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Corrosion Performance of Aluminum-containing Zinc Coatings

Nai‐Yong Tang、Yihui Liu2010-01-01ISIJ International

Corrosion performance of zinc coatings containing aluminum in excess of 5% was assessed in modified salt-spray tests. X-ray diffraction studies indicated that the corrosion products consisted mainly of simonkolleite Zn5(OH)8Cl2·H2O, hydrozincite Zn5(OH)6(CO3)2, and zinc aluminum carbonate hydroxide hydrate Zn6Al2(OH)1…

Corrosion Behavior and Inhibition

Spin crossover in an elastic chain of exchange clusters beyond mean field approximation

Vitaly Morozov、Nikita N. Lukzen、В.И. Овчаренко2010-01-01Physical Chemistry Chemical Physics

Exact analysis of spin crossover in infinite elastic chain of two-spin exchange clusters was performed theoretically beyond mean-field approximation. Statistical mechanics of the system was exactly calculated by means of the transfer matrix technique. A possibility of spin-Peierls-like magneto-structural transition in…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Luminescence in CeIV polyoxometalate [Ce(W 5 O 18 ) 2 ] 8− : a combined experimental and theoretical study

Lindsay E. Roy、Denisse Ortiz‐Acosta、Enrique R. Batista 等 8 位作者2010-01-01Chemical Communications

Herein we describe the unique luminescent behavior observed in [Ce(IV)(W(5)O(18))(2)](8-) clusters and examine the photophysical properties using density functional theory.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Preparation of ZnO/In2O3(ZnO)n heterostructure nanobelts

Li Li Wu、Yao Liang、Fu-Wei Liu 等 7 位作者2010-01-01CrystEngComm

Bent In2O3(ZnO)n/ZnO (n = 4 and 5) heterostructure nanobelts were successfully synthesized by a simple thermal vapor method for the first time, using Au as a catalyst. The heterostructures were characterized by transmission electron microscopy and nanoprobe X-ray energy dispersive. The relationship between the strain…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsNanowire Synthesis and Applications

The Environmental Impacts of Fire-Fighting Foams

Ivana Tureková、Karol Balog2010-01-01Research Papers Faculty of Materials Science and Technology Slovak University of Technology

The Environmental Impacts of Fire-Fighting Foams Extinguishing foams are commonly used for extinguishing the fire of flammable liquids, whereby their insulating, choking and quenching effects are exploited. The purpose of the paper is to consider and compare the foams currently used in fire departments, regarding main…

Fire dynamics and safety researchFlame retardant materials and propertiesEnvironmental and Industrial Safety

Direct synthesis of an heterometallic {MnII3CrIII4} wheel by decomposition of Reineckes salt

V.V. Semenaka、Oksana V. Nesterova、Volodymyr N. Kokozay 等 9 位作者2010-01-01Dalton Transactions

A new heterometallic Mn/Cr molecular wheel complex has been synthesized using zerovalent manganese, Reineckes salt, ammonium thiocyanate and triethanolamine (H(3)tea) as starting materials. The compound [Mn(3)Cr(4)(NCS)(6)(Htea)(6)] (1) has been characterized in terms of its electrochemical, IR and EPR spectroscopic a…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Corrosion of Uranium Dioxide Containing Simulated Fission Products in Dilute Hydrogen Peroxide and Dissolved Hydrogen

M.E. Broczkowski、Peter Keech、Jamie Noel 等 4 位作者2010-01-01Journal of The Electrochemical Society

A combination of electrochemical methods and X-ray photoelectron spectroscopy has been used to study the combined influence of and dissolved on the oxidation of SIMFUEL ( electrodes fabricated to simulate spent nuclear fuel without the accompanying radiation fields) electrodes in 0.1 mol/L KCl (pH 9.5) at . The SIMFUE…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

Preparation and Characterization of Chitosan/Polyvinyl Alcohol Blends‐A Rheological Study

Esam A. El-hefian、Mohamed Mahmoud Nasef、Abdul Hamid Yahaya2010-01-01Journal of Chemistry

Blends of chitosan (CS) and polyvinyl alcohol (PVA) of different proportions (considering chitosan as the main component) were prepared. The rheological properties of the obtained blend solutions such as the shearing viscosity and the shear stress were investigated as a function of shear rate under various temperature…

Nanocomposite Films for Food PackagingMaterial Properties and ProcessingTransport Systems and Technology

Investigation of Triple Extrinsic Origins of Colossal Dielectric Constant in CaCu[sub 3]Ti[sub 4]O[sub 12] Ceramics

Wen‐Xiang Yuan、Suikong Hark、Wai‐Ning Mei2010-01-01Journal of The Electrochemical Society

Polycrystalline (CCTO) ceramics were prepared via a wet-chemistry method. Complex dielectric permittivity spectroscopy was performed on CCTO ceramics. We noticed that three distinct Maxwell–Wagner relaxations were clearly separated and could be associated with three mechanisms of extrinsic origins. These relaxations,…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Commercialization of Fuel Cell Bipolar Plate Manufacturing by Electromagnetic Forming

