Materials Literature
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Four crystalline forms of isotactic poly(4-methyl-1-pentene) (i-P4MP) (forms I, II, II, and IV) have been studied through solid-state 13 C NMR CP-MAS spectroscopy. The assignment of the resonances observed in the 13 C NMR CP-MAS spectra was made by dipolar dephasing experiments. The presence in all spectra of two dist…
The structural, electronic and magnetic properties of spinel are investigated using the periodic ab initio Hartree - Fock program CRYSTAL. The geometry is fully optimized and the bulk modulus evaluated. The system is a large-gap insulator; the Mn - O bond is fully ionic, whereas in the Cr - O case there is a relativel…
The goal of this work has been to propose a novel approach to fine tune the transition temperatures of spin transition materials, based on the concept of spin transition molecular alloys. It has concerned the alloys of composition [Fe(R 1 trz) 3-3 x (R 2 trz) 3 x ]A 2, where R 1 trz and R 2 trz stand for two different…
The title complexes, (P•)FeIVO(Im) and (P•)FeIVO(OAr), have been prepared by the ozone oxidation of iron(III) porphyrins. The absorption spectra of (P•)FeIVO(Im) and (P•)FeIVO(OAr) are similar to those of compounds I of horseradish peroxidase and catalase, respectively. The NMR measurements of (P•)FeIVO(Im) show an a1…
Using a single-phase sample of ${\mathrm{Ce}}_{2}{\mathrm{Fe}}_{17}$ with the rhombohedral ${\mathrm{Th}}_{2}{\mathrm{Zn}}_{17}$-type structure, we measured the magnetization, resistivity, and specific heat under various magnetic fields up to 5.5 T. Below ${T}_{c}=125$ K, giant magnetoresistance (GMR) is induced by th…
Abstract Ni-Fe pyroaurite-type hydroxychlorides were prepared by aerial oxidation of Ni(II)-Fe(II) hydroxides precipitated in aqueous solution with various P = Fe/Ni ratios. When P ≥ 1/3, Ni(II)-Fe(II)-Fe(III) hydroxychlorides characterized by a specific Fe(IIl)/[Fe(II)+Ni(II)] ratio of 1/3, corresponding to the ideal…
Phase transitions and morphology of poly(diethylsiloxane) have been studied with help of differential scanning calorimetry and transmission electron microscopy on carbon−platinum replicas of freeze-fractured samples. The TEM experiments showed distinct lamellae in the case of the β and γ crystalline polymorphs, whose…
The γ-radiolysis of poly(tetrafluoroethylene- co -perfuoromethyl vinyl ether) (TFE/PMVE) was investigated using solid state 19 F and 13 C NMR spectroscopy. Chain scission products identified in the polymer were saturated chain ends −CF 2 CF 3 ( G = 1.0), methyl ether end groups −CF 2 OCF 3 ( G = 0.9), acid end groups…
Perovskite lead scandium tantalate (PST)—PbSc1/2Ta1/2O3—thin films have been prepared from lead-rich targets by rf magnetron sputtering onto a variety of substrates (e.g., MgO-on-sapphire and platinized silicon). Detailed microstructural chemical analysis of the films using transmission electron microscopy and energy…
The Bacillus subtilis araR locus (mapped at about 294 degrees on the genetic map) comprises two open reading frames with divergently arranged promoters, the regulatory gene, araR, encoding a repressor, and a partially cloned gene, termed araE by analogy to the Escherichia coli L-arabinose permease gene. Here, we repor…
Measurements of sonoluminescence from isolated cavities that spontaneously form on solid objects in a fluid-filled acoustic resonator are reported. The subnanosecond light flashes have a smooth ultraviolet spectrum similar to that from single bubbles, although with organic liquids low intensity Swan lines ride on the…
Antibody 03-1, which was prepared by immunization with meso-tetrakis(4-carboxyphenyl)porphyrin (TCPP) conjugate, has been found to bind strongly to Mn(III)-TCPP and Fe(III)-TCPP complexes with dissociation constants of 4.1 x 10(-)(7) and 1.5 x 10(-)(7) M, respectively, although other monoclonal antibodies raised again…
The aging phenomena of porous silicon (PS) over a 192 day time span have been studied using photoluminescence (PL) spectroscopy, Fourier transform infrared spectroscopy, and transmission electron microscopy. As-prepared PS exhibits red PL peaking near 650 nm. The PL intensity increases with time to some equilibrium va…
The surfaces of emeraldine (EM) base films of polyaniline (PANi) have been functionalized by thermal graft copolymerization with acrylic acid (AAc) and N, N -dimethyl(methacryloylethyl)ammonium propanesulfonate (DMAPS). The AAc graft copolymerized EM films were further functionalized via covalent immobilization of glu…
Abstract (CuI) 2 Cu 3 SbS 3 was prepared by solid‐state reaction of stoichiometric amounts of CuI, Cu, S, and Sb. The crystal structure was determined from single crystals at room temperature and ‐ 80°C. Red‐orange (CuI) 2 Cu 3 SbS 3 crystallizes in the orthorhombic system, space group Pnnm (no. 58) with a = 10.488(2)…
Online studies of structure and morphology development during continuous drawing of a nylon 66 fiber at different temperatures were carried out using synchrotron wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) techniques. From the two-dimensional (2D) WAXD measurement, unit-cell parameters…
The evolution of tidally truncated globular clusters is investigated by integrating a two-dimensional Fokker-Planck equation that allows the development of velocity anisotropy. We start from the isotropic Plummer model with tidal cut-off and follow the evolution through the core collapse. The heating by a three-body b…
The reaction of Pd with a molten mixture of A(2)Q(x)()/P(2)Q(5)/Q (A = K, Q = S, x = 3; A = Cs, Q = Se, x = 1) produced the molecular compounds K(4)Pd(PS(4))(2) (I), Cs(4)Pd(PSe(4))(2) (II), and Cs(10)Pd(PSe(4))(4) (III) and the solid-state KPdPS(4) (IV), K(2)PdP(2)S(6) (V), and Cs(2)PdP(2)Se(6) (VI). Compounds I-III…
Physico-chemical cell surface properties of 23 coagulase-negative staphylococcal strains, including contact angles, zeta potentials and elemental cell surface composition were measured, together with the adhesion of all strains to hexadecane. The data were employed in a hierarchical cluster analysis, revealing that th…
The synthesis and characterization of the following heterosapphyrins is presented: 3,7,18,22-tetraethyl-2,8,12,13,17,23-hexamethyl-27-oxasapphyrin ( 5 ), 3,8,12,13,17,22-hexaethyl-2,7,18,23-tetramethyl-15,29-dioxasapphyrin ( 6 ), and 3,7,18,22-tetraethyl-2,8,12,13,17,23-hexamethyl-15,27,29-trioxasapphyrin ( 7 ). These…