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Seeing Molecular Configuration in Twisted Crystal Form

Bart Kahr、Alexander G. Shtukenberg2016-07-06Israel Journal of Chemistry

Abstract Structural chemistry began with Louis Pasteur, who first saw the configuration of molecules manifest in the shapes of crystals. Here is reviewed forgotten, century‐old efforts to make molecular configuration vivid in polycrystalline ensembles. Resorcinol, and a variety of other simple molecular crystals, when…

Crystallography and molecular interactionsCrystallization and Solubility StudiesMolecular spectroscopy and chirality

Fabrication and properties of rare‐earth‐doped optical fiber using barium as an alternate codopant

Anirban Dhar、Mukul Chandra Paul、Sourav Das Chowdhury 等 6 位作者2016-07-06physica status solidi (a)

Barium has been established as an alternate codopant other than conventional aluminum or phosphorous for fabrication of rare‐earth‐ (RE) doped optical fiber through modified chemical vapor deposition (MCVD) coupled with solution doping technique. Different optical and material characterization results of our fabricate…

Advanced Fiber Optic SensorsGlass properties and applicationsPhotonic Crystal and Fiber Optics

Modelling biodiesel–diesel spray combustion using multicomponent vaporization coupled with detailed fuel chemistry and soot models

Sujith Sukumaran、Song‐Charng Kong2016-07-06Combustion Theory and Modelling

A multicomponent vaporization model is integrated with detailed fuel chemistry and soot models for simulating biodiesel–diesel spray combustion. Biodiesel, a fuel mixture comprised of fatty-acid methyl esters, is an attractive alternative to diesel fuel for use in compression-ignition engines. Accurately modelling of…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceBiodiesel Production and Applications

Defect analysis by transmission electron microscopy of epitaxial Al-doped ZnO films grown on (0001) ZnO and a-sapphire by RF magnetron sputtering

R. Mythili、André Bikowski、K. Ellmer2016-07-06Journal of Applied Physics

Microstructural investigations by cross section Transmission Electron Microscopy have been carried out on Al-doped ZnO films epitaxially grown on (0001) ZnO and a-sapphire by RF magnetron sputtering, since it is known that crystallographic defects influence the physical properties of ZnO films. Threading dislocations…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Large Orbital Magnetic Moment Measured in the [TpFe III (CN) 3 ] − Precursor of Photomagnetic Molecular Prussian Blue Analogues

Sadaf Fatima Jafri、Evangelia S. Koumousi、Philippe Sainctavit 等 14 位作者2016-07-06Inorganic Chemistry

Photomagnetism in three-dimensional Co/Fe Prussian blue analogues is a complex phenomenon, whose detailed mechanism is not yet fully understood. Recently, researchers have been able to prepare molecular fragments of these networks using a building block synthetic approach from mononuclear precursors. The main objectiv…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Catalytic Effect of Two Shapes of Nano‐Fe2O3 on Hexanitrohexaazaisowurtzitane Using a Non‐Isothermal Decomposition Kinetic Method

Rong Gao、Ningning Zhao、Jianbing Liu 等 5 位作者2016-07-06Propellants Explosives Pyrotechnics

Abstract Nanosized Fe2O3 particles (nano‐Fe2O3) with two shapes (tetrakaidecahedral and grainy) were synthesized by hydrothermal methods. The morphologies and structures were characterized using a combination of experimental techniques including X‐ray diffraction (XRD) and scanning electron microscopy (SEM). Two compo…

Energetic Materials and CombustionInorganic and Organometallic ChemistryThermal and Kinetic Analysis

Preparation and characterization of nanocomposites made from chemoenzymatically prepared polyester urethanes and functionalized multiwalled carbon nanotubes

Víctor H. Antolín‐Cerón、Karla A. Barrera‐Rivera、M.A. Fuentes‐García 等 5 位作者2016-07-06Polymer Composites

Multiwalled carbon nanotubes (MWNTs) were functionalized with four different functional groups and used as nanofillers to reinforce biodegradable polyurethanes (PU), in an effort to explore their effect on the thermal and mechanical properties of the obtained nanocomposites. The PU were synthesized via one step proces…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Numerical study of the giant nonlocal resistance in spin-orbit coupled graphene

Zibo Wang、Haiwen Liu、Hua Jiang 等 4 位作者2016-07-06Physical review. B./Physical review. B

Recent experiments find the signal of giant nonlocal resistance ${R}_{\mathrm{NL}}$ in $\mathsf{H}$-shaped graphene samples due to the spin/valley Hall effect. Interestingly, when the Fermi energy deviates from the Dirac point, ${R}_{\mathrm{NL}}$ decreases to zero much more rapidly compared with the local resistance…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Optimization of multi-grating volume holographic spectrum splitters for photovoltaic applications

G. B. Ingersoll、James R. Leger2016-07-06Applied Optics

Recent research has shown that using multiple diverse-bandgap photovoltaic (PV) cells in conjunction with a spectrum splitting optical system can significantly improve PV power generation efficiency. Although volume Bragg gratings (VBGs) can serve as effective spectrum splitters, the inherent dispersion of a VBG can b…

Photonic and Optical DevicesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings

Effect of Surface Deposited Layer on Active Screen Plasma Nitriding

Akio Nishimoto、Toshiaki Tanaka、T. Matsukawa2016-07-06Materials Performance and Characterization

The nitriding process is widely used to improve the tribological properties and wear resistance of metal surfaces. An “edge effect” occurs due to distortions of the electric field around the corners and edges of the components, although the components are well heated. This results in nonuniformity in properties such a…

