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Epitaxial phases ofBiMnO3from first principles

Oswaldo Diéguez、Jorge Íñiguez2015-05-28Physical Review B

${\mathrm{BiMnO}}_{3}$ is the only transition-metal perovskite oxide that is insulating and shows strong ferromagnetism in bulk. This distinctive behavior would make it a promising candidate as a magnetoelectric multiferroic if it was also a polar material, but experiments have shown that bulk ${\mathrm{BiMnO}}_{3}$ h…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Thermotropic Behavior of Syndiotactic Polymethylenes with ω-[4-(trans-4-Pentylcyclohexyl)phenoxy]alkyloxycarbonyl Side Chains

Noboru Koshimizu、Yosuke Aizawa、Koichi Sakajiri 等 7 位作者2015-05-28Macromolecules

A series of syndiotatic P5CP n polymethylenes was prepared with 4-(trans-4-pentylcyclohexyl)phenoxy moieties linked to each backbone carbon atom via an alkyloxycarbonyl spacer and with even numbers of alkyl carbons n ranging from 2 to 14, and their thermotropic behaviors were investigated. The P5CP n, except P5CP2, fo…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesConducting polymers and applications

Effects of functionalized graphene nanoplatelets on the morphology and properties of epoxy resins

Fuzhong Wang、Lawrence T. Drzal、Yan Qin 等 4 位作者2015-05-28High Performance Polymers

Graphene nanoplatelets (GnPs) were successfully functionalized with a liquid rubber, amine-terminated poly(butadiene- co-acrylonitrile) (ATBN), and the functionalized GnPs (ATBN-GnP) were characterized by microscopic and spectroscopic techniques. Different amounts of ATBN-GnP and pristine GnP were individually incorpo…

Graphene research and applicationsThermal properties of materialsFiber-reinforced polymer composites

X-ray diffraction of polycrystalline materials

C. Hammond2015-05-28OpenAlex

Abstract Chapter 10 begins by considering the geometrical basis of polycrystalline (powder) X-ray diffraction techniques, i.e. the focusing circle, focusing, and semi-focusing methods. It then considers the Bragg–Brentano semi-focusing geometry of the powder diffractometer and its applications (measurement of lattice…

X-ray Diffraction in Crystallography

Granitic Pegmatites

W.D. Sinclair2015-05-28Geological Society of America eBooks

This volume defines and summarizes in a comprehensive and systematic manner the essential characteristics of all economically significant types of Canadian mineral deposits. These summaries reflect the current understanding of mineral deposits and correspond closely to the definition of mineral-deposit types in common…

Crystal Structures and PropertiesClay minerals and soil interactionsNuclear materials and radiation effects

Investigation of Tensile and Impact of Composite Materials Reinforced with Natural Materials

Alaa A. Mohammed2015-05-28Engineering and Technology Journal

This work focuses on studying the effect of Data Seeds (DS) and Olive Seeds (OS) particles on tensile and impact properties of epoxy resin. Olive and dates seeds powder were added to epoxy matrix at weight fraction (0, 8, 13, &18 wt %) with grain size (300, 450 & 600µm). The composite specimens were prepared by Hand-L…

Natural Fiber Reinforced Composites

Practical silicon deposition rules derived from silane monitoring during plasma-enhanced chemical vapor deposition

R. Bartlomé、Stefaan De Wolf、Bénédicte Demaurex 等 6 位作者2015-05-28Journal of Applied Physics

We clarify the difference between the SiH4 consumption efficiency η and the SiH4 depletion fraction D, as measured in the pumping line and the actual reactor of an industrial plasma-enhanced chemical vapor deposition system. In the absence of significant polysilane and powder formation, η is proportional to the film g…

Thin-Film Transistor TechnologiesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence

Reduction-cleavable hyperbranched polymers with limited intramolecular cyclization via click chemistry

Heng Chen、Jiqiong Jia、Xiao Duan 等 5 位作者2015-05-28Journal of Polymer Science Part A Polymer Chemistry

In this contribution, we present new reduction-cleavable hyperbranched disulfide bonds-containing poly(ester triazole)s with limited intramolecular cyclization, which can be synthesized by the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) of A2 monomer of dipropargyl 3,3′-dithiobispropionate and B3 monomer of tri…

RNA Interference and Gene DeliveryClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

Tracking Site-Specific C–C Coupling of Formaldehyde Molecules on Rutile TiO2(110)

Ke Zhu、Yaobiao Xia、Miru Tang 等 10 位作者2015-05-28The Journal of Physical Chemistry C

Direct imaging of site-specific reactions of individual molecules as a function of temperature has been a long-sought goal in molecular science. Here, we report the direct visualization of molecular coupling of formaldehyde on reduced rutile TiO 2 (110) surfaces as we track the same set of molecules using scanning tun…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Ferroelectric polarization and defect-dipole switching in an epitaxial (111) BiFeO3 thin film

Boyuan Zhao、Zhihui Chen、Jianwei Meng 等 6 位作者2015-05-28Journal of Applied Physics

The time and field control of defect-dipole alignment as well as ferroelectric polarization switching has been investigated in an epitaxial BiFeO3 thin film. Under electric field poling, a double hysteresis loop arising from individual ferroelectric domain switching and defect dipole alignment can be artificially indu…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Influence of CdSe quantum dot on molecular/ionic relaxation phenomenon and change in physical parameters of ferroelectric liquid crystal

