Materials Literature
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Polyindene was prepared by the controlled cationic polymerization of indene initiated with cumyl methyl ether/TiCl 4 in CH 2 Cl 2 at −65 °C. The number-average molecular weight was controlled by the ratio of monomer to cumyl methyl ether; polydispersity indicies ranged from 1.8 to 3. Polyindene samples prepared by thi…
Silica-supported molybdenum surface complexes were prepared by the reaction between (N)Mo(OtBu)3 and silica via displacement of the tert-butoxy ligands for siloxyls from the silica surface. The structure of the surface molybdenum complexes was well defined by in-situ FT-IR, elemental analysis, 1H NMR and 13C CP/MAS NM…
Different spectroscopic and photoelectrochemical behaviors were observed when racemic and enantiomeric [Ru(bpy) 3 ] 2+ complexes were intercalated in the interlayer of K 4 Nb 6 O 17, even for the same intercalation amount. The results are interpreted in terms of the stronger interaction between racemic [Ru(bpy) 3 ] 2+…
Abstract An efficient strategy for the backbone functionalization of a tripodal phosphane ligand which allows its attachment to solid supports and polymers has been developed. Using pentaerythrol ( 1 ) as the starting material, the functionalized phosphane tripod HOCH 2 CH 2 OCH 2 C(CH 2 PPh 2 ) 3 ( 9 ) was obtained i…
Ein einzähniger Ligand dient als Solvens: Durch Solvothermalsynthesen in n-Butylamin wurden Chalkogenid-Nanostäbe mit Halbleitereigenschaften aus leicht zugänglichen anorganischen Reaktanten erhalten. Das Amin eignete sich ausgezeichnet zur Formsteuerung von CdS-, CdSe-, ZnSe- und PbSe-Nanostäben (siehe Bild) unter re…
It was shown that, when filled with gallium, carbon nanotubes can absorb copper vapor with extraordinarily high efficiency. The copper vapor generated from the supporting copper grid upon heating to 800 °C in an electron microscope under a pressure of 1.0×10−5 Pa quickly deposited into the carbon nanotubes and formed…
Binary mixtures of lamellar colloids represented by hard platelets are studied within a generalization of the Zwanzig model for rods, whereby the square cuboids can take only three orientations along the x, y or z axes. The free energy is calculated within Rosenfeld’s “fundamental measure theory” adapted to the presen…
A study of the thermally induced and photoinduced changes in the mechanical properties of thin azobenzene polymer layers utilizing electromechanical spectroscopy is presented. Upon illumination at room temperature, weak photoinduced plasticization is observed. This is well below the degree of softening induced by heat…
Abstract Eight solvates of magnesium bis(tetrahydroborate) have been prepared and characterised by NMR and IR spectroscopy, and five of them also by X‐ray crystallography. Compounds Mg(BH 4 ) 2 ·3NH 2 t Bu and Mg(BH 4 ) 2 ·3pip each have a distorted trigonal‐bipyramidal structure (with the BH 4 group viewed as a simpl…
Abstract Plasma glow‐discharge application is known as a technique to coat or modify the surfaces of various materials. In this study, the influence of oxygen rf‐plasma treatment on surface and bulk properties of a biological polyester, poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate), were studied by determining water co…
Lead zirconate titanate (PZT) thin films were deposited on stainless steel (SS) substrates by a sol-gel spin-on technique, and crystallized by a low-temperature annealing process. A lead titanate thin coating was deposited between the PZT film and SS substrate in order to decrease the annealing temperature. X-ray diff…
Nanowires are grown from a cold-field-emission tip in the presence of a precursor, typically an organometallic or organic compound. Electron emission from the newly grown nanowire tip continues the growth and can give rise to nanowires that are tens of microns long. Single nanowires are obtained by limiting the field-…
Adsorption of H2, H22, O2, and CO on ZrB2(0001) was investigated by using high-resolution electron energy loss spectroscopy. In hydrogen and oxygen adsorption, a strong loss peak appears in the specular spectra, showing the dissociative adsorption on the threefold hollow site. The vibrational frequency shifts toward h…
Die charakteristische gelbe Farbe des TS-1/H2O2/H2O-Systems wird einer Side-on-Ti-Peroxo-Spezies als der aktiven Zwischenstufe bei Partialoxidationen zugeschrieben. Die Resonanz-Raman-spektroskopische Analyse des Zeoliths und eines Modellsalzes ((NH4+)3(TiO2F5)3−, siehe Bild) in Kombination mit der Analyse eines Ti-fr…
Abstract The trinuclear zinc siloxane [(MeZn) 2 Zn(OSiPh 3 ) 4 ] ( 1 ) and the first novel siloxane‐bridged hexanuclear dimer [{Me(THF)Zn} 2 OZn(OSiR 2 )(R 1 )] 2 (R = Ph, R 1 = OSiR 2 OSiR 2 O) ( 2 ) are accessible by Brønsted acid/base reaction of triorganosilanols with the zinc base ZnMe 2 . Both compounds were cha…
The surface pressure−area (π− A ) isotherms of enantiomeric polylactides and their equimolar blend reveal differences in the appearance of features and compression rate effects. Surface potential data indicate that the poly( l -lactide) monolayer interacts differently than the 50:50 poly( l -lactide)/poly( d -lactide)…
Abstract A one dimensional cobalt( II )−radical complex [Co(tmpyim) 2 (tp)] [tmpyim = 4,4,5,5‐tetramethyl‐2‐(3′‐pyridyl)imidazoline‐1‐oxyl 3‐oxide and tp = terephthalate dianion] has been synthesized and characterized by X‐ray crystallography. The crystal structure consists of infinite chains of Co(tmpyim) 2 units cro…
Polyoxoanions have enormous potential as drug delivery hosts, as catalysts, as agents for sequestering nuclear waste heavy metals, and as luminescent materials for laser and optical devices applications. We report the encapsulation of the polyoxoanion [Eu(H 2 O) 3 (α-1- P 2 W 17 O 61 )] 7- within Mobil crystalline mat…
The adsorption and oxidation reaction of CO on γ-Al 2 O 3 single-crystal thin films with Au nanoparticles were studied as a function of the particle size using reflection−adsorption infrared spectroscopy, temperature-programmed desorption (TPD), and the molecular beam technique in a temperature range of 93 K < T s < 2…
The symmetry adapted cluster (SAC)/SAC-configuration interaction method was applied to calculate the ground and excited states of zinc porphyrin monomers (without and with phenyl groups, ZnP and ZnPPh, respectively) and meso–meso linked (Zn2PMM) and doubly fused (Zn2PDF) zinc porphyrin dimers. Various features of the…