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STXM Characterization of PEM Fuel Cell Catalyst Layers

Darija Susac、Viatcheslav Berejnov、Adam P. Hitchcock 等 4 位作者2013-03-15ECS Transactions

The synchrotron based scanning transmission soft X-ray microscopy (STXM) utilizing near edge X-ray absorption fine structure (NEXAFS) is a novel technique for characterization of membrane electrode assembly (MEA) components in proton exchange membrane fuel cells (PEMFC). Component maps for carbon support, Pt and ionom…

Advanced Electron Microscopy Techniques and ApplicationsMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Reversibly Slowing Dewetting of Conjugated Polymers by Light

Ioan Botiz、Paul Freyberg、Natalie Stingelin 等 5 位作者2013-03-15Macromolecules

Dewetting, i.e., the retraction of a fluid from a surface it “dislikes”, is a macroscopic phenomenon controlled through parameters like viscosity and surface tension on length-scales much larger than the size of the molecules. So far, dewetting was known to proceed in the same manner, independent of the dewetting film…

Material Dynamics and PropertiesBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Spatial Pattern of Benthic Diatoms and Water Quality Assessment Using Diatom Indices in a Subtropical River, China

Xiang Tan、Peiming Ma、Xiaoling Xia 等 4 位作者2013-03-15CLEAN - Soil Air Water

Abstract Benthic algae including benthic diatoms are one of the most vital primary producers in riverine ecosystems, and their spatial distribution and assemblage structure respond sensitively to various environmental variables. Thus, benthic diatoms have been widely used as indicators of water quality in riverine sys…

Aquatic Ecosystems and Phytoplankton DynamicsFreshwater macroinvertebrate diversity and ecologyDiatoms and Algae Research

Photoluminescent Gold Nanoclusters as Sensing Probes for Uropathogenic Escherichia coli

Po-Han Chan、Bhaswati Ghosh、Hong‐Zheng Lai 等 6 位作者2013-03-15PLoS ONE

Glycan-bound nanoprobes have been demonstrated as suitable sensing probes for bacteria containing glycan binding sites. In this study, we demonstrated a facile approach for generating glycan-bound gold nanoclusters (AuNCs). The generated AuNCs were used as sensing probes for corresponding target bacteria. Mannose-capp…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Thermochemistry of Barium Hollandites

Gustavo Costa、Hongwu Xu、Alexandra Navrotsky2013-03-15Journal of the American Ceramic Society

Barium hollandites, a family of framework titanates that can potentially be used for the immobilization of short‐lived fission products (especially 137 Cs ) in radioactive wastes, have been investigated by high‐temperature oxide melt solution calorimetry using 2 PbO · B 2 O 3 solvent at 702°C. The enthalpies of format…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

Preparation and Luminescence Properties of Blue‐emitting Phosphor Ba 2 Ca ( PO 4 ) 2 : Eu 2+

Yuanyuan Zhang、Zhiguo Xia、Weiwei Wu2013-03-15Journal of the American Ceramic Society

Using the conventional high temperature solid‐state reaction method Ba 2 Ca ( PO 4 ) 2 : Eu 2+ phosphors were prepared. The phase structure, photoluminescence ( PL ) properties, and the PL thermal stability of the samples were investigated, respectively. Under the excitation at 365 nm, the phosphor exhibited an asymme…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsRadiation Detection and Scintillator Technologies

Controlled Preparation of Uniform TiO2-Catalyzed Silver Nanoparticle Films for Surface-Enhanced Raman Scattering

Dawei Li、Lujun Pan、Shuai Li 等 6 位作者2013-03-15The Journal of Physical Chemistry C

Silver nanoparticle (AgNP) film is a kind of useful material in biochemical and biomedical fields as it can be used as a sensor based on its surface plasmon resonance for surface enhanced Raman scattering (SERS) analysis. In this work, a uniform AgNP film with controlled nanoparticle size, shape, and density have been…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Comparison of Channeling Contrast between Ion and Electron Images

L. A. Giannuzzi、Joseph R. Michael2013-03-15Microscopy and Microanalysis

Ion channeling contrast (iCC) and electron channeling contrast (eCC) are caused by variation in signal resulting from changes in the angle of the incident beam and the crystal lattice with respect to the target. iCC is directly influenced by the incident ion range in crystalline materials. The ion range is larger for…

Nuclear Physics and ApplicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Molecular Orbitals Strictly Localized on Small Molecular Fragments from X-ray Diffraction Data

Alessandro Genoni2013-03-15The Journal of Physical Chemistry Letters

Nowadays, the electron density is recognized as a fundamental property that contains most of the information concerning the electronic structure of molecules, and, therefore, its determination from high-resolution X-ray diffraction data is becoming more and more important. In this context, we propose a new strategy fo…

Crystallography and molecular interactionsX-ray Diffraction in CrystallographyChemical Thermodynamics and Molecular Structure

Investigation of skutterudite MgyCo4Sb12: High pressure synthesis and thermoelectric properties

Jianqing Yang、Long Zhang、Yadi Liu 等 10 位作者2013-03-15Journal of Applied Physics

The filling behavior of Mg atoms into CoSb3 lattice voids under pressure was investigated theoretically, revealing ambient-pressure-inaccessible Mg-filled CoSb3 can be stabilized under high pressure. Inspired by this result, we synthesized Mg-filled CoSb3 using high pressure synthesis. The synthetic samples show Im3¯…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsThermal properties of materials