GaN-based semiconductor devices and materialsMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Band alignment at a MgO/GaSb heterointerface using x-ray photoelectron spectroscopy measurements

Ruxue Li、Zhipeng Wei、Xue Liu 等 13 位作者2016-07-06Materials Research Express

Band alignment at a MgO/GaSb heterointerface using x-ray photoelectron spectroscopy measurements, Li, Ruxue, Wei, Zhipeng, Liu, Xue, Li, Yongfeng, Fang, Xuan, Tang, Jilong, Fang, Dan, Gao, Xian, Wang, Dengkui, Hao, Yongqin, Yao, Bin, Ma, Xiaohui, Wang, Xiaohua

Semiconductor Quantum Structures and DevicesZnO doping and propertiesAdvanced Semiconductor Detectors and Materials

Mushroom-type structures with the wires connected through diodes: Theory and applications

Ali Forouzmand、Chandra S. R. Kaipa、Alexander B. Yakovlev2016-07-06Journal of Applied Physics

In this paper, we establish a general formalism to quantify the interaction of electromagnetic waves with mushroom-type structures (high impedance surface and bi-layer) with diodes inserted along the direction of the wires. The analysis is carried out using the nonlocal homogenization model for the mushroom structure…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Improving the measurement of dielectric function by TEM-EELS: avoiding the retardation effect

Norihito Sakaguchi、Luka Tanda、Yuji Kunisada2016-07-06Microscopy

, avoiding the retardation effect arising in electron energy-loss spectroscopy (EELS). The EELS data differed from the optical data in the energy range of 10-20 eV due to the retardation effect, even though Cerenkov loss was thoroughly suppressed. The calculated differential cross-section indicates that the influence…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Metallic Nanodroplet Induced Coulomb Catalysis for Off-Resonant Plasmonic Enhancement of Photoemission in Semiconductors

Arup Neogi、Karol Gryczynski、Antonio Llopis 等 10 位作者2016-07-06ACS Omega

The enhancement of light from semiconductors due to surface plasmons coupled resonantly to its emission is limited because of dissipation in the metal and is also restricted by the dielectric characteristics and homogeneity of the metal-semiconductor interface. We report a new mechanism based on electrostatic interact…

GaN-based semiconductor devices and materialsGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Microscopic theory on charge transports of a correlated multiorbital system

Naoya Arakawa2016-07-06Physical review. B./Physical review. B

Current vertex correction (CVC), the backflowlike correction to the current, comes from conservation laws, and the CVC due to electron correlation contains information about many-body effects. However, it has been little understood how the CVC due to electron correlation affects the charge transports of a correlated m…

Physics of Superconductivity and MagnetismAdvanced Condensed Matter PhysicsOrganic and Molecular Conductors Research

Dielectric spectroscopy of CuInSe2 single crystals

С. Н. Мустафаева2016-07-06Semiconductor Physics Quantum Electronics & Optoelectronics

The results of high-frequency dielectric measurements with obtained -CuInSe 2 single crystals provided an opportunity to determine the mechanisms of dielectric losses and charge transport, and also to evaluate the density of states at the Fermi level; the average time of charge carrier hopping between localized states…

Chalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallography

The onset of layer undulations in smectic A liquid crystals due to a strong magnetic field

A Contreras、C Garcia-Azpeitia、C J García-Cervera 等 4 位作者2016-07-06Nonlinearity

Abstract We investigate the effect of a strong magnetic field on a three dimensional smectic A liquid crystal. We identify a critical field above which the uniform layered state loses stability; this is associated to the onset of layer undulations. In a previous work García-Cervera and Joo (2012 Arch. Ration. Mech. An…

Liquid Crystal Research AdvancementsMathematical Dynamics and FractalsNonlinear Dynamics and Pattern Formation

Phase Diagram and Structure of Mixtures of Large Colloids and Linear Polymers under Good-Solvent Conditions

Giuseppe D’Adamo、Andrea Pelissetto、Carlo Pierleoni2016-07-06Macromolecules

Efficient Monte Carlo simulations are used to determine the liquid–liquid binodal line of mixtures of hard-sphere colloids and neutral polymers under good-solvent conditions for two values of the polymer-to-colloid size ratio q, q = 0.5 and 1. We use a multiblob coarse-graining approach, in which groups of monomers ar…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesPickering emulsions and particle stabilization

The orientation relationships of nanobelt-like Si2Hf precipitates in an Al–Si–Mg–Hf alloy

Xueli Wang、Huilan Huang、Xinfu Gu 等 6 位作者2016-07-06Journal of Applied Crystallography

The orientation relationships (ORs) between the Al matrix and Si2Hf precipitates with an orthorhombic structure in an Al–Si–Mg–Hf alloy after heat treatment at 833 K for 20 h were investigated by transmission electron microscopy and electron diffraction. Four ORs are identified as (100)Al||(010)p, (0\overline {1}1)Al|…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Protective applications of vacuum-deposited perfluoropolymer films

Kostyantyn Grytsenko2016-07-06Semiconductor Physics Quantum Electronics & Optoelectronics

The paper summarizes in brief applications of perfluoropolymer thin films deposited from the gas phase by several different methods, for protection of various materials and devices both at the research stage and already in industry. Perfluoropolymer films protect from corrosion coated metals, attain superhydrophobic p…

Polymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane ChemistryNanotechnology research and applications