Glenn S. Daehn、Steve Hatkevich、Jianhui Shang 等 4 位作者2010-01-01Technische Universität Dortmund Eldorado (Technische Universität Dortmund)

The cost of manufacturing bipolar plates is a major component to the overall cost structure of a Proton Exchange Membrane (PEM) fuel cell stack. To achieve the commercialization of PEM fuel cells, a high volume and low cost manufacturing process for the bipolar plate must be developed. American Trim has identified hig…

Metal Forming Simulation TechniquesHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

The use of concrete in maritime engineering : - a guide to good practice

Sébastien Dupray2010-01-01Medical Entomology and Zoology

This guide aims to distil conclusions from existing research and practical experience, develop good practice guidance on marine concrete materials selection and design, and set out guidance on pre-casting of a variety of elements.

Material Selection and Properties

Side Reactions in the System Cellulose/1-Alkyl-3-methyl-imidazolium Ionic Liquid

Michael Schrems、Gerald Ebner、Falk Liebner 等 6 位作者2010-01-01ACS symposium series

In solutions of cellulose in 1-alkyl-3-methyl-imidazolium ILs, both the ionic liquid and the cellulose are evidently not inert. Side reactions can be distinguished according to whether they involve the cation or the anion of the ionic liquid or just autodegradation products of the IL. Ionic liquids with 1-alkyl-3-meth…

Ionic liquids properties and applicationsAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Investigation of liposome formulation effects on rivastigmine transport through human colonic adenocarcinoma cell line (CACO-2).

Zelihagül Değim、Mutlu Nb、Şükran Yılmaz 等 5 位作者2010-01-01PubMed

Transportations of rivastigmine containing liposomes across Caco-2 cells were studied and in vitro test results were compared with in vivo results. MTT test was used for cell viability studies. Series of formulations were prepared containing rivastigmine which is used for the treatment of Alzheimer's disease. Characte…

Nanoparticle-Based Drug DeliveryDrug Transport and Resistance MechanismsSupramolecular Chemistry and Complexes

Silver-N-Carboxymethyl Chitosan Nanocomposites: Synthesis and its Antibacterial Activities

Nguyễn Tiến An、Nguyen Thi Kim Dong、Pham Thi Bich Hanh 等 5 位作者2010-01-01Journal of Bioterrorism & Biodefense

In this work, silver-N-carboxymethyl chitosan nanocomposites (Ag-N-CMC) were synthesized in the homogeneous state via the reduction of Ag+ (using [Ag(NH3)2]OH instead of AgNO3) by NaBH4 in the presence of water-soluble N-carboxymethyl chitosan as a stabilizer. The resulting Ag-N-CMG was characterized by FTIR, TEM and…

Nanoparticles: synthesis and applicationsNanocomposite Films for Food Packaging

Investigation on Tensile and Flexural properties of Cotton Fiber Reinforced Isophthallic Polyester Composites

S. Sabinesh2010-01-01International Journal of Current Engineering and Technology

Natural fiber reinforced composite materials are one such capable material which replaces the conventional and synthetic materials for the practical applications where there require less weight and energy conservation. Increasing concern about global warming and depleting petroleum reserves have made scientists to foc…

Natural Fiber Reinforced CompositesInnovations in Concrete and Construction MaterialsMaterial Properties and Applications

Identification and characterization of gadolinium(iii) complexes in biological tissue extracts

Chethaka Kahakachchi、Dennis A. Moore2010-01-01Metallomics

The gadolinium species present in a rat kidney following intravenous administration of a gadolinium-based magnetic resonance contrast agent (Optimark™, Gadoversetamide injection) to a rat was examined in the present study. The major gadolinium species in the supernatant of the rat kidney tissue extracts was determined…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Multiaxial yield behaviour of polypropylene

Michael Jerabek、Daniel Tscharnuter、Zoltán Major 等 5 位作者2010-01-01EPJ Web of Conferences

In order to characterize the yield behavior of polypropylene as a function of pressure and to verify the applicability of the Drucker-Prager yield function, various tests were conducted to cover a wide range of stress states from uniaxial tension and compression to multiaxial tension and confined compression. Tests we…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Mixed-valent vanadium substituted polyoxometalates: the wheel shaped [Rb3⊂{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15−

Awatef S. Assran、Natalya V. Izarova、Ulrich Kortz2010-01-01CrystEngComm

The wheel shaped polyoxoanion [Rb3⊂{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15− comprising a macrocyclic tungstophosphate template wheel [P6W39O147(H2O)3]30− ({P6W39}) capped by two unprecedented mixed-valent oxovanadium {(VVO)(VIVO)3(µ2-O)3(H2O)6}3+ groups has been prepared and characterized by X-ray diffraction, element…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry