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Compatibilized blends of thermoplastic polyurethane (TPU) and polypropylene

LU Qi-wei、Christopher W. Macosko、J. Horrion2003-08-01Macromolecular Symposia

Abstract Compatibilized blends of thermoplastic polyurethane (TPU) and polypropylene (PP) were developed using amine (primary or secondary) functionalized PP's (PP‐g‐NH 2 or PP‐g‐NHR). The strategy of reactive compatibilization is based on fast reactions between amine functional groups and urethane linkages or traces…

Polymer composites and self-healingSynthesis and properties of polymersSilicone and Siloxane Chemistry

A Comparative Investigation of Structure and Bonding in Mo and W [TeM6O24]6-and [PM12O40]3-Heteropolyanions

Adam J. Bridgeman、Germán Cavigliasso2003-08-01The Journal of Physical Chemistry A

The structure and bonding in [TeM 6 O 24 ] 6- (Anderson) and [PM 12 O 40 ] 3- (α-Keggin) heteropolyanions have been investigated by density-functional methods. Various molecular-orbital and population approaches have been employed in the analysis of the structural and electronic properties. Good agreement between comp…

Polyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysisVanadium and Halogenation Chemistry

Dove prism with increased throughput for implementation in a rotational-shearing interferometer

Iván Moreno、Гонзало Паез、Marija Strojnik2003-08-01Applied Optics

An analytical expression is derived for the tilt introduced into a wave front by a Dove prism with manufacturing errors in the prism's base angles and pyramidal angle. We found that the tilt decreases when the base angles are increased above the values of traditional design. The increase in the length-aperture ratio o…

Photonic and Optical DevicesOptical measurement and interference techniquesOptical Coatings and Gratings

Four glycosides from the leaves of Abeliophyllum distichum with inhibitory effects on angiotensin converting enzyme

Hyuncheol Oh、Dae-Gill Kang、Tae‐Oh Kwon 等 8 位作者2003-08-01Phytotherapy Research

The bioassay-guided fractionation of the n-BuOH extract of Abeliophyllum distichum afforded acteoside (1), isoacteoside (2), rutin (3), and hirsutrin (4). Compounds 1-3 moderately inhibited the angiotensin I converting enzyme activity in a dose-dependent manner. Compounds 1-3 showed the 50% inhibitory concentration va…

Phytochemistry and Biological ActivitiesTraditional and Medicinal Uses of AnnonaceaePhytochemistry and Bioactive Compounds

Occurrence, Prediction, and Prevention of Zinc Sulfide Scale Within Gulf Coast and North Sea High-Temperature and High-Salinity Fields

I. R. Collins、M. M. Jordan2003-08-01SPE Production & Facilities

Summary In oil and gas production operations, precipitation of mineral scales causes many problems, such as formation damage, production losses, increased workovers in both producers and injectors, poor injection-water quality, and equipment failures caused by underdeposit corrosion. The most common mineral scales are…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesMine drainage and remediation techniques

Pt and Pt2 on MgO(100) and BaO(100): structure, bonding, and chemical properties

Henrik Grönbeck、Peter Broqvist2003-08-01The Journal of Chemical Physics

The density functional theory has been applied to study the interaction of platinum (atoms, dimers, and layers with equal number of platinum atoms as oxygen surface atoms) with the (100) surfaces of MgO and BaO. The systems are characterized with respect to preferred geometrical configurations and electronic structure…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Molecular and Microdomain Orientation in Semicrystalline Block Copolymer Thin Films by Directional Crystallization of the Solvent and Epitaxy

Cheolmin Park、Claudio De Rosa、Bernard Lotz 等 5 位作者2003-08-01Macromolecular Chemistry and Physics

Abstract The directional crystallization of crystallizable organic solvents and the subsequent epitaxial crystallization of crystalline blocks onto the surface of crystalline substrates in semicrystalline block copolymers, control both molecular chain orientation of the crystalline block and the microdomain structure…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Alteration of Chain Length Substrate Specificity of Aeromonas caviae R -Enantiomer-Specific Enoyl-Coenzyme A Hydratase through Site-Directed Mutagenesis

