Materials Literature
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PURPOSE: Chemical exchange saturation transfer (CEST) is a contrast mechanism enhancing low-concentration molecules through saturation transfer from their exchangeable protons to bulk water. Often many scans are acquired to form a Z-spectrum, making the CEST method time-consuming. Here, an ultrafast localized CEST-spe…
A novel approach to facilitate excitation and readout processes of isolated negatively charged nitrogen‐vacancy (NV) centers is proposed. The approach is based on the concept of all‐dielectric nanoantennas. It is shown that the all‐dielectric nanoantenna can significantly enhance both the emission rate and emission ex…
We numerically investigate the properties of a hybrid grating structure acting as a resonator with ultrahigh quality factor. This reveals that the physical mechanism responsible for the resonance is quite different from the conventional guided mode resonance (GMR). The hybrid grating consists of a subwavelength gratin…
We describe a high throughput method for screening up to 1728 distinct chemicals with protein crystals on a single microplate. Acoustic droplet ejection (ADE) was used to co-position 2.5nL of protein, precipitant, and chemicals on a MiTeGen in situ-1 crystallization plate™ for screening by co-crystallization or soakin…
For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O)n](2+) with n = 12 for Ln = Sm-Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by (89)Y and (1)H NMR spectros…
Cisplatin-incorporating pseudoblock copolymer nanoparticles with high drug loading efficiency (ca. 50%) were prepared built on host-guest inclusion complexation between β-cyclodextrin end-capped poly(N-vinylpyrrolidone) block and admantyl end-capped poly(aspartic acid) block, followed by the coordination between cispl…
A new class of advanced structural materials, based on the Fe-O-vacancy system, has exceptional resistance to high-temperature creep and excellent tolerance to extremely high-dose radiation. Although these remarkable improvements in properties compared to steels are known to be associated with the Y-Ti-O-enriched nano…
Cu/Au multilayers with individual layer thickness of 100 nm were deformed by cyclic sliding using a nanoindenter. With increasing cycle number, a distinct sequence of changes was observed, from uniform thinning through formation of waviness and vortices until finally a mechanically mixed structure developed. Fluid-lik…
A silk protein, fibroin, was isolated from the cocoons of the domesticated silkworm (Bombyx mori) and cast into membranes to serve as freestanding templates for tissue-engineered corneal cell constructs to be used in ocular surface reconstruction. In this study, we sought to enhance the attachment and proliferation of…
Two collagen-mimetic peptides, CP(+) and CP(-), are reported in which the sequences comprise a multiblock architecture having positively charged N-terminal (Pro-Arg-Gly)3 and negatively charged C-terminal (Glu-Hyp-Gly)3 triad extensions, respectively. CP(+) rapidly self-associates into positively charged nanosheets ba…
Ample biodegradable eggshell powder (ESP)/wheat protein isolate (WPI) composite films were made by solution casting method of altering the WPI solution and fused with ESP particles in the percentage of 5, 10, 20, 30, and 40% (w/w) and asses the properties, i.e., physical, mechanical, and thermal as a function of ESP c…
It is generally observed that the existence of geometrical discontinuity like notches in materials will lead to strength weakening, as a resultant of local stress concentration. By comparing the influence of notches to the strength of three typical materials, aluminum alloys with intermediate tensile ductility, metall…
We have developed a label-free method for sequence-specific DNA detection based on surface plasmon enhanced energy transfer (SPEET) process between fluorescent DNA/AgNC string and gold nanoparticles (AuNPs). DNA/AgNC string, prepared by a single-stranded DNA template encoded two emitter-nucleation sequences at its ter…
The goal of this study is twofold. The first one is to assess the applicability of approaches based on dynamicmechanical analysis to investigate the viscoelastic properties of a self-adhesive synthetic rubber. The second goal is to identify the parameters of a viscoelastic model which accurately represents the frequen…
Polyurethane hybrid membranes containing graphene oxide (GO) with different morphologies were prepared by in situ polymerization. The separation of CO2/N2 gas mixtures was studied using these novel membranes. The results from the morphology characterization of GO samples indicated that the oxidation process in the imp…
Energy loss due to carrier recombination is among the major factors limiting the performance of TiO2/PbS colloidal quantum dot (QD) heterojunction solar cells. In this work, enhanced photocurrent is achieved by incorporating another type of hole-transporting QDs, Zn-doped CuInS2 (Zn-CIS) QDs into the PbS QD matrix. Bi…
Discovery of fullerenes and other nanosized carbon allotropes has opened a vast new field of possibilities in nanotechnology and has become one of the most promising research areas. Carbon nanomaterials have drawn interest as carriers of biologically pertinent molecules due to their distinctive physical, chemical and…
Magnetosensitive nanocomposites on the basis of monodomain magnetite Fe3O4/meso-2,3-dimercaptosuccinic acid, Fe3O4/γ-aminopropyltriethoxysilane, Fe3O4/polyacrylamide, Fe3O4/hydroxyapatite were synthesized. Size distribution of magnetite nanoparticles in ensemble and their magnetic properties were studied. It has been…
Cassava is a type of plant which has different purposes of use. It is used to produce various foods, bio‐fibers, bio‐composites, and bio‐polymers. Besides, it is now used as renewable energy source of starch. The intention of the paper is to focus on the importance of cassava fibers, polymers, and composites as well a…
Nanovesicles self-assembled from amphiphilic peptides are promising candidates for applications in drug delivery. However, complete high-resolution data on the local and supramolecular organization of such materials has been elusive thus far, which is a substantial obstacle to their rational design. In the absence of…