Materials Literature
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An electrolytic process was utilised to fabricate NiCoCrAlY coatings, involving deposition of a composite coating consisting of the (Ni,Co) matrix and CrAlY particles, followed by a diffusion heat treatment to convert the composite coating to the desired NiCoCrAlY microstructure. This study focused on the effects of t…
Abstract Five new CuI/[Au(CN)2]−‐based coordination polymer materials—Cu(py)2[Au(CN)2] (1), Cu(PPh3)(MeCN)[Au(CN)2]⋅MeCN (2 a), Cu(PPh3)(MeCN)[Au(CN)2] (2 b), Cu3(THT)4[Au(CN)2]3 (3 a) and Cu(THT)[Au(CN)2] (3 b)—were prepared and characterized in terms of their structural and photoluminescence properties, and thermal…
Porous NiO, Co 3O 4 and NiCo2O4 superstructures were successfully prepared via a facile hydrothermal-annealing method. The products were characterized by powder X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and energy dispersive spectrometry (EDS). The Brunauer-Emmett-Teller surface area…
Abstract Water‐soluble platinum(IV) prodrugs, which proved kinetically stable to reduction in the presence of physiological concentration of ascorbate, were quickly reduced to their active form, oxaliplatin, when co‐incubated with a macrocycle metallotexaphyrin (i.e., Motexafin Gadolinium (MGd)). The reduction of PtIV…
An inorganic nano light-emitting transistor (INLET) consisting of p-type porous Si nanowires (PoSiNWs) and an n-type ZnO nanofilm was integrated on a heavily doped p-type Si substrate with a thermally grown SiO2 layer. To verify that modulation of the Fermi level of the PoSiNWs is key for switchable light emitting, I-…
Controlling the topologies of polymers is a hot topic in polymer chemistry because the physical and/or chemical properties of polymers are determined (at least partially) by their topologies. This study exploits the host-guest interactions between dibenzo-24-crown-8 and secondary ammonium salts and metal coordination…
Spatial atomic layer deposition (S-ALD) is a potential high-throughput manufacturing technique offering fast and large scale ultrathin films deposition. Here, an S-ALD system with modular injectors is introduced for fabricating binary oxides and their nanolaminates. By optimizing the deposition conditions, both ZnO an…
Crude oil fouling on heat transfer surfaces is often described as the result of two competing mechanisms: a deposition and a deposition-offsetting mechanism. There is uncertainty about whether the offsetting mechanism is suppression (due inhibition of attachment or back-diffusion of foulant from near the wall into the…
We present a versatile synthetic route leading toward generating surface-attached polyacrylamide gels, in which the cross-link density varies continuously and gradually across the substrate in two orthogonal directions. We employ free radical polymerization to synthesize random copolymers comprising ∼5% of photoactive…
Robust and fast methods for chemical or multiphase equilibrium calculation are routinely needed by chemical-process engineers working on sizing or simulation aspects. Yet, while industrial applications essentially require calculation tools capable of discriminating between stable and nonstable states and converging to…
Abstract The International Tokamak Physics Activity Topical Group on scrape-off layer and divertor physics has amassed a database comprising hundreds of reciprocating Langmuir probe measurements of the main scrape-off layer heat-flux width λ q in inner-wall limited discharges. We have carried out an analysis, based on…
Although multidomain proteins predominate the proteome of all organisms and are expected to display complex folding behaviors and significantly greater structural dynamics as compared with single-domain proteins, their conformational heterogeneity and its impact on their interaction with ligands are poorly understood…
Abstract The evolution of the microstructure and texture during annealing of a modified ferritic/martensitic 9Cr-1Mo steel compressed by dynamic plastic deformation (DPD) to a strain of 2.3 has been investigated using transmission electron microscopy and electron backscatter diffraction. It is found that the duplex 〈1…
Simple methods for patterning single crystals are critical to fully realize their applications in electronics. However, traditional vapor and solution methods are deficient in terms of crystals with random spatial and quality distributions. In this work, we report a dewetting-induced assembly strategy for obtaining la…
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Coplanar and noncoplanar polychlorinated biphenyls (PCBs) are known to have different routes and degree of toxicity. Here, the effects of noncoplanar PCB 52 and coplanar PCB 77 present at 2 mol % in a model system consisting of POPC liposomes (50% hydrated) are investigated by solid-state (13)C and (31)P NMR at 298 K.…
Ultrahigh molecular weight polyethylene (UHMWPE) is one of the most preferred materials as an acetabular cup-liner for bone implant applications. The current work develops a correlation between wettability, protein adsorption with osteogenic differentiation upon reinforcement of functionalized carbon nanotube (f-CNT)…
Effects of laser shock peening (LSP) on laser-welded aluminium alloy joints filling Al + 1.0 wt-% CeO 2 were investigated. Porosity ratio, microstructure, residual stress, hardness, tensile strength and fracture morphology were evaluated. Double-side LSP decreased the porosity ratio, refined microstructure, relieved t…
Pinocembrin-7-O-β-D-glucoside (PCBG), a flavonoid isolated from Penthorum chinense Pursh., has significant liver-protecting effects. The pharmacokinetics of PCBG and its major metabolite pinocembrin (PCB) in rats were investigated in this study. A sensitive and accurate UPLC-MS/MS method was developed and validated fo…
Surfaces with patterned wettability contrast are important in industrial applications such as heat transfer, water collection, and particle separation. Traditional methods of fabricating such surfaces rely on microfabrication technologies, which are only applicable to certain substrates and are difficult to scale up a…