Novel metastable metallic and semiconducting germaniums

Daniele Selli、Igor A. Baburin、Roman Martoňák 等 4 位作者2013-03-15Scientific Reports

Group-IVa elements silicon and germanium are known for their semiconducting properties at room temperature, which are technologically critical. Metallicity and superconductivity are found at higher pressures only, Ge β-tin (tI4) being the first high-pressure metallic phase in the phase diagram. However, recent experim…

Diamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials ResearchSemiconductor materials and interfaces

A review of fabric tactile properties and their subjective assessment for next-to-skin knitted fabrics

T.J. Mahar、H. Wang、R. Postle2013-03-15Journal of the Textile Institute

A review of studies is presented in the evaluation of fabric tactile properties with a focus on knitted fabrics and developments since the mid-1990s in particular. The fundamental differences in structure between woven and knitted fabrics are highlighted with their consequent different fabric tactile properties. Consi…

Textile materials and evaluationsIndustrial Vision Systems and Defect DetectionColor perception and design

Morphology, Microstructure, and Magnetic Properties of Ordered Large-Pore Mesoporous Cadmium Ferrite Thin Film Spin Glasses

Christian Reitz、Christian Suchomski、Venkata Sai Kiran Chakravadhanula 等 6 位作者2013-03-15Inorganic Chemistry

Herein, we report the synthesis, microstructure, and magnetic properties of cadmium ferrite (CdFe2O4) thin films with both an ordered cubic network of 18 nm diameter pores and single-phase spinel grains averaging 13 nm in diameter. These mesoporous materials were produced through facile polymer templating of hydrated…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Nanoparticles: An Overview

Davinder Singh Khatra、S L Harikumar、Nirmala Nirmala2013-03-15Journal of Drug Delivery and Therapeutics

Nanoparticles are the preparations having size in nanometers. Particulate systems like nanoparticles have been used as a physical approach to alter and improve the pharmacokinetic and pharmacodymanic properties of various types of drug molecules.They have been used in vivo to protect the drug entity in the systemic c…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsCancer Research and Treatment

Optical Properties of a Particle above a Dielectric Interface: Cross Sections, Benchmark Calculations, and Analysis of the Intrinsic Substrate Effects

J. Lermé、Christophe Bonnet、M. Broyer 等 6 位作者2013-03-15The Journal of Physical Chemistry C

We show that the optical properties of a particle above a plane dielectric interface differ dramatically from those of the same particle embedded in a homogeneous matrix. Calculations for gold and silver spheres have been carried out in using the exact multipole expansion method, providing thus benchmark results for t…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchOptical Coatings and Gratings

The effect of atmospheric tarnishing on the optical and structural properties of silver nanoparticles

T. W. H. Oates、María Losurdo、Suguru Noda 等 4 位作者2013-03-15Journal of Physics D Applied Physics

We investigate the optical and morphological effects of silver island films exposed to atmosphere. Silver nanoparticles with an average radius below 5 nm were highly tarnished after one week, showing significant morphological changes. Using x-ray photoelectron spectroscopy we demonstrate that the tarnishing is predomi…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanocluster Synthesis and Applications

Chirality‐Dependent Reactivity of Individual Single‐Walled Carbon Nanotubes

Bilu Liu、Hua Jiang、Arkady V. Krasheninnikov 等 8 位作者2013-03-15Small

Electronic characteristics of a single-walled carbon nanotube (SWCNT) strongly depend on minor variations in its atomic arrangement, specifically chirality. Therefore, precise control over nanotube chirality is highly desired for their application. Theoretically, SWCNTs with different structures have different chemica…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

First‐Principles Study of Elastic, Structural, Electronic, Thermodynamical, and Optical Properties of Yttria ( Y 2 O 3 ) Ceramic in Cubic Phase

Hojat Allah Badehian、Hamdolah Salehi、Marzieh Ghoohestani2013-03-15Journal of the American Ceramic Society

Structural, elastic, optical, thermodynamical, and electronic properties of yttrium oxide compound in cubic phase have been studied using the full‐potential augmented plane waves ( FP ‐ LAPW ) within density functional theory ( DFT ) framework. Four different approximations were used for exchange‐correlation potential…

Chalcogenide Semiconductor Thin FilmsHeusler alloys: electronic and magnetic propertiesThermal Expansion and Ionic Conductivity

Dominant Role of Compromise between Diffusion and Reaction in the Formation of Snow-Shaped Vaterite

Han Wang、Yongsheng Han、Jinghai Li2013-03-15Crystal Growth & Design

The diffusion and reaction are two general kinetic factors playing an important role in the structure development of materials. Upon diffusion limitation, a noncompact structure is easily formed, while a compact structure is usually formed in a reaction-limited condition. In this Article, we take the precipitation of…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Wettability Control on ZnO Nanowires Driven by Seed Layer Properties

Marco Laurenti、Valentina Cauda、Rossana Gazia 等 7 位作者2013-03-15European Journal of Inorganic Chemistry

Abstract This study proposes a way to control the wettability of zinc oxide nanowires (NWs) by properly selecting the kind of seed layer used to promote the growth of the wires. ZnO seed layers were synthesized on silicon and conductive substrates by a physical vapor deposition approach and a wet‐chemical route, namel…

ZnO doping and propertiesSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials