Materials Literature
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Structural and optical properties of ZnO nanoparticles can be fine tuned by a novel variant of milling performed at cryogenic temperatures. In this study intrinsic defect centers such as oxygen and zinc vacancies are characterized using electron paramagnetic resonance (EPR) and photoluminescence (PL) spectroscopy. Thr…
Predicting structure from the attributes of a material's building blocks remains a challenge and central goal for materials science. Isolating the role of building block shape for self-assembly provides insight into the ordering of molecules and the crystallization of colloids, nanoparticles, proteins, and viruses. We…
Abstract To take advantage of the property of supercritical carbon dioxide as both a solvent and swelling agent, the bulk grafting of poly(styrene‐ alt ‐maleic anhydride) [P(MAH‐ alt ‐St)] onto preirradiated polyolefin membranes was performed by a combination of γ‐ray‐preirradiation‐induced graft copolymerization and…
The superior strength and stiffness of carbon nanotubes (CNTs) make them attractive for many structural applications. Although the strength and stiffness of CNTs are extremely high, fibres of aligned CNTs have been found to date to be far weaker than the constituent CNTs. The intermolecular interactions between the CN…
본 연구에서는 다중벽 탄소나노튜브(MWCNT)의 함량을 1에서 10 wt%까지 달리하여 MWCNT 강화 폴리프로필렌(PP) 나노복합재료의 전자파 차폐효과 및 기계적 특성에 미치는 영향에 대해서 살펴보았다. 전기전도도는 4단자법으로 측정하였고, 전자파 차폐효과는 흡수와 반사방법으로 분석하였다. 기계적 특성은 임계응력세기인자(<TEX>$K_{IC}$</TEX>) 측정을 통하여 고찰하였으며, 모폴로지는 주사전자현미경(SEM)으로 관찰하였다. 실험결과, MWCNT의 함량이 증가함에 따라 차폐효과가 향상됨을 확인할 수 있었으며, MWCNT의 함량이 전자파 차폐효과를 결정하는…
Multi-scale characterisation using TEM, EELS and 3D FIB reconstruction was carried out on both pre-transition and post-transition oxides grown in high-temperature water. 3-D characterisation of cracks using high resolution FIB sequential sectioning gave a quantitative measure of crack density over time. There is no su…
Abstract Poly(propylene) (PP)/chlorinated PP (CPP)/multiwalled carbon nanotube (MWNT) composites are prepared via melting blend with a MWNT masterbatch obtained by a solution process under ultrasonic irradiation. The effects of ultrasonic irradiation on the microstructure and the electric properties of the PP/CPP/MWNT…
Abstract The synthesis of cylindrical silicon‐core and ferroelectric oxide perovskite‐shell nanowires and their response characteristics as individual three‐terminal nanoscale electronic devices is reported. The co‐axial nanowire geometry facilitates large ferroelectric field‐effect modulation (>10 4 ) of nanowire…
Density distribution, fluid structure and solvation forces for fluids confined in Janus slit-shaped pores are investigated using grand canonical Monte Carlo simulations. By varying the degree of asymmetry between the two smooth surfaces that make up the slit pores, a wide variety of adsorption situations are observed.…
We used initiation solutions of DBU and different thiols for the controlled ring-opening homo- and copolymerization of ethoxy ethyl thio glycidyl ether (EETGE) and allyl thio glycidyl ether (ATGE) to side-chain multifunctional polysulfides. Optimized preparation conditions allow the syntheses of monomodal homopolysulf…
Sodium zirconium phosphate ( NZP ) is a potential material for immobilization of nuclear effluents. It was observed up to ~7.16 wt% (~2.67 mol%) of strontium and ~14.46 wt% (~3.56 mol%) of cesium could be simultaneously loaded into NZP formulations without significant changes in the three‐dimensional framework structu…
Pd capped pure Mg thin film (50 nm thick) was prepared by magnetron sputtering and its hydrogenation at room temperature has been investigated. After exposure to 4% hydrogen gas diluted by argon, the Pd/Mg thin films show drastic optical changes from the metallic state to the transparent state within five seconds by h…
Alkali silicates are basic constituents of molten rock and technologically used glass materials. The addition of alkali oxides to pure silica (SiO2) causes a decrease in the melt viscosity by order...
Abstract The surface properties of a series of imidazoline‐based dissymmetric bis‐quaternary ammonium (DBA) salts with different hydrophobic chain lengths DBA‐12, DBA‐14 and DBA‐16 were determined. The adsorption behaviors of these compounds in 1 M HCl solution and their inhibitive effect on Q235 steel (U12350) were i…
Exciton localization is studied for polar ZnO/Mg${}_{0.27}$Zn${}_{0.73}$O quantum wells (QWs) grown by pulsed laser deposition. The samples exhibit both quantum confinement as well as the quantum-confined Stark effect. Emission energies between $3.46$ and $3.18\phantom{\rule{0.16em}{0ex}}\phantom{\rule{0.16em}{0ex}}\t…
A combined theoretical–semiempirical penetration model of ballistic penetration of thick section composites has been developed. The penetration model is developed by breaking down the penetration event into two major phases, that is, (i) the short-time phase I shock compression and (ii) the long-time phase II dynamic…
Type I collagen has been extensively exploited as a biomaterial for biomedical applications and drug delivery; however, small molecular alterations occurring during the isolation procedure and its interaction with residual bone extracellular matrix molecules or proteins might affect the overall material biocompatibili…
Abstract Many variations in the electrospinning process have emerged to control pore size needed in tissue scaffolds including introducing voids in the collector plate. However, the effect of different shapes and sizes of voids on fiber and pore sizes is not well understood. In this study, we evaluated the effect of v…
Large area GO-Cd composite Langmuir-Blodgett monolayers were transferred onto Si substrate by introducing Cd(2+) ions into the subphase. The changes in the behaviour of the Langmuir monolayer isotherm in the presence of Cd(2+) ions are attributed to changes in the microstructure and density of the GO sheets on the sub…
The degradation mechanism of polypropylene (PP)–clay nanocomposites is investigated in the present study. The PP–clay nanocomposites are prepared through a solution process with 4 and 8 wt % incorporation of nanoclay in a polymer matrix. Nanoclay with two types of organic modifications (25–30 wt % methyl dihydroxyethy…