Materials Literature
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A series of cyclic metalloporphyrin trimers containing one Ru(II)-CO porphyrin center are synthesized. A stepwise convergent route is used to synthesize Ru(CO)Zn(2)2.Py3T, where tripyridyltriazine (Py3T) templates the formation of the trimer and forces the CO group to the outside of the cavity. Three mixed-metal trime…
Pseudomonas sp. 61-3 produces a blend of poly(3-hydroxybutyrate) [P(3HB)] homopolymer and poly(3-hydroxybutyrate-co-3-hydroxyalkanoates) [P(3HB-co-3HA)] random copolymer consisting of monomeric units of 4-12 carbon atoms from sugars. The phaG(Ps) gene encoding (R)-3-hydroxyacyl-acyl carrier protein coenzyme A transfer…
A "spin diverse" S = 3/2 ground-state complex, NN-SQCuTpCum,Me, has been prepared. The three S = 1/2 spin carriers are nitronyl nitroxide (NN), o-semiquinone (o-SQ), and cupric ion. The solid-state structure of the ZnII derivative, NN-SQZnTpCum,Me (C56H69BN8O4Zn), was determined: monoclinic, P2(1)/c, a = 12.5781(12) A…
Higher plants represent a rich source of new molecules with pharmacological properties, which are lead compounds for the development of new drugs. During the last decades, the renewed interest in investigating natural products has led to the advent of several important drugs, such as the anticancer substances vinblast…
Treatment of cis-[W(N2)2(PMe2Ph)4] (5) with an equilibrium mixture of trans-[RuCl(eta 2-H2)(dppp)2]X (3) with pKa = 4.4 and [RuCl(dppp)2]X (4) [X = PF6, BF4, or OTf; dppp = 1,3-bis(diphenylphosphino)propane] containing 10 equiv of the Ru atom based on tungsten in benzene-dichloroethane at 55 degrees C for 24 h under 1…
A shape memory alloy (SMA) spring actuator for an active catheter was fabricated by the heat treatment of wound SMA wire on a mandrel. In order to evaluate the characteristics of the fabricated SMA spring actuator, four types of tests were performed, as follows: isothermal loading and unloading, measurement of shape r…
The structural and thermal behavior of all members of the homologous series of neodymium(III) alkanoates, ranging from neodymium(III) butyrate to neodymium(III) eicosanoate are described. Neodymium(III) butyrate monohydrate, Nd(C3H7COO)3.H2O crystallizes in space group P1 (No. 2), Z = 2. The lattice parameters are a =…
The capability of periodic structures to act as filters for traveling waves is used to control the longitudinal wave propagation in rods. Shape memory inserts placed periodically along the rods act as sources of impedance mismatch with tunable characteristics. Such characteristics are attributed to the unique behavior…
The numerical simulation analyses were performed on the buckling and postbuckling behavior of laminated composite shells with embedded shape memory alloy (SMA) wires. These analyses using ABAQUS code were conducted to investigate the effect of embedded SMA wires on the characteristics of buckling and postbuckling caus…
Ag/Fe/Ag and Cr/Fe/Cr trilayers with a single $25 nm$ thick ferromagnetic layer exhibit giant magnetoresistance (GMR) type behavior. The resistance decreases for parallel and transversal magnetic field alignements with a Langevin-type magnetic field dependence up to B=12 T. The phenomenon is explained by a granular in…
A microscopic theory for the coupling of intrinsic Josephson oscillations due to charge fluctuations on the quasi two-dimensional superconducting layers is presented. Thereby in close analogy to the normal state the effect of the scalar potential on the transport current is taken into account consistently. The dispers…
The time dependent cluster approximation called the path probability method (PPM) is applied to a pseudo-spin Ising Hamiltonian of the Slater-Takagi model for KH2PO4-type hydrogen-bonded ferroelectrics in order to calculate the homogeneous dynamical susceptibility above and below the ferroelectric transition temperatu…
Abnormal grain growth in the presence of second phase particles is investigated with the help of a two-dimensional Monte Carlo simulation. An aggregate of equiaxed grains is considered with constant grain boundary energy and mobility. The only driving force accounted for stems from the grain boundary curvature. The pr…
Experimental osmotic second virial coefficients are reported for polystyrene in toluene (good solvent), cyclohexane (ϑ solvent) and methylcyclohexane (poor solvent) in the temperature range 10−60 ° C. The ϑ temperature for eight-arm star polystyrene in methylcyclohexane is 29 ± 3 ° C. Intrinsic viscosity for polystyre…
The design of the multilayer coatings and multilayer grating for the EIS spectrometer is presented. The grating substrate has a rectangular laminar groove profile with 4200 grooves/mm and a 58 angstrom groove depth. The grating and mirror have two multilayer coatings, each covering half of the areas of the grating and…
The visible luminescence of Pr 3+ -doped lead-germanate glass of composition (in mol%) 60GeO 2 -25PbO-15Nb 2 O 5 has been investigated for different Pr 3+ concentrations and temperatures by using steady-state and time-resolved laser spectroscopy. The fluorescence from the 1 D 2 level shows a strong concentration quenc…
Pulse radiolytically generated (SCN) 2 •- radicals bind strongly to the gold nanoparticle surface, with an apparent equilibrium constant of 4.7 × 10 3 M -1 . The resultant complex has a strong absorption band at 390 nm which quickly undergoes chemical changes to yield an oxidation product, [Au(SCN) 2 ] -, with an abso…
High-pressure, low-angle X-ray diffraction is used to examine the compressibility of periodic hexagonal, surfactant-templated silicas. Mesoscopic order in these materials can be retained up to 12 GPa, and pressure-induced distortions are reversible. Postsynthetic treatments can greatly enhance the mechanical propertie…
The magnetic properties of Sr 2 FeMoO 6 oxides are investigated over a broad temperature range extending from 10 K to 800 K. It is found that the magnetization fully saturates at low temperatures at a value of 3.75 µ B . In the paramagnetic regime, above the Curie temperature ( T C ≈420 K), the magnetic susceptibility…
Repeated bilayers of a polycation and a polyanion were assembled by adsorption from their aqueous solutions. The polycations used were PEI (poly(ethylenimine)), PAH (poly(allylamine hydrochloride)), and generation 3.0 dendrimer (poly(propylenimine)). The polyanion was PAZO (poly[1-[4-(3-carboxy-4-hydroxyphenylazo)benz…