Materials Literature
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We synthesized a series of tri-component biodegradable copolymers with elastic characteristics by ring-opening copolymerization of cyclic lactones, that is, glycolide, L-lactide, and ϵ-caprolactone, in the presence of stannous octoate as a catalyst. We evaluated the physical and chemical characteristics of poly(glycol…
The present work aimed to treat a polyethylene terephthalate (PET) surface to make the biomaterial more 'attractive' in terms of attachment and shear stress response to endothelial cells with a view to possible applications in vascular grafting. A surface wet-chemistry protocol was applied to graft track-etched PET me…
In this letter, a universal ultrafast sandpaper assisting rubbing method was proposed to fabricate two-dimensional nanosheets (graphene, hexagonal boron nitride, tungsten disulfide, molybdenum disulfide) directly on flexible polymer substrate under room temperature. By two steps of rubbing progresses totally within 2…
The Schlenk diradical has been known since 1915. After a detailed experimental work by Rajca, its magnetic nature has remained more or less unexplored. We have investigated by quantum chemical calculations the nature of magnetic coupling in 11 substituted Schlenk diradicals. Substitution has been considered at the fif…
The efficiency of dicarboxylate corrosion inhibitors for mild steel in near neutral NaCl solution was studied using electrochemical methods as open circuit potential, potentiodynamic polarisation curves and electrochemical impedance spectroscopy. Surface analysis was carried out to determine the kind of protection aff…
Abstract Nanoporous network polymer nanocomposites with tunable pore size for size‐dependent selective ion transport are successfully prepared via the surface‐induced cross‐linking polymerization of methyl methacrylate (MMA) and 1,6‐hexanediol diacrylate (HDDA) on the surfaces of nanocrystalline TiO 2 particles. The m…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation K. Mitsuishi, T. Ohnishi, Y. Tanaka, K. Watanabe, I. Sakaguchi, N. Ishida, M. Takeguchi, T. Ohno,…
The dependence of the photocurrent generated in a Pd/graphene/Ti junction device on the incident photon polarization is studied. Spatially resolved photocurrent images were obtained as the incident photon polarization is varied. The photocurrent is maximum when the polarization direction is perpendicular to the graphe…
The design and fabrication of functional nanocomposites is an active area of research because composite particles have significantly improved physical and chemical properties over those of their single-component counterparts. Traditionally, chemical pretreatments of the components were used to enhance their physicoche…
We report a general approach to overcome the enormous obstacle of the integration of CNTs into devices by bonding single-walled carbon nanotubes (SWNTs) films to arbitrary substrates and transferring them into densified and lithographically processable "CNT wafers". Our approach allows hierarchical layer-by-layer asse…
A number of charge transferring molecules with varying electron donor, acceptor and π-conjugative paths have been considered for the theoretical study of their NLO properties in terms of the linear polarizability and the ground state dipole moment. The equilibrium structures are calculated at the HF, MP2 and B3LYP lev…
Undoped Y 2 O 3 and Y 2 O 3 doped with either Si 4+ , Er 3+ , Yb 3+ , Al 3+ or Ti 4+ were fabricated by a two‐step sintering method. The concentration of each dopant cation ( Si 4+ , Er 3+ , Yb 3+ , Al 3+ , and Ti 4+ ) was adjusted so that the dopant:yttria molar ratio was 0.01 and the mechanical properties and the mi…
The environmental friendly inhibitor system DL‐phenylalanine‐Zn 2+ has been investigated by weight loss method. A synergistic effect exists between DL‐phenylalanine and Zn 2+ system. The formulation consisting of 150 ppm of DL‐phenylalanine and 5 ppm of Zn 2+ offers good inhibition efficiency of 90%. Polarization stud…
Abstract Oligoporphyrinoid materials composed of two or three tetrapyrrolic macrocycles have been synthesized by either mono‐ or disubstitution (S N Ar) of a phenolic Zn‐AB 3 ‐porphyrin on a meso ‐dichloropyrimidinyl‐substituted Cu‐AB 2 ‐corrole. Selective metallation/demetallation sequences were carried out on these…
The availability of the coupling agent bis (3-triethoxysilylpropyl)-tetrasulfide (TESPT) has provided an opportunity for enhancing the reinforcing capabilities of precipitated amorphous white silica in rubber. Styrene-butadiene rubber, synthetic polyisoprene rubber (IR), acrylonitrile-butadiene rubber, and natural rub…
A rollable and all-solid-state textile lithium battery based on fabric matrix and polymer electrolyte that allows flexibility and fast-charging capability is reported. When immerged into poly(3,4-ethylenedioxythiophene) (PEDOT) nano-emulsion inks, an insulating fabric is converted into a conductive battery electrode f…
Metal-containing tubes: The structures of several iron-containing C-methylpyrogallol[4]arene (PgC1) nanoassemblies were studied in both the solid and solution phases. The nanoassemblies have a tubular architecture with the iron as part of the framework (see picture; gray C, red O, turquoise/blue Fe), and magnetic anal…
The CO adsorption and subsequent reaction with preadsorbed NO(x) on Pd and K cosupported Mg-Al mixed oxides (Pd-K/MgAlO, 1/8/100 w/w) were investigated using in situ FTIR spectroscopy. During CO adsorption, a peculiar and well-defined IR band at 2160 cm(-1) was observed. Several elaborately designed experiments such a…
In this work, a simultaneously photoactive and electroactive polyamide exhibiting interesting spectroscopic and electrochemical properties was prepared. Firstly, a 4-aminoazobenzene-capped amide oligomer (ACAO) was synthesized and characterized by 1H NMR, 13C NMR and mass spectroscopy. Subsequently, the photoactively…
To obtain a different backbone structure of conductors in disordered insulator/conductor composites, Cu 2 O/Cu composites were prepared using two methods, named the direct hot-pressing (DHP) method and the in-situ reduction hot-pressing (IRHP) method via hot-pressing Cu 2 O powders and branch-like or spherical Cu powd…