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Improved light absorbance does not lead to better DSC performance: studies on a ruthenium porphyrin–terpyridine conjugate

Angelo Lanzilotto、Laura A. Büldt、Hauke C. Schmidt 等 7 位作者2016-01-01RSC Advances

Despite having a good spectral response, a bis(tpy)ruthenium complex with peripheral porphyrin and phosphonate anchoring domains gives poor photoconversion efficiency due to a triplet–triplet energy transfer process.

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesPorphyrin and Phthalocyanine Chemistry

The Interaction Potential of an Open Nanotube and its Permeability: Molecular Dynamics Simulation

M. A. Bubenchikov、А. И. Потекаев、Alexey M. Bubenchikov 等 6 位作者2016-01-01EPJ Web of Conferences

The integration of the modified LJ-potential allowed revealing the universal effect of the open carbon tube on the molecular objects moving within or proximate to the tube. There has been established that there are modes of the molecule motion without the energy exchange with the atoms of the carbon framing, under whi…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

High-temperature heat capacity and thermodynamic properties of pyrovanadate Pb2V2O7 and orthovanadate Pb3(VO4)2

Л. Т. Денисова、А. Д. Изотов、L. A. Irtyugo 等 6 位作者2016-01-01Doklady Physical Chemistry

The heat capacities of Pb2V2O7 and Pb3(VO4)2 as a function of temperature in the range 350–965 K have been studied by the differential scanning calorimetry method. The C P = f(T) curve for Pb2V2O7 is described by the equation C p = (230.76 ± 0.51) + (73.60 ± 0.50)×10-3 T − (18.38 ± 0.54)×105 T -2 in the entire tempera…

Luminescence Properties of Advanced MaterialsCatalysis and Oxidation ReactionsChemical Thermodynamics and Molecular Structure

Metallogels through glyme coordination

W. Scott Compel2016-01-01Dalton Transactions

Glyme intercalation in copper-thiolate polymers is studied. The amorphous polymer network observed is significantly stronger than previously reported coinage metal-thiolate supramolecular hydrogels synthesized without glyme. Glyme chain length and water content strongly influence mechanical and optical behavior.

Gold and Silver Nanoparticles Synthesis and ApplicationsSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications

Controlled synthesis of hollow Si–Ni–Sn nanoarchitectured electrode for advanced lithium-ion batteries

Ke Wang、Ying Huang、Duo Wang 等 7 位作者2016-01-01RSC Advances

The hollow Si–Ni–Sn nanospheres with porous and hollow microspheric structure were fabricated via a versatile template synthesis approach followed by an in situ chemical reaction, and directly used as an anode material for lithium-ion batteries.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationSemiconductor materials and interfaces

The Efficacy of Iranian Traditional and Folk Medicinal Plants for Some Gastroduodenal Disorders

Maliheh Safavi、Mohammad Reza Shams-Ardakani、Maryam Sadat-Seyedbagheri 等 4 位作者2016-01-01DOAJ (DOAJ: Directory of Open Access Journals)

Peptic ulcer and gastritis are common and universal disease which affect up to 50% of the world’s adult population. Helicobacter pylori is a major cause of chronic-active gastritis and primary duodenal ulcers, and is strongly linked to gastric cancer. H. pylori induce chronic gastritis in virtually all infected patien…

Helicobacter pylori-related gastroenterology studiesPhytochemistry and Bioactive CompoundsPhytochemistry and biological activities of Ficus species

Magnetic structure of (C 5 H 12 N)CuBr 3 : origin of the uniform Heisenberg chain behavior and the magnetic anisotropy of the Cu 2+ (S = 1/2) ions

Changhoon Lee、Jisook Hong、Won‐Joon Son 等 6 位作者2016-01-01RSC Advances

The AFM chain behavior observed for (pipH)CuBr 3 is not caused by the CuBr 3 chains, but by the interchain exchanges leading to two-leg spin ladders. The Cu 2+ ions have easy-axis anisotropy, and this arises largely from the SOC of the Br − ligands.

Magnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsOrganic and Molecular Conductors Research

Facile evaluation of the crystallization of nano-ZSM-5 using diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy and multivariate curve resolution-alternating least squares

Mohammadreza Khanmohammadi、Sh. Amani、Amir Bagheri Garmarudi2016-01-01Analytical Methods

Nano-crystal ZSM-5 was fabricated through the reflux crystallization method under atmospheric pressure and the crystallization evolutionary process was investigated utilizing DRIFT spectroscopy.

Spectroscopy and Chemometric AnalysesAdvanced Chemical Sensor TechnologiesCrystallization and Solubility Studies

Inducing LTD-Like Effect in the Human Motor Cortex with Low Frequency and Very Short Duration Paired Associative Stimulation: An Exploratory Study

Prachaya Srivanitchapoom、Jung E. Park、Nivethida Thirugnanasambandam 等 8 位作者2016-01-01Neural Plasticity

Introduction. Paired associative stimulation (PAS) is an established technique to investigate synaptic plasticity in the human motor cortex (M1). Classically, to induce long-term depression- (LTD-) or long-term potentiation-like effects in the human M1, studies have used low frequency and long duration trains of PAS.…

Transcranial Magnetic Stimulation StudiesConducting polymers and applicationsNeuroscience and Neural Engineering

Surface activation of CNT Webs towards layer by layer assembly of biosensors

Mustafa Musameh、Chi Huynh、Mark Hickey 等 4 位作者2016-01-01The Analyst

Several surface activation methods such as chemical, electrochemical and plasma have been used for enhancing the electrochemical performance of carbon based electrodes for various applications. However, some of these surface activation methods may not be useful depending on the chemical and physical properties of the…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Eulerian--Lagrangian Treatment of Nondilute Two-Phase Gels

Víctor Fuentes Camacho、Aaron L. Fogelson、James P. Keener2016-01-01SIAM Journal on Applied Mathematics

We develop a three-dimensional Eulerian--Lagrangian two phase mixture model for a gel in which fluid is represented in Eulerian coordinates and network in Lagrangian coordinates. The equations of motion and boundary conditions in their respective frames are derived using a principle of virtual power. The volume fracti…

Solidification and crystal growth phenomenaRheology and Fluid Dynamics StudiesLattice Boltzmann Simulation Studies

Continuous polycrystalline silicon layers on glass grown from tin solutions

Roman Bansen、Christian Ehlers、Th. Teubner 等 6 位作者2016-01-01CrystEngComm

Polycrystalline silicon on glass for photovoltaic applications is grown at low temperatures in a two-step process.

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

In situ synthesized single-crystalline LiMn 2 O 4 embedded in carbon nanotube films as free-standing cathodes for Li-ion batteries

Zhiyu Wang、Jianli Cheng、Xiaodong Li 等 6 位作者2016-01-01RSC Advances

Single-crystalline octagonal LiMn 2 O 4 nanoparticles embedded in a carbon nanotube film are synthesized and used as a binder-free and self-standing cathode for lithium ion batteries.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Growth, structure, and properties of GaAs-based (GaAs)1–x–y (Ge2) x (ZnSe) y epitaxial films

S.Z. Zaynabidinov、А. С. Саидов、A. Yu. Leĭderman 等 7 位作者2016-01-01Semiconductors

The possibility of growing the (GaAs)1–x–y (Ge2) x (ZnSe) y alloy on GaAs substrates by the method of liquid-phase epitaxy from a tin solution–melt is shown. X-ray diffraction shows that the grown film is single-crystal with the (100) orientation and has the sphalerite structure. The crystal-lattice parameter of the f…

Semiconductor Quantum Structures and DevicesPhase-change materials and chalcogenidesSemiconductor materials and interfaces

Study on the Machinability Characteristics of Ti2AlNb Based Alloy in Turning with Coated Cemented Carbide Tools

Bing Bai、Hong Hua Su、Lin He 等 5 位作者2016-01-01Materials science forum

As a new type of material, Ti2AlNb based alloy has a broad application prospects in aerospace field due to its excellent properties such as low density, high specific strength at elevated temperature, excellent oxide and creep resistance. Many studies involving its material composition and structural properties have b…

Metal and Thin Film MechanicsIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Encapsulation of Platinum Complex of Indole-7-Carbaldehyde Thiosemicarbazone, Pt(L)(PPh3) into Nanolipid Carrier for Sustain Released Anti-Cancer Treatment

Tiew Shu Xian、Woo Juin Onn、Misni Misran 等 4 位作者2016-01-01Materials Today Proceedings

Pt(L)(PPh 3 ) which possess significant cytotoxicity towards cancer cell lines was encapsulated in NLC prepared by melt-emulsification technique. Increase in particles size with decreasing zeta potential of nanolipid was observed when the drug amount in the formulation was increased, which is in agreement with the inc…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvancements in Transdermal Drug DeliveryProtein Interaction Studies and Fluorescence Analysis

Validation of MCNP NPP Activation Simulations for Decommissioning Studies by Analysis of NPP Neutron Activation Foil Measurement Campaigns

Ben Volmert、Manuel Pantelias、R.K. Mutnuru 等 5 位作者2016-01-01EPJ Web of Conferences

In this paper, an overview of the Swiss Nuclear Power Plant (NPP) activation methodology is presented and the work towards its validation by in-situ NPP foil irradiation campaigns is outlined. Nuclear Research and consultancy Group (NRG) in The Netherlands has been given the task of performing the corresponding neutro…

Nuclear reactor physics and engineeringNuclear Physics and ApplicationsGraphite, nuclear technology, radiation studies

Medium bandgap copolymers based on carbazole and quinoxaline exceeding 1.0 V open-circuit voltages

Kyu Cheol Lee、Taehyo Kim、Seyeong Song 等 8 位作者2016-01-01RSC Advances

Given the desire for superior VOC values in PSCs, we have designed and synthesized a series of ‘medium bandgap’ donor–acceptor (D–A) copolymers containing carbazole (Cz) and quinoxaline (Qx) ( PCzDT-Qx , PCzDT-fQx , and PCzDT-ffQx ).

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications