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Fabrication of a thermo-responsive membrane with cross-linked smart gates via a ‘grafting-to’ method

Cheng-Jing Wu、Rui Xie、Hong-Bo Wei 等 8 位作者2016-01-01RSC Advances

A novel thermo-responsive membrane with the cross-linked microspheres as smart gates is fabricated by the “grafting to” technique, which exhibits excellent thermo-responsive characteristics with satisfactory reversibility and stability.

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Antimicrobial azobenzene compounds and their potential use in biomaterials

Lucia Sessa、Simona Concilio、Pio Iannelli 等 6 位作者2016-01-01AIP conference proceedings

We recently synthesized a class of active compounds with azobenzene structure [1] and lowest in silico toxicity values. The antimicrobial activity of these molecules and their thermal stability are very promising and indicate that they may have interesting and therapeutically significant applications. This work aims t…

Nanocomposite Films for Food PackagingAntimicrobial agents and applicationsPhotopolymerization techniques and applications

Solid-state characterization of 17β-estradiol co-crystals presenting improved dissolution and bioavailability

Jian‐Rong Wang、Xiaojuan Wang、Yong Yang 等 5 位作者2016-01-01CrystEngComm

17β-estradiol (E2) is a steroid hormone with low oral bioavailability due to its low aqueous solubility (0.2–5 μg mL−1). To improve its solubility and thus bioavailability, two co-crystals of E2 with isonicotinamide (INA) (1) and piperazine (PIP) (2) were successfully designed and synthesized and their structures were…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchCrystallization and Solubility Studies

Fabrication and characterization of antifouling carbon nanotube/polyethersulfone ultrafiltration membranes

Qi Zhang、Yuan Liu、Yanlei Su 等 8 位作者2016-01-01RSC Advances

SBMA@CNT particles were used as a novel kind of surface modifier, which could undergo self-organization at the interface of a membrane/coagulation bath. The modified membranes performed excellent pollution resistance.

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Performance of polarisation functionals for linear and nonlinear optical properties of bulk zinc chalcogenides ZnX (X = S, Se, and Te)

Myrta Grüning、Claudio Attaccalite2016-01-01Physical Chemistry Chemical Physics

We calculated the frequency dependent macroscopic dielectric function and second-harmonic generation of cubic ZnS, ZnSe and ZnTe within time-dependent density-polarisation functional theory. The macroscopic dielectric function is calculated in a linear response framework, and second-harmonic generation in a real-time…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNonlinear Optical Materials Research

Synthesis of LiCoO2 Prepared by Sol–gel Method

Nur Azilina Abdul Aziz、Tuti Katrina Abdullah、Ahmad Azmin Mohamad2016-01-01Procedia Chemistry

LiCoO2 was synthesized by sol–gel method using lithium acetate and cobalt acetate as the precursors and citric acid as the chelating agent. The solutions were stirred for different stirring times with a magnetic stirrer, followed by heating at 80 °C under vigorous stirring until a viscous gel was formed. The as-formed…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Nanogold POxylation: towards always-on fluorescent lung cancer targeting

Ana Sofia Silva、Marta C. Silva、Sónia P. Miguel 等 6 位作者2016-01-01RSC Advances

Gold nanoparticles (GNPs) were POxylated with fluorescent oligomers, synthesized in supercritical CO 2 , and conjugated with a laminin fragment. Particle design strongly impacts on probes uptake by the A549 cell line.

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsDendrimers and Hyperbranched Polymers

W(CO) 3 (Ph 2 PC 2 H 4 PPh 2 )(η 2 -Sc 3 N@I h -C 80 /Sc 3 N@D 5h -C 80 ): regioselective synthesis and crystallographic characterization of air-stable mononuclear complexes of endohedral fullerenes

Lipiao Bao、Bin Liu、Xiaofang Li 等 6 位作者2016-01-01Dalton Transactions

The organometallic chemistry of endohedral metallofullerenes has lagged far behind that of empty fullerenes. Herein, we report a highly regioselective coordination reaction involving two Sc3N@C80 isomers and W(CO)4(Ph2PC2H4PPh2) (1), which affords only one mononuclear complex for each Sc3N@C80 isomer (2a for Sc3N@Ih-C…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsSynthesis and Properties of Aromatic Compounds

In situ observation, X–ray diffraction and Raman analyses of carbon minerals in ureilites: Origin and formation mechanisms of diamond in ureilites

Y. Nakamuta、F. Kitajima、Kazuhiko Shimada2016-01-01Journal of Mineralogical and Petrological Sciences

Carbon minerals in sixteen monomict ureilites which are variable in shock features in olivine were observed in situ by optical microscopy, scanning electron microscopy, X–ray powder diffraction, and Raman analyses. Euhedral blade–like shaped or amoeboid shaped graphite crystals occur in the very low–shock ureilites, n…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Synthesis and extraction studies with a rationally designed diamide ligand selective to actinide( iv ) pertinent to the plutonium uranium redox extraction process

Shikha Sharma、S. Panja、Arunasis Bhattacharyya 等 6 位作者2016-01-01Dalton Transactions

A new class of conformationally constrained oxa-bridged tricyclo-dicarboxamide (OTDA) ligand was rationally designed for the selective extraction of tetravalent actinides pertinent to the Plutonium Uranium Redox EXtraction (PUREX) process. Two of the designed diamide ligands were synthesized and extraction studies wer…

Radioactive element chemistry and processingNuclear Materials and PropertiesChemical Synthesis and Characterization

Thin Film ZnO Coated on FTO/TiO2 as an Anti Reflection Coatingfor EnhancingVisible Light Harversting in Dye Sensitized Solar Cells System

Sayekti Wahyuningsih、Ganjar Fadillah、Rahmat Hidayat 等 4 位作者2016-01-01Procedia Chemistry

ZnOmaterial has unique electrical and optical properties that many important applications, including as an anti-reflection coating in dye sensitized solar cells. Flat anti-reflective coatings (ARC) made of ZnO on top to improve the optical properties of the coating. In this study, ZnO nanoparticle were coated with TiO…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesZnO doping and properties

Molecular conductance of double-stranded DNA evaluated by electrochemical capacitance spectroscopy

William da Cunha Ribeiro、Luís Moreira Gonçalves、Susana Liébana 等 5 位作者2016-01-01Nanoscale

Conductance was measured in two different double stranded DNA (both with 20 bases), the more conducting poly(dG)-poly(dC) (ds-DNAc) and the less conducting poly(dA)-poly(dT) (ds-DNAi), by means of Electrochemical Capacitance Spectroscopy (ECS). The use of the ECS approach, exemplified herein with DNA nanowires, is equ…

Advanced biosensing and bioanalysis techniquesConducting polymers and applicationsMolecular Junctions and Nanostructures

Aqueous sol–gel synthesized anatase TiO 2 nanoplates with high-rate capabilities for lithium-ion and sodium-ion batteries

Hao Yang、Jenq-Gong Duh2016-01-01RSC Advances

The graph shows the structure of anatase nanoplates that is assembled using terephthalic acid. After the acid is burned out and transforms into CO 2 , the nanoplates exhibit uniform nanopores, which is suitable for Li-ion/Na-ion insertion.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationExtraction and Separation Processes

Thermal-activated nanocarriers for the manipulation of cellular uptake and photothermal therapy on command

Jingjing Zhao、Penghui Zhang、Zhimei He 等 6 位作者2016-01-01Chemical Communications

Smart nanocarriers with switchable surfaces consisting of thermo-sensitive polymers and aptamers have been developed, through which the cellular uptake and photothermal therapy in five different cells could be spatial-temporally controlled on command, which is beneficial in maximizing therapy efficacy and minimizing s…

Advanced biosensing and bioanalysis techniquesNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis

3D-Encapsulated iridium-complexed nanophosphors for highly efficient host-free organic light-emitting diodes

Fuquan Han、Xiaolin Zhang、Xiaolin Zhang 等 9 位作者2016-01-01Chemical Communications

Iridium-complexed nanosize phosphors 3D-encapsulated with nine 3,6-di-tert-butyl-N-propyl-carbazole groups were constructed as host-dopant integrated systems, which achieved a high photoluminescence quantum yield beyond 70% from neat evaporated films, and an electroluminescence external quantum efficiency up to ∼8.5%…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Polydimethylsiloxane (PDMS) modulates CD38 expression, absorbs retinoic acid and may perturb retinoid signalling

Kathryn Futrega、Jianshi Yu、Jace W. Jones 等 7 位作者2016-01-01Lab on a Chip

Polydimethylsiloxane (PDMS) is the most commonly used material in the manufacture of customized cell culture devices. While there is concern that uncured PDMS oligomers may leach into culture medium and/or hydrophobic molecules may be absorbed into PDMS structures, there is no consensus on how or if PDMS influences ce…

Adenosine and Purinergic SignalingLuminescence and Fluorescent MaterialsCalcium signaling and nucleotide metabolism