Materials Literature
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Methods are presented to synthesize suspensions of chemically and shape anisotropic colloids on submicrometer length scales. Particles are synthesized through seeded emulsion polymerