Materials Literature
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We hereby report a simple route for the low temperature synthesis of mesoporous nanocrystalline titania involving brief hydrothermal treatment of butanolic precursors and non-ionic tri-block-copolymer surfactant at 100 degrees C, followed by evaporation induced self assembly to make a crack-free flexible film. At no t…
New banana shaped liquid crystals with a carbosilane unit at one end were synthesised and depending on the number of Si-atoms either antiferroelectric (AF) or ferroelectric (FE) switching polar smectic C phases have been obtained.
In this study, yttrium-stabilized zirconia (YSZ) thin films 1-2 μm thick electrolyte have been prepared using NiO-YSZ anode as substrates. Fuel cell test was conducted with the single chamber configuration in methane-air gas mixture using (LSCF) as the cathode. Test results showed that the open-circuit voltage to be >…
Chemical reactions and stability of Ti3SiC2 in Cu during processing of Cu/Ti3SiC2 composites in the temperature range of 900-1070 degreesC were investigated using X-ray diffraction and scanning electron microscopy. The results indicated that Cu reacted with Ti3SiC2 above 900 degreesC, and the reaction products were cl…
Nanotechnology is set to change the world. Nanotechnology is increasingly talked about with the same breathless excitement that surrounded biotechnology and information technology at the start of the 1990s. Nanotechnology has caught the attention of several nongovernmental organizations (NGOs) that have spent the past…
The peripheral nitrogen of N -confused porphyrins ( NCP ) can serve as a hydrogen bonding donor and acceptor, and a metal coordination site as well. NCP forms versatile dimers with the assistance of metal ions such as Pd II , Pt II , Zn II , Cd II , Hg II , Mn II and Fe II . The square-planar divalent metal complexes…
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Using the HETPHEN concept a general and quantitative approach to the formation of heteroleptic nanogrids is illustrated.
The crystal structures of Ce2Zr2O7 and β-Ce2Zr2O7.5 were precisely determined by the Rietveld refinement of powder X-ray diffraction data. The present refinement revealed that the structure of β-Ce2Zr2O7.5 was formed by filling a half of oxygen vacancies of Ce2Zr2O7 in the specific ordered manner. The oxygen vacancy s…
The development of a small-diameter vascular graft has long been awaited. This review covers research activities, achievements and progress on vascular engineering in Japan, which was conducted over the last decade. The article includes recently developed experimental scaffolds, biologically active artificial extracel…
Ultrahigh temperature ceramics (UHTCs) including vol % SiC (HS), vol % SiC (ZS), and (ZCS) have been investigated for use as potential aeropropulsion engine materials. These materials were oxidized in water vapor (90%) using a cyclic vertical furnace at 1 atm. The total exposure time was 10 h at temperatures of 1200,…
Two methods for determination of the mean size of gold nanoparticles, based on measurement of the wavelengths of the maxima λ max of side scattering and extinction in the range 400–700 nm, are compared. Four sols with mean particle diameters d of about 15, 20, 25, and 30 nm, measured using the dynamic light-scattering…
A homologous series of silver complexes of 1-alkylimidazoles (R-im, R = CnH(2n+1), where n= 10, 12, 14, 16 and 18) was synthesized. All the CnH(2n+1)-im ligands are non-mesomorphic. Upon complexation, all the [Ag(CnH(2n+1)-im)2]-[NO3], except for n = 10, exhibit liquid crystalline properties. The crystal structure of…
Ultrasound was irradiated to a micro-1D and -2D space having a characteristic length of 200 microm, and the presence of cavitation was confirmed from video images, and the generation of OH radicals, which was quantitatively evaluated with fluorometry.
A series of fourteen heteroleptic (phthalocyaninato)(porphyrinato) rare earth(III) double-decker complexes, [MIII(Pc)(TClPP)] [M = Y, La–Lu except Ce and Pm; Pc = phthalocyaninate; TClPP = meso-tetrakis(4-chlorophenyl)porphyrinate] has been prepared by base-promoted cyclization of phthalonitrile on the corresponding […
Porous titanium dioxide is an attractive material for solar cell application on account of its stability, electron transport properties, and the possibilities for controlling surface morphology as well as for its ease of fabrication and low cost. Nanostructured TiO 2 has been intensively studied for applications to dy…
Ni-free Ti-Sc-Mo shape memory alloys are designed as a substitute for Ti-Ni alloys in the biomedical field. From results of bending and recovery test with heating, Ti-Sc-Mo alloys were found to have superior shape memory effect. The optimum composition for the shape memory effect was Ti-4.0 to 6.0Sc-6.0Mo alloys. The…
We report a carboxylate triangle consisting of three manganese(II) centres which is made from manganese(II) carbonate and pivalic acid. The magnetic exchange within the triangle is extremely weak, and antiferromagnetic. Several models have been used to fit the magnetic data, and the best fit uses two weak antiferromag…
Biocomposites can be designed and engineered from plant bio-fibres and a blend of unsaturated polyester resin and derivatized vegetable oil to replace existing glass fibre-polyester composites for use in housing applications. Natural fibre composites (biocomposites) would provide environmental gains, reduced energy co…
We present here the synthesis, physicochemical characterisation and catalytic evaluation of mesoporous silicon oxynitride materials. The solid base catalytic materials were prepared by subjecting pure silica MCM-41 mesoporous molecular sieves to nitridation, i.e., treatment with ammonia at high temperature. The mesopo…