Materials Literature
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DFT investigations have been carried out on the hydrogen evolution reaction (HER) mechanism followed by [NiFe] hydrogenases. Calculations on the active site of the [NiFe] hydrogenase from Desulfovibrio vulgaris str. “Miyazaki F” reveal that H 2 is formed as the final product through the “singlet multiplicity” pathway.…
An (Au/Ti)/Al2O3/n-GaAs structure with thin (30 ) interfacial oxide layer (Al2O3), formed by atomic layer deposition technique is fabricated to investigate both frequency and applied bias voltage dependences of real and imaginary parts of dielectric constant ( and ) and electric modulus (M and M ), loss tangent tan an…
This paper considers features of processing of machinery parts for the workability during the transition to new construction materials (in particular polymer composite materials). It describes the qualitative and quantitative methods for assessing the workability of designs.
We report the linear and nonlinear optical properties of single GaAs nanowires with polytypism effect. Electron transmission microscopy experiments show that the nanowires contain wurtzite segments as well as zinc blende segments with two different crystallographic orientations. Time-resolved photoluminescence spectro…
Current use of decellularized articular cartilage as a regenerative platform suffers from limited implant diffusion characteristics and cellular infiltration. Attempts to address this concern using decellularized cartilage microparticles allow for customized implant shape, tailored porosity, and improved cell infiltra…
The use of very high voltage power modules (> 10 kV) requires the implementation of appropriate structures for the device packaging. Particularly the triple point between the insulating substrate, the metallization and the encapsulation is subjected to strong electric field stress. A novel architecture is proposed for…
We observe magnetic domain structures of MgO/CoFeB with a perpendicular magnetic easy axis under an electric field. The domain structure shows a maze pattern with electric-field dependent isotropic period. The analysis of the period indicates a major role of the electric-field modulation of interfacial magnetic anisot…
In this research, the drying rates of ground chip and ground pellet particles of pine were investigated. Pulp wood chips and whole pellets were ground in a hammer mill. Grinder screens with perforations 3.2, 6.3, 12.7, and 25.4 mm were installed in the hammer mill to produce a range of ground particle sizes. Particle…
The Cosmetic Ingredient Review (CIR) Expert Panel assessed the safety of 131 alkyl polyethylene glycol (PEG)/polypropylene glycol ethers as used in cosmetics, concluding that these ingredients are safe in the present practices of use and concentration described in this safety assessment when formulated to be nonirrita…
This paper analyzes the feasibility of applying model predictive control strategies for mitigation of the auto-ignition phenomenon, which affects the performance of spark-ignition internal combustion engines. The first part of this paper shows the implementation and experimental validation of a two-dimensional model,…
Nonlinear guided waves have been investigated widely in simple geometries, such as plates, pipe and shells, where analytical solutions have been developed. This paper extends the application of nonlinear guided waves to waveguides with arbitrary cross sections. The criteria for the existence of nonlinear guided waves…
In this work, we report on the spontaneous formation of ordered arrays of nanometer-sized Bi-rich structures due to lateral composition modulations in Ga(As,Bi)/GaAs quantum wells grown by molecular beam epitaxy. The overall microstructure and chemical distribution is investigated using transmission electron microscop…
The optical performance and relevant physical properties of near-ultraviolet (NUV) GaN-based light-emitting diodes (LEDs) are investigated. Specifically, the influence of traditional AlGaN bulk electron blocking layer (EBL) and AlGaN/GaN superlattice (SL) EBL with various thicknesses of AlGaN layers on NUV LEDs is exp…
The design and synthesis of Aviram-Ratner-type molecular rectifiers, featuring an anilino-substituted extended tetracyanoquinodimethane (exTCNQ) acceptor, covalently linked by the σ-spacer bicyclo[2.2.2]octane (BCO) to a tetrathiafulvalene (TTF) donor moiety, are described. The rigid BCO spacer keeps the TTF donor and…
We report the abnormal behavior of the threshold voltage (VTH) shift under positive bias Temperature stress (PBTS) and negative bias temperature stress (NBTS) at top/bottom gate in dual gate amorphous indium-gallium-zinc-oxide (a-IGZO) thin-film transistors (TFTs). It is found that the PBTS at top gate shows negative…
This work targets the area selective atomic layer deposition (AS-ALD) of TiN onto HfO 2 for use as the word line in a memory device. Unlike other patterning processes, AS-ALD eliminates etching steps and also allows for growth of patterned films with precise thickness control. This study investigates how AS-ALD differ…
Raman spectroscopic data were obtained for (Mg,Fe) 2 SiO 4 samples during compression to 57 GPa. Single crystals of San Carlos olivine compressed hydrostatically above 41 GPa showed appearance of a new “defect” peak in the 820–840 cm –1 region associated with SiOSi linkages appearing between adjacent SiO44−${\rm{SiO}}…
For describing hypervelocity impact (relative low-speed as related to space debris and much lower than travelling speed of meteoroids) phenomenon associated with plasma generation, a self-developed 3D code was advanced to numerically simulate projectiles impacting on a rigid wall. The numerical results were combined w…
AIM: To develop a safe and efficient method for targeted, anti-apoptotic gene therapy of corneal endothelial cells (CECs). MATERIALS & METHODS: Magnetofection (MF), a combination of lipofection with magnetic nanoparticles (MNPs; PEI-Mag2, SO-Mag5, PalD1-Mag1), was tested in human CECs and in explanted human corneas. E…
Ion-exchange membranes (IEMs) have been used in different processes and applications and have shown the advantages over other comparative processes. The extensive applications of IEMs in many areas have necessitated the improvement in their properties to achieve better performance and lower cost. As the first commerci…