Dharmendra Pratap Singh、Swadesh Kumar Gupta、Shashikant Pandey 等 9 位作者2015-05-28Liquid Crystals

Spherical cadmium selenide (CdSe) quantum dots (QDs), capped with octadecylamine, dispersed in ferroelectric liquid crystal (FLC), can remarkably alter the electro-optical (E-O) parameters (material parameters) of the host compound. Here we present an E-O, dielectric, surface anchoring and fluorescence study demonstra…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Understanding Strain‐Induced Phase Transformations in BiFeO3 Thin Films

Hemant Dixit、Christianne Beekman、Christian M. Schlepütz 等 10 位作者2015-05-28Advanced Science

Experiments demonstrate that under large epitaxial strain a coexisting striped phase emerges in BiFeO 3 thin films, which comprises a tetragonal‐like ( T ′) and an intermediate S ′ polymorph. It exhibits a relatively large piezoelectric response when switching between the coexisting phase and a uniform T ′ phase. This…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Transient thermal finite element analysis of CFC–Cu ITER monoblock using X-ray tomography data

Ll.M. Evans、Lee Margetts、Valentina Casalegno 等 11 位作者2015-05-28Fusion Engineering and Design

The thermal performance of a carbon fibre composite-copper monoblock, a sub-component of a fusion reactor divertor, was investigated by finite element analysis. High-accuracy simulations were created using an emerging technique, image-based finite element modelling, which converts X-ray tomography data into micro-stru…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Physics and Applications

Machined immersion grating with theoretically predicted diffraction efficiency

Yuji Ikeda、Naoto Kobayashi、Yuki Sarugaku 等 12 位作者2015-05-28Applied Optics

An immersion grating composed of a transmissive material with a high refractive index (n>2) is a powerful device for high-resolution spectroscopy in the infrared region. Although the original idea is attributed to Fraunhofer about 200 years ago, an immersion grating with high diffraction efficiency has never been real…

Photonic and Optical DevicesOptical Coatings and GratingsSurface Roughness and Optical Measurements

Tuning the Direction of Intramolecular Charge Transfer and the Nature of the Fluorescent State in a T-Shaped Molecular Dyad

Abdellah Felouat、Anthony D’Aléo、Azzam Charaf-Eddin 等 11 位作者2015-05-28The Journal of Physical Chemistry A

Controlling photoinduced intramolecular charge transfer at the molecular scale is key to the development of molecular devices for nanooptoelectronics. Here, we describe the design, synthesis, electronic characterization, and photophysical properties of two electron donor-acceptor molecular systems that consist of tola…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Optical Activity and Dehydration-Driven Switching of Magnetic Properties in Enantiopure Cyanido-Bridged CoII3WV2 Trigonal Bipyramids

Szymon Chorąży、Robert Podgajny、Wojciech Nogaś 等 12 位作者2015-05-28Inorganic Chemistry

The unique enantiopure {[Λ-Co(II)((R)-mpm)2]3[W(V)(CN)8]2}·9H2O [(R)-1] and {[Δ-Co(II)((S)-mpm)2]3[W(V)(CN)8]2}·9H2O [(S)-1], where mpm = α-methylpyridinemethanol, magnetic spongelike materials, crystallizing in the chiral P21 space group, are constructed of cyanido-bridged {Co3W2} trigonal bipyramids with three cis-[…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Nucleation and temperature-driven phase transitions of silicene superstructures on Ag(1 1 1)

Carlo Grazianetti、Daniele Chiappe、Eugenio Cinquanta 等 5 位作者2015-05-28Journal of Physics Condensed Matter

Silicene grown on Ag(1 1 1) is characterized by several critical parameters. Among them, the substrate temperature plays a key role in determining the morphology during growth. However, an unexpected important role is also equally played by the post-deposition annealing temperature which determines the self-organizati…

Graphene research and applicationsTopological Materials and PhenomenaSynthesis and Properties of Aromatic Compounds

Gate-tunable valley-spin filtering in silicene with magnetic barrier

Xiuqiang Wu、Hao Meng2015-05-28Journal of Applied Physics

We theoretically study the valley- and spin-resolved scattering through magnetic barrier in a one layer thick silicene, using the mode-matching method for the Dirac equation. We show that the spin-valley filtering effect can be achieved and can also be tuned completely through both a top and bottom gate. Moreover, whe…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Mode I fracture toughness of bio-fiber and bio-shell particle reinforced epoxy bio-composites

Prakash Chandra Gope、Vinay K. Singh、Dinesh Kumar Rao2015-05-28Journal of Reinforced Plastics and Composites

The effect of bio-fibres and bio-particles on the fracture toughness has been investigated. Epoxy resin is used as matrix material and different bio-fibers such as banana fiber, bagasse fiber, coconut fiber and particles such as silica and walnut shell particle with different wt% are added as reinforcing material. The…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesMechanical Engineering and Vibrations Research

Luminescent Nanofibers Fabricated from Phenanthroimidazole Derivatives by Organogelation: Fluorescence Response towards Acid with High Performance

Jiang Peng、Jingbo Sun、Peng Gong 等 7 位作者2015-05-28Chemistry - An Asian Journal

Nanofibers based on phenanthroimidazole derivatives PCC, PDC, and PSC were fabricated by organogelation processes, and their fluorescence sensory properties towards acid were investigated. It was found that the emission of PCC in the nanofiber-based film could be quenched significantly upon exposure to gaseous TFA due…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications