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From gold nanoparticles to luminescent nano‐objects: experimental aspects for better gold‐chromophore interactions

Julien R. G. Navarro、Frédéric Lerouge2016-07-06Nanophotonics

Abstract Gold nanoparticles have been the center of interest for scientists since many decades. Within the last 20 years, the research in that field has soared with the possibility to design and study nanoparticles with controlled shapes. From spheres to more complex shapes such as stars, or anisotropic architectures…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Finite-size effect on evolution of Griffiths phase in manganite nanoparticles

A. K. Pramanik、A. Banerjee2016-07-06Journal of Physics Condensed Matter

The finite-size effect on the evolution of the Griffiths phase (GP) is studied using nanoparticles of half-doped manganite Pr0.5Sr0.5MnO3 with different average particle sizes but with similar structural parameters. All the samples exhibit pronounced GP behavior. With reducing the particle size, the Griffiths temperat…

Advanced Thermoelectric Materials and DevicesTheoretical and Computational PhysicsMagnetic and transport properties of perovskites and related materials

Self-assembly of colloidal micelles in microfluidic channels

Arash Nikoubashman2016-07-06Soft Matter

The self-assembly of amphiphilic Janus colloids in microfluidic channels is studied using hybrid molecular dynamics simulations with fully resolved hydrodynamic interactions incorporated through the multi-particle collision dynamics algorithm. The simulations are conducted at a density and temperature where the Janus…

Surfactants and Colloidal SystemsInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

Native defects as sources of optical transitions in MgAl2O4spinel

Pablo D. Borges、J Cott、Frederico Garcia Pinto 等 5 位作者2016-07-06Materials Research Express

The outstanding physical and chemical properties of the magnesium aluminate (MgAl 2 O 4 ) spinel makes it an important material for novel technological applications. Considering that a presence of native defects can promote important changes in those properties, in this work we present a study of the structural, elect…

Luminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Lorentz microscopy and small-angle electron diffraction study of magnetic textures in La1−xSrxMnO3 (0.15

Atsuhiro Kotani、Hiroshi Nakajima、Kenji Harada 等 5 位作者2016-07-06Physical review. B./Physical review. B

Magnetic textures in the ferromagnetic phases of $\mathrm{L}{\mathrm{a}}_{1\ensuremath{-}x}\mathrm{S}{\mathrm{r}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}$ for $0.15<x<0.30$ have been investigated by Lorentz microscopy combined with small-angle electron diffraction experiments. Various types of magnetic textures characterized b…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Preparation and properties of polyimide/chopped carbon fiber composite foams

Jianwei Li、Guangcheng Zhang、Jiantong Li 等 6 位作者2016-07-06Polymers for Advanced Technologies

In this study, a series of reinforced polyimide (PI)/carbon fiber (CF) composite foams were fabricated through thermal foaming of polyester ammonium salt (PEAS) precursor powders. The PEAS precursor powders containing different contents of chopped CF were synthesized from benzophenone‐3,3′,4,4′‐tetracarboxylic dianhyd…

Flame retardant materials and propertiesSynthesis and properties of polymersTribology and Wear Analysis

High Thermal Gradient in Thermo-electrochemical Cells by Insertion of a Poly(Vinylidene Fluoride) Membrane

Syed Waqar Hasan、Suhana Mohd Said、Mohd Faizul Mohd Sabri 等 8 位作者2016-07-06Scientific Reports

Thermo-Electrochemical cells (Thermocells/TECs) transform thermal energy into electricity by means of electrochemical potential disequilibrium between electrodes induced by a temperature gradient (ΔT). Heat conduction across the terminals of the cell is one of the primary reasons for device inefficiency. Herein, we em…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

In Situ Single‐Nanoparticle Spectroscopy Study of Bimetallic Nanostructure Formation

Jeremy G. Smith、Indranath Chakraborty、Prashant K. Jain2016-07-06Angewandte Chemie International Edition

Bimetallic nanostructures (NSs), with utility in catalysis, are typically prepared using galvanic exchange (GE), but the final catalyst morphology is dictated by the dynamics of the process. In situ single nanoparticle (NP) optical scattering spectroscopy, coupled with ex situ electron microscopy, is used to capture t…

Electrocatalysts for Energy ConversionGold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactions

Unprecedented Electro‐Optic Performance in Lead‐Free Transparent Ceramics

Alexander D. Dupuy、Yasuhiro Kodera、Javier E. Garay2016-07-06Advanced Materials

A high-performance lead-free electro-optic (EO) transparent material is introduced and used in an EO device operating up to 10 kHz. The BZT–BCT ceramic, named as BXT, has an effective DC EO coefficient, rc = 530 pm V−1, which is higher than state-of-the-art materials such as LiNbO3. The high EO response can be leverag…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Cyclotriphosphazene-Based Intumescent Flame Retardant against the Combustible Polypropylene

Panyue Wen、Qilong Tai、Yuan Hu 等 4 位作者2016-07-06Industrial & Engineering Chemistry Research

Flame retardant polypropylene (PP) was obtained through appropriately blending with microencapsulated ammonium polyphosphate (MAPP) and a novel cyclotriphosphazene-based char-forming agent (CPCFA) and synthesized using a one-pot method in high yield (86.5%). An increase in the limiting oxygen index (LOI) and the obser…

Fire dynamics and safety researchFlame retardant materials and propertiesSynthesis and properties of polymers

Using Asphaltene Supermolecules Derived from Coal for the Preparation of Efficient Carbon Electrodes for Supercapacitors

Wen-Hui Qu、Yubo Guo、Wenzhong Shen 等 4 位作者2016-07-06The Journal of Physical Chemistry C

