Materials Literature
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We report the behavior of the charge carrier plasmon of $2H$-transition metal dichalcogenides (TMDs) as a function of intercalation with alkali metals. Intercalation and concurrent doping of the TMD layers have a substantial impact on plasmon energy and dispersion. While the plasmon energy shifts are related to the in…
The almost multiferroic perovskite EuTiO3 (ETO) has been prepared as films on substrates of SrTiO3. For all prepared film thicknesses highly transparent insulating films with atomically flat surfaces and excellent orientation have been grown. They were characterized by X-ray diffraction, magnetic susceptibility and bi…
In this work, the authors discuss a systematic method of characterizing the damage process in graphene. The mathematical formulation is limited to the elastic range. In the elastic constitutive equation for graphene, both the second-order and third-order elastic stiffnesses are considered. The formulation is performed…
Many technical applications of woven fabric are subject to increasing high pressure from air transport through the fabric. The through-thickness permeability (TP) of woven materials exhibits a dynamic response to increased air pressure. This paper presents an analytical model for predicting the steady TP of woven fabr…
The structures of the subnanometer clusters of CdS that form in zeolite Y (FAU), prepared as follows, have been determined. A single crystal of Cd 2+ -exchanged zeolite Y was prepared by the exchange of Na 75 –Y (|Na 75 |[Si 117 Al 75 O 384 ]–Y with aqueous Cd(NO 3 ) 2 at 294 K, followed by vacuum dehydration at 723 K…
Surface‐enhanced Raman spectra of two cyclic cationic peptides with therapeutic interest, somatostatin‐14 and its synthetic analog octreotide, were simultaneously analyzed as a function of concentration and colloidal size. It appeared that the large size (~95 nm) citrate‐reduced gold nanoparticles are the most adequat…
We investigate the mechanisms of incipient plasticity at low angle twist and asymmetric tilt boundaries in fcc metals. To observe plasticity of grain boundaries independently of the bulk plasticity, we simulate nanoindentation of bicrystals. On the low angle twist boundaries, the intrinsic grain boundary (GB) dislocat…
Hollow carbon nanospheres with controlled morphologies were synthesized via the copper-carbon direct current arc discharge method by alternating the concentrations of methane in the reactant gas mixture. A self-healing process to keep the structural integrity of encapsulated graphitic shells was evolved gradually by a…
Radio frequency magnetron sputtering has been used here to find the parameters at which to deposit Ta2O5 optical thin films with negligible absorption in the visible spectrum. The design of experiment methodology was employed to minimize the number of experiments needed to find the optimal results. Two independent app…
The equilibrium between 6- and 8-bromo-apigeninidin is quantitatively displaced toward the formation of the former in the presence of cucurbit[7]uril because of the selective recognition of the 6-bromo isomer by the host. This phenomenon permits us to conceive a unidirectional multistate switch addressed with host-gue…
Diacetylenes have been the subject of current research because of their interesting optoelectronic properties. Herein, we report that substituted diphenylbutadiynes exhibit locally excited (LE) and excimer emissions in water and multiple emissions from the LE, excimer, and intramolecular charge transfer (ICT) states i…
Quasielastic neutron scattering measurements and molecular dynamics simulations were combined to investigate the collective dynamics of deuterated methanol, CD3OD. In the experimentally determined dynamic structure factor, a slow, non-Fickian mode was observed in addition to the standard density-fluctuation heat mode.…
The structure of water in 70 wt % sorbitol-30 wt % water mixture is investigated by wide-angle neutron scattering (WANS) as a function of temperature. WANS data are analyzed using empirical potential structure refinement to obtain the site-site radial distribution functions (RDFs). Orientational structure of water is…
Oxide formation under oxygen-rich reaction conditions has independently been reported for both CO oxidation and NO oxidation with Pd single-crystal model catalysts. We present a first-principles kinetic Monte Carlo study addressing the simultaneous occurrence of both reactions at Pd(100) exposed to CO- and NO-containi…
In this paper, we investigate the role of deposition angle on the physical properties and work function of pulsed dc sputter-deposited Al-doped zinc oxide (AZO) thin films. It is observed that average grain size and crystal quality increase with higher angle of deposition, yielding improved optical properties. A syste…
Abstract Biopolymer films are increasing in popularity due to its environmental friendly. The objectives of this work were to study the effect of drying temperatures and plasticizer types on the physical and mechanical properties of films. Konjac glucomannan (KGM) was used for base film forming. A heat pump dryer was…
High-throughput fabrication of microstructured surfaces with multi-directional, re-entrant, or otherwise curved features is becoming increasingly important for applications such as phase change heat transfer, adhesive gripping, and control of electromagnetic waves. Toward this goal, curved microstructures of aligned c…
The ligand shell structure of the aspicule Ag 44 (4-MBA) 30 (MBA: mercaptobenzoic acid, in the thiolate form) was modified in a precise, site-specific manner. Laser irradiation at 633 nm of a monolayer assembly of plasmonic Ag nanoparticles (NPs) covered with Ag 44 (4-MBA) 30 clusters leads to decarboxylation of 4-MBA…
Structural and magnetic properties of the LaCoO3/SrTiO3 (LCO/STO) multilayers (MLs) with a fixed STO layer of 4 nm but varied LCO layer thicknesses have been systematically studied. The MLs grown on Sr0.7La0.3Al0.65Ta0.35O3 (LSAT) and SrTiO3 (STO) exhibit the in-plane lattice constant of the substrates, but those on L…
Abstract Two-dimensional spectroscopic observations were conducted for an inductively coupled thermal plasma (ICTP) torch during TiO 2 nanopowder synthesis. The feedstock was injected intermittently into the ICTP torch to investigate the Ti feedstock evaporation process clearly and to elucidate the formation process o…