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Surface‐Enhanced Raman Detection on Metalized Nanostructured Poly(p‐xylylene) Films

Ping Kao、Niranjan Malvadkar、Murat Çetinkaya 等 6 位作者2008-07-23Advanced Materials

The development of a SERS substrate with high uniformity and sample-to-sample reproducibility is reported. Nanostructured poly(p-xylylene) films are prepared using an oblique-angle polymerization method, and SERS-active metals are deposited onto the nanostructured polymer by using thermal evaporation (see figure). The…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchBiosensors and Analytical Detection

σ- and π-Defects at Graphene Nanoribbon Edges: Building Spin Filters

T. Martins、Antônio J. R. da Silva、R. H. Miwa 等 4 位作者2008-07-23Nano Letters

The presence of certain kinds of defects at the edges of monohydrogenated zigzag graphene nanoribbons changes dramatically the charge transport properties inducing a spin-polarized conductance. Using an approach based on density functional theory and nonequilibrium Green's function formalism to calculate the transmitt…

Graphene research and applicationsQuantum and electron transport phenomenaAdvanced Memory and Neural Computing

Polytetrahydrofuran/Clay Nanocomposites by In Situ Polymerization and “Click” Chemistry Processes

Mehmet Atilla Taşdelen、Wim Van Camp、Eric J. Goethals 等 6 位作者2008-07-23Macromolecules

Polytetrahydrofuran (PTHF)/clay nanocomposites were prepared by two routes: in situ cationic ring opening polymerization (CROP) and a method involving “click” chemistry. In the first method, PTHF chains were grown from the surface of the organo-modified montmorillonite clay by CROP of tetrahydrofuran (THF) through the…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Energy Transfer and Tunable Luminescence Properties of Eu3+ in TbBO3 Microspheres via a Facile Hydrothermal Process

Jun Yang、Cuimiao Zhang、Chunxia Li 等 5 位作者2008-07-23Inorganic Chemistry

Tb (1- x) BO 3: xEu (3+) ( x = 0-1) microsphere phosphors have been successfully prepared by a simple hydrothermal process directly without further sintering treatment. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmi…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsRadiation Detection and Scintillator Technologies

Glycine Polymorphism in Nanoscale Crystallization Chambers

Benjamin D. Hamilton、Marc A. Hillmyer、Michael D. Ward2008-07-23Crystal Growth & Design

Crystallization of glycine by evaporation of aqueous solutions in nanometer-scale channels of controlled-pore glass (CPG) powders and porous polystyrene-poly(dimethyl acrylamide) (p-PS-PDMA) monoliths, the latter prepared by etching polylactide (PLA) from aligned PS-PDMA-PLA triblock copolymers, preferentially results…

Analytical Chemistry and ChromatographyEnzyme Structure and FunctionCrystallization and Solubility Studies

A key role for unusual spin dynamics in ferropnictides

I. I. Mazin、M. D. Johannes2008-07-23arXiv

The 2008 discovery of superconducting ferropnictides with Tc~26K-56K introduced a new family of materials into the category of high Tc superconductors. The ongoing project of understanding the superconducting mechanism and pairing symmetry has already revealed a complicated and often contradictory underlying picture o…

Materials ScienceSuperconductivity

Time-resolved and continuous-wave optical spin pumping of semiconductor quantum wells

G. V. Astakhov、M. M. Glazov、D. R. Yakovlev 等 7 位作者2008-07-23arXiv

Experimental and theoretical studies of all-optical spin pump and probe of resident electrons in CdTe/(Cd,Mg)Te semiconductor quantum wells are reported. A two-color Hanle-MOKE technique (based on continuous-wave excitation) and time-resolved Kerr rotation in the regime of resonant spin amplification (based on pulsed…

Mesoscale and Nanoscale PhysicsMaterials Sciencecond-mat.other

Energy transfer in Er-dopedSiO2sensitized with Si nanocrystals

Ignacio Izeddin、Dolf Timmerman、T. Gregorkiewicz 等 7 位作者2008-07-23Physical Review B

We present a high-resolution photoluminescence study of Er-doped ${\text{SiO}}_{2}$ sensitized with Si nanocrystals (Si NCs). Emission bands originating from recombination of excitons confined in Si NCs, internal transitions within the $4f$-electron core of ${\text{Er}}^{3+}$ ions, and a band centered at $\ensuremath{…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsCarbon and Quantum Dots Applications

Transmission-line analysis ofε-near-zero–filled narrow channels

Andrea Alù、Mário G. Silveirinha、Nader Engheta2008-07-23Physical Review E

Following our recent interest in metamaterial-based devices supporting resonant tunneling, energy squeezing, and supercoupling through narrow waveguide channels and bends, here we analyze the fundamental physical mechanisms behind this phenomenon using a transmission-line model. These theoretical findings extend our t…

Metamaterials and Metasurfaces ApplicationsMicrowave Engineering and WaveguidesAdvanced Antenna and Metasurface Technologies

Photonic-Plasmonic Scattering Resonances in Deterministic Aperiodic Structures

Ashwin Gopinath、Svetlana V. Boriskina、Ning-Ning Feng 等 5 位作者2008-07-23Nano Letters

In this paper, we combine experimental dark-field scattering spectroscopy and accurate electrodynamics calculations to investigate the scattering properties of two-dimensional plasmonic lattices based on the concept of aperiodic order. In particular, by discussing visible light scattering from periodic, Fibonacci, Thu…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Polymeric Microcapsules for Synthetic Applications

Dennis Lensen、Dennis M. Vriezema、Jan C. M. van Hest2008-07-23Macromolecular Bioscience

For decades scientists have been working on closed systems for transportation, catalysis and protection, which are inspired by natural cells. Only recently polymer based systems have emerged for these systems, since they are more robust, give protection from the environment and give a more stable membrane. Various met…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

High-Field 17 O MAS NMR Investigation of Phosphonic Acid Monolayers on Titania

Florence Brodard-Séverac、Gilles Guerrero、Jocelyne Maquet 等 6 位作者2008-07-23Chemistry of Materials

High-field 17 O MAS NMR was used to investigate the binding of self-assembled monolayers of 17 O-enriched phosphonic acids deposited on a titania anatase support. The spectra were recorded at two different magnetic fields (9.4 and 17.6 T), to improve the reliability of the simulations of the different resonances. The…

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Structural transition and anisotropic properties of single-crystallineSrFe2As2

Jiaqiang Yan、A. Kreyßig、S. Nandi 等 11 位作者2008-07-23Physical Review B

Platelike single crystals of ${\text{SrFe}}_{2}{\text{As}}_{2}$ as large as $3\ifmmode\times\else\texttimes\fi{}3\ifmmode\times\else\texttimes\fi{}0.5\text{ }{\text{mm}}^{3}$ have been grown out of Sn flux. The ${\text{SrFe}}_{2}{\text{As}}_{2}$ single crystals show a structural phase transition from a high-temperatur…

Iron-based superconductors researchIntellectual Capital and Performance Analysis

Exploiting Ionic Coupling in Electronic Devices: Electrolyte‐Gated Organic Field‐Effect Transistors

Matthew J. Panzer、C. Daniel Frisbie2008-07-23Advanced Materials

Abstract Currently there is great interest in using organic semiconductors to develop novel flexible electronic applications. An emerging strategy in organic semiconductor materials research involves development of composite or layered materials in which electronic and ionic conductivity is combined to create enhanced…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Local ordering of polymer-tethered nanospheres and nanorods and the stabilization of the double gyroid phase

Christopher R. Iacovella、Mark A. Horsch、Sharon C. Glotzer2008-07-23The Journal of Chemical Physics

We present results of Brownian dynamics simulations of tethered nanospheres and tethered nanorods. Immiscibility between tether and nanoparticle facilitates microphase separation into the bicontinuous, double gyroid structure (first reported by Iacovella et al. [Phys. Rev. E 75, 040801(R) (2007)] and Horsch et al. [J.…

Surfactants and Colloidal SystemsBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Statistical mechanics of damage phenomena

S. G. Abaimov2008-07-23arXiv

This paper applies the formalism of classical, Gibbs-Boltzmann statistical mechanics to the phenomenon of non-thermal damage. As an example, a non-thermal fiber-bundle model with the global uniform (meanfield) load sharing is considered. Stochastic topological behavior in the system is described in terms of an effecti…

Materials Sciencecond-mat.stat-mech

Magnetic-field-induced transitions in multiferroicTbMnO3probed by resonant and nonresonant x-ray diffraction

J. Strempfer、B. Bohnenbuck、Ioannis Zegkinoglou 等 7 位作者2008-07-23Physical Review B

Multiferroic ${\text{TbMnO}}_{3}$ is investigated using x-ray diffraction in high magnetic fields. Measurements on first- and second-harmonic structural reflections due to modulations induced by the Mn and Tb magnetic order are presented as function of temperature and field oriented along the $a$ and $b$ directions of…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

On the effect of temperature on the reentrant condensation in polyelectrolyte-liposome complexation

S. Sennato、D. Truzzolillo、F. Bordi 等 4 位作者2008-07-23arXiv

In systems of highly charged linear polyelectrolytes and oppositely charged colloidal particles, long-lived clusters of polyelectrolyte-decorated particles form in an interval of concentrations around the isoelectric point, where reentrant condensation connected to charge inversion of cluster is observed. The mechanis…

Materials ScienceSoft Condensed Matter

Lattice Green function for extended defect calculations: Computation and error estimation with long-range forces

Dallas R. Trinkle2008-07-23Physical Review B

Computing the atomic geometry of lattice defects---e.g., point defects, dislocations, crack tips, surfaces, or boundaries---requires an accurate coupling of the local deformations to the long-range elastic field. Periodic or fixed boundary conditions used by classical potentials or density-functional theory may not ac…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsSurface and Thin Film Phenomena

Long-Term Stabilization of Foams and Emulsions with In-Situ Formed Microparticles from Hydrophobic Cellulose

H. A. Wege、Sejong Kim、Vesselin N. Paunov 等 5 位作者2008-07-23Langmuir

We report a simple method to produce foams and emulsions of extraordinary stability by using hydrophobic cellulose microparticles, which are formed in situ by a liquid-liquid dispersion technique. The hydrophobic cellulose derivative, hypromellose phthalate (HP), was initially dissolved in water-miscible solvents such…

Proteins in Food SystemsAdvanced Cellulose Research StudiesPickering emulsions and particle stabilization