Asphaltene supermolecules extracted from coal consist of highly condensed polyaromatic units and peripheral aliphatic chains, which is a natural source with high carbon content. In this study, we demonstrate that the asphaltene can be used as an ideal supermolecular carbon precursor for the fabrication of carbon nanos…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationConducting polymers and applications

Ultrabright single-photon source on diamond with electrical pumping at room and high temperatures

Dmitry Yu. Fedyanin、Mario Agio2016-07-06New Journal of Physics

The recently demonstrated electroluminescence of color centers in diamond makes them one of the best candidates for room temperature single-photon sources.However, the reported emission rates are far off what can be achieved by state-of-the-art electrically driven epitaxial quantum dots.Since the electroluminescence m…

Quantum and electron transport phenomenaDiamond and Carbon-based Materials ResearchPhotonic Crystals and Applications

Scalable and Formable Tellurite‐Based Transparent Ceramics for Near Infrared Applications

Anthony Bertrand、Julie Carreaud、Sébastien Chenu 等 13 位作者2016-07-06Advanced Optical Materials

Innovative transparent tellurite polycrystalline ceramics are demonstrated to be simply elaborated by full and congruent crystallization of the 75TeO2–12.5Bi2O3–12.5Nb2O5 parent glass. The low temperature tellurite glass elaboration and its stability both enable the preparation of scalable tailor-shaped ceramics with…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Enzymatic extraction and characterisation of a thermostable collagen from swim bladder of rohu (Labeo rohita)

Pal Gaurav Kumar、Nidheesh Thadathil、Karadka Govindaraju 等 5 位作者2016-07-06Journal of the Science of Food and Agriculture

Abstract BACKGROUND The fish swim bladder is considered as a potential source of realistic collagen. Currently, processing of the Indian major carp rohu (Labeo rohita) generates an enormous quantity of non‐edible by‐products, including swim bladders, which are discarded as waste with no commercial value. In the presen…

Protein Hydrolysis and Bioactive PeptidesCollagen: Extraction and CharacterizationPolysaccharides Composition and Applications

Chemically Triggered Formation of Two-Dimensional Epitaxial Quantum Dot Superlattices

Willem Walravens、Jonathan De Roo、Emile Drijvers 等 9 位作者2016-07-06ACS Nano

Two dimensional superlattices of epitaxially connected quantum dots enable size-quantization effects to be combined with high charge carrier mobilities, an essential prerequisite for highly performing QD devices based on charge transport. Here, we demonstrate that surface active additives known to restore nanocrystal…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsElectronic and Structural Properties of Oxides

3D Visualization of the Iron Oxidation State in FeO/Fe3O4Core–Shell Nanocubes from Electron Energy Loss Tomography

Pau Torruella、Raúl Arenal、Francisco de la Peña 等 15 位作者2016-07-06Nano Letters

The physicochemical properties used in numerous advanced nanostructured devices are directly controlled by the oxidation states of their constituents. In this work we combine electron energy-loss spectroscopy, blind source separation, and computed tomography to reconstruct in three dimensions the distribution of Fe(2+…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesCharacterization and Applications of Magnetic Nanoparticles

Nanoanalytical Electron Microscopy Reveals a Sequential Mineralization Process Involving Carbonate-Containing Amorphous Precursors

Kharissa Ayu Perdana Nitiputri、Quentin M. Ramasse、Hélène Autefage 等 8 位作者2016-07-06ACS Nano

A direct observation and an in-depth characterization of the steps by which bone mineral nucleates and grows in the extracellular matrix during the earliest stages of maturation, using relevant biomineralization models as they grow into mature bone mineral, is an important research goal. To better understand the proce…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionIron oxide chemistry and applications

Amide proton transfer imaging of brain tumors using a self-corrected 3D fast spin-echo dixon method: Comparison With separate B 0 correction

Osamu Togao、Jochen Keupp、Akio Hiwatashi 等 7 位作者2016-07-06Magnetic Resonance in Medicine

Purpose To assess the quantitative performance of three-dimensional (3D) fast spin-echo (FSE) Dixon amide proton transfer (APT) imaging of brain tumors compared with B0 correction with separate mapping methods. Methods Twenty-two patients with brain tumors (54.2 ± 18.7 years old, 12 males and 10 females) were scanned…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Preparation and Properties of Epoxy Resin-Coated Micro-Sized Ferrosilicon Powder

Jiangang Ku、Huihuang Chen、Kui He 等 4 位作者2016-07-06Materials Research

Ferrosilicon powder surface coated with a dense epoxy resin membrane was prepared via coating precipitation methods using silane coupling agents as the modifier and epoxy resin as the coating agent. FTIR, FESEM, MPMS-XL, and TG-DSC were used to analyze the morphology, surface composition, magnetic property and thermos…

Advanced ceramic materials synthesisPowder Metallurgy Techniques and MaterialsMaterial Properties and Applications

Synthesis and Characterization of CuNb2O6 from an Oxalic Precursor Via Solid State Reaction

Maria Veronilda Macedo Souto、Maria José Santos Lima、Cleonilson Mafra Barbosa 等 6 位作者2016-07-06Materials Research

The present paper's objective was to synthesize and characterize both the oxalic niobium precursor (NH4)3NbO(C2O4)3.H2O, and the product of its doping with Cu and calcining, CuNb2O6. In order to obtain the niobium precursor, commercially available niobium oxide (Nb2O5) was subject to fusion with potassium bisulfate (K…

Hydrocarbon exploration and reservoir analysisPetroleum Processing and AnalysisX-ray Diffraction in Crystallography