Takeharu Tsuge、Tamao Hisano、Seiichi Taguchi 等 4 位作者2003-08-01Applied and Environmental Microbiology

Aeromonas caviae R-specific enoyl-coenzyme A (enoyl-CoA) hydratase (PhaJ(Ac)) is capable of providing (R)-3-hydroxyacyl-CoA with a chain length of four to six carbon atoms from the fatty acid beta-oxidation pathway for polyhydroxyalkanoate (PHA) synthesis. In this study, amino acid substitutions were introduced into P…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Consequence of Intermittent Exposure to Moisture and Salt Fog on the High‐Temperature Fatigue Durability of Several Ceramic‐Matrix Composites

Larry P. Zawada、James M. Staehler、Steve Steel2003-08-01Journal of the American Ceramic Society

Fatigue behavior of four ceramic‐matrix composites (CMCs) was documented at 1000°C, and a fifth composite was documented at 1200°C. Additional fatigue specimens were cycled for set blocks of cycles, removed from the fatigue machine, and exposed in a cyclic corrosion tester for 24 h with a fog of deionized water and a…

Advanced ceramic materials synthesisThermal properties of materialsAdvanced materials and composites

Protection of plants from frost using hydrophobic particle film and acrylic polymer

Michael P. Fuller、Faisal Hamed、Michael Wisniewski 等 4 位作者2003-08-01Annals of Applied Biology

Summary Frost damage to potatoes, grapevine and citrus plants was assessed following treatment with either an acrylic polymer (Antistress™) or with a hydrophobic particle film (CM‐96–018). In large freezing tests, the application of the hydrophobic particle film consistently led to less damage whilst the acrylic polym…

Surface Modification and SuperhydrophobicityPlant Surface Properties and TreatmentsTurfgrass Adaptation and Management

Direct observation of confined states in metallic single-walled carbon nanotubes

Theophilos Maltezopoulos、André Kubetzka、Markus Morgenstern 等 6 位作者2003-08-01Applied Physics Letters

We investigated the local density of states (LDOS) of extended individual metallic single-walled carbon nanotubes using low-temperature scanning tunneling spectroscopy. We observed that the LDOS oscillates with energy close to the Fermi level. The oscillation period of about 50 meV varies with position on the nanotube…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Delivery of an anticancer drug and a chemosensitizer to murine breast sarcoma by intratumoral injection of sulfopropyl dextran microspheres

Zhi Liu、James R. Ballinger、Andrew M. Rauth 等 5 位作者2003-08-01Journal of Pharmacy and Pharmacology

Intratumoral injection of controlled-release microsphere formulations of anticancer compounds has the potential to selectively increase tumour exposure to drugs. This work aimed to evaluate the therapeutic effect and toxicity of microsphere formulations containing the anticancer drug, doxorubicin, in a murine tumour m…

Nanoparticle-Based Drug DeliveryDrug Transport and Resistance MechanismsRNA Interference and Gene Delivery

SEM Observations of the Fractured Surfaces of Coir Composites

J. Rout、Manjusri Misra、Amar K. Mohanty 等 5 位作者2003-08-01Journal of Reinforced Plastics and Composites

Coir composites had been prepared using coir fiber (both continuous and short fiber) as reinforcement with both thermosetting and thermoplastics as matrices. The composite specimens were prepared using both untreated and chemically modified such as defatted, PMMA grafted, PAN grafted and cyanoethylated coir fibers. Co…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical Applications

Chemistry of Mg Smectites in Lacustrine Sediments from the Vicalvaro Sepiolite Deposit, Madrid Neogene Basin (Spain)

Jaime Cuevas、R. Vigil de la Villa、Susana Ramirez 等 6 位作者2003-08-01Clays and Clay Minerals

Abstract The chemical and structural properties of Mg smectites in the Vicálvaro sepiolite deposit have been studied in detail. The characterization was performed on different size-fractions of selected smectitic samples (5−2 µm; 2−1 µm; 1−0.5 µm; <0.5 µm and <0.1 µm). The chemical compositions of individual par…

