Materials Literature
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Abstract The polyethylene–clay nanocomposites were prepared by the in situ graft copolymerization of styrene containing twin‐benzyldimethyldioctadecylammonium bromine modified montmorillonite (TBDO‐MMT) in polyethylene with dicumyl peroxide (DCP) as an initiator in molten state. XRD and TEM analysis indicated that int…
Abstract The thermal behavior of allyl PPO and its cured resin were investigated. In the allyl PPO curing process, the specific temperatures were T gel = 173.6°C, T cure = 225.4°C, and T treat = 237.7°C, and the activation energy ( E a ) was 122 kJ/mol. The average number of PPO molecular units between two crosslinkin…
Abstract In this study, a polymeric N ‐functionalized mutilithium ( N ‐M‐Li) compound was prepared from commercial divinylbenzene (DVB) and lithiohexamethyleneimine (LHMI), and star‐shaped copoly(styrene–butadiene–isoprene) was obtained by anionic polymerization using preformed N ‐M‐Li as initiator, tetramethylethlene…
Abstract The article deals with method of preparation, rheological properties, phase structure, and morphology of binary blend of poly(ethylene terephthalate) (PET)/poly(butylene terephthalate) (PBT) and ternary blends of polypropylene (PP)/(PET/PBT). The ternary blend of PET/PBT (PES) containing 30 wt % of PP is used…
Multiple shapes of nano- and micro-structured cystine aggregates, including spheres, rods, spindles, dendrites, and multipods, were easily synthesized just by adjusting the concentrations and pH values of L-Cysteine solutions under ultrasonic irritation. Importantly, highly monodispersed nanospheres of cystine aggrega…
Abstract The performance of acrylonitrile–butadiene–styrene (ABS) core–shell modifier with different grafting degree, acrylonitrile (AN) content, and core–shell ratio in toughening of poly(butylene terephthalate) (PBT) matrix was investigated. Results show PBT/ABS blends fracture in ductile mode when the grafting degr…
A means for synthesizing paramagnetic nanoparticles composed of an Au-Fe alloy is described using pulsed laser deposition (PLD) of the alloy into a mesoporous alumina membrane template. Nanoparticles 46 +/- 13 nm in diameter and composed of a 17% Fe alloy have been created by depositing a 35% Fe alloy into a template…
Abstract Multiple‐wavelength interferometry (MWI), a new optical method for the thermal probing of thin polymer films, is introduced and explored. MWI is compared with two standard optical methods, single‐wavelength interferometry and spectroscopic ellipsometry, with regard to the detection of the glass transition tem…
As a one-dimensional nanostructural material, carbon nanotube (CNT) has been used to build different nanoelectronic devices due to its unique electrical properties. In this paper, the infrared (IR) responses of individual single-wall carbon nanotube (SWNT) and SWNT film are studied. A single-wall carbon nanotube is as…
Abstract A novel trifluoromethyl‐containing aromatic diamine monomer, 2,5‐bis (4‐amino‐2‐trifluoromethylphenoxy)biphenyl (2), was prepared through the nucleophilic substitution reaction of 2‐chloro‐5‐nitrobenzotrifluoride and phenylhydroquinone in the presence of potassium carbonate to yield the intermediate dinitro c…
Abstract The thermal expansion properties of three commercial elastomers; Pebax®, Estane® and Hytrel® modified with 2.5–10 wt % boron nitride were investigated. The glass transition temperatures of the filled materials were relatively unaffected; however boron nitride did effectively reinforce all the three elastomers…
Abstract The objective of this study is to demonstrate the feasibility of using esterified derivatives of corncobs to clean back condensates from high‐pressure industrial boilers. Copper ions were retained by these modified natural polymers based within working pH and temperature conditions even at very low concentrat…
Abstract Montmorillonite (MMT) was modified with dodecylamine, 1,12‐diaminododecane, and 1,11‐aminoundecanoic acid to prepare CHMMT, NHMMT, and COMMT, respectively. The three clays were mixed with poly( L ‐lactide) (PLLA) with the aid of chloroform. Depending on the modifiers, PLLA/MMT composites exhibited different m…
Abstract Acrylonitrile butadiene rubber (NBR) was used as a polymeric plasticizer in poly(vinyl chloride) (PVC) for the partial replacement of di(2‐ethyl hexyl)phthalate (DEHP). The effect of this partial replacement on DEHP leaching from the PVC was evaluated at 10, 25, and 40°C. The study shows that the incorporatio…
Abstract A series of waterborne polyurethane (WPU) derived from isophorone isocyanate and poly(tetramethylene glycol) were modified by hydroxyl‐terminated polydimethylsiloxane (HPMS). The solutions were then cast into films named as PUHS. Rheological behavior of the emulsions were studied using Rheometer and morpholog…
Abstract Bahera gum, extracted from the bark of Terminalia bellerica , is a waste material. The present study involves the use of this natural gum as a multifunctional additive in natural rubber (NR) and brominated isobutylene‐ co ‐paramethyl styrene (BIMS). Fourier transform infrared (FTIR) analysis was employed to s…
Abstract To introduce N ‐methylmorpholine‐ N ‐oxide (NMMO) process to prepare antibacterial lyocell fiber, the blend films of O ‐carboxymethyl chitosan (O‐CMCS) and cellulose were prepared. O‐CMCS in aqueous suspension with particles having a surface mean diameter of 2.24 μm was blended with cellulose in NMMO hydrate.…
Abstract A hyperbranched polyethoxysiloxane was synthesized via hydrolytic polycondensation between methyltriethoxysilane (MTES) and tetraethoxysilane (TEOS), with hydrochloride acid as catalyst. FTIR, 1 H NMR, 29 Si NMR, and GPC measurements confirmed that the polyethoxysiloxane synthesized was indeed a hyperbranched…
Abstract The grafting copolymerization of maleic anhydride (MAH) onto styrene‐butadiene‐styrene terpolymer (SBS) was carried out through a new synthesis method––solvothermal synthesis. Infrared (IR) spectra and solid state 13 C‐NMR confirmed that maleic anhydride was successfully grafted onto the SBS backbone. The eff…
Abstract Neutral protease was immobilized on glutaraldehyde‐pretreated N ‐succinyl chitosan hydrogel beads and the biocatalyst obtained was used for the preparation of low molecular weight chitosan and chito‐oligomers with molecular weight of 1.9–23.5 kDa from commercial chitosan. Factors affecting the chitinolytic hy…