelopment of new adhesion agents for asphalt cementCarlo Giavarini and Gilberto RinaldiCite this: Ind. Eng. Chem. Res. 1989, 28, 8, 1231–1236Publication Date (Print):August 1, 1989Publication History Published online1 May 2002Published inissue 1 August 1989https://pubs.acs…

Asphalt Pavement Performance EvaluationPolymer composites and self-healingSynthesis and properties of polymers

Ceramic Materials Science in Society

W. D. Kingery1989-08-01Annual Review of Materials Science

Gallium is a metal that literally melts in your hand. It has low toxicity, near-zero vapor pressure, and a viscosity similar to water. Despite possessing a surface tension larger than any other liquid (near room temperature), gallium can form nonspherical ...Read More

Advanced ceramic materials synthesisSemiconductor materials and interfacesMXene and MAX Phase Materials

Catalysis by Interlayer Anions of a Synthetic Hydrotalcite-like Mineral in a Halide Exchange between Organic Halides

Eiichi Suzuki、Masaki Okamoto、Yoshio Ono1989-08-01Chemistry Letters

Abstract Exchgangeable Cl− anions in the interlayer sites of a hydrotalcite-like mineral, Mg6Al2(OH)16Cl2·4H2O, catalyzed a halide-exchange reaction between C6H5CH2Cl and C4H9Br or C4H9I in toluene or in DMF. Thus, for example, a reaction between C6H5CH2Cl (33 mmol) and C4H9Br (195 mmol) in DMF at 343 K for 20 h gave…

Flame retardant materials and propertiesLayered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and Materials

Tensile Strengths of Se, As 2 S 3 , As 2 Se 3 , and Ge 30 As 15 Se 55 Glass Fibers

David J. McEnroe、William C. LaCourse1989-08-01Journal of the American Ceramic Society

The strengths of as‐drawn, abraded, and pristine Se, As 2 Se 3 , As 2 S 3 , and Ge 30 As 15 Se 55 fibers are reported. Pristine strength values range from an average of 80 MPa for Se and Ge 30 As 15 Se 55 to 100 and 180 MPa for As 2 Se 3 and As 2 S 3 , respectively. Although these values are considerably higher than t…

Glass properties and applicationsPhase-change materials and chalcogenidesMineralogy and Gemology Studies