Clay minerals and soil interactionsIron oxide chemistry and applicationsTherapeutic Uses of Natural Elements

Titanium coordination in silicate glasses investigated using O K-edge X-ray absorption spectroscopy

Grant S. Henderson、Xiaoyang Liu、Michael E. Fleet2003-08-01Mineralogical Magazine

Abstract A series of titanium silicate glasses along the composition joins TiO 2 -SiO 2 , TiO 2 -Na 2 SiO 3 , TiO 2 -K 2 SiO 3 and TiO 2 -CaSiO 3 , has been examined using oxygen K -edge X-ray absorption near edge structure spectroscopy (XANES) confined to the near-surface region. Sharp pre-edge features in the spectr…

Glass properties and applicationsX-ray Spectroscopy and Fluorescence AnalysisNuclear materials and radiation effects

Geometric and electronic structure ofTi2AlX(X=V,Nb,orTa)

Qing‐Miao Hu、Rong Yang、Dongdong Xu 等 6 位作者2003-08-01Physical review. B, Condensed matter

Using a first-principles plane-wave pseudopotential method, the geometric and electronic structures of ${\mathrm{Ti}}_{2}\mathrm{Al}X$ $(X=V,$ Nb, or Ta) are investigated. The supercells of ${\mathrm{Ti}}_{2}\mathrm{Al}X$ are constructed by replacing certain Ti atoms in ${\ensuremath{\alpha}}_{2}\ensuremath{-}{\mathrm…

Intermetallics and Advanced Alloy PropertiesBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Futile Cycling of Intermediates of Fatty Acid Biosynthesis toward Peroxisomal β-Oxidation in Saccharomyces cerevisiae

Silvia Marchesini、Yves Poirier2003-08-01Journal of Biological Chemistry

The flux of fatty acids toward beta-oxidation was analyzed in Saccharomyces cerevisiae by monitoring polyhydroxyalkanoate synthesis in the peroxisome from the polymerization, by a bacterial polyhydroxyalkanoate synthase, of the beta-oxidation intermediates 3-hydroxyacyl-CoAs. Synthesis of polyhydroxyalkanoate was depe…

biodegradable polymer synthesis and propertiesPeroxisome Proliferator-Activated ReceptorsBiochemical Acid Research Studies

Chemical Resistance and Tensile Properties of Epoxy/Unsaturated Polyester Blend Coated Bamboo Fibers

A. Varada Rajulu、L. Ganga Devi、G. Babu Rao 等 4 位作者2003-08-01Journal of Reinforced Plastics and Composites

The untreated and 2%aqueous NaOH treated bamboo fibers (Dendrocalamus strictus) were coated with epoxy, unsaturated polyester (UP) and their blends. The chemical resistance of these fibers to acetic acid, nitric acid, hydrochloric acid, sodium hydroxide, ammonium hydroxide, sodium carbonate, benzene, toluene, carbon t…

Natural Fiber Reinforced CompositesTextile materials and evaluationsBamboo properties and applications

Structure-mesomorphism relationship in terminally functionalised liquid crystal dendrimers

Mercedes Marcos、Ana Omenat、José Luís Serrano2003-08-01Comptes Rendus Chimie

We have carried out a study on the supramolecular liquid crystal organisation shown by LC dendrimers. This study has allowed us to draw interesting conclusions about the molecular plasticity of this type of dendromesogens and even to predict the mesogenic behaviour of higher generations of homologous dendrimers or sim…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

Ohmic Contact Formation for N-Type Diamond by Selective Doping

Tokuyuki Teraji、Masayuki Katagiri、Satoshi Koizumi 等 5 位作者2003-08-01Japanese Journal of Applied Physics

Ohmic contacts with low contact resistivity were formed on phosphorus-doped n -type {111} diamond thin films grown by microwave-plasma chemical-vapor deposition. Heavily-doped diamond layers were selectively grown on a diamond substrate by covering a part of substrate surface with a titanium/gold layer. Gold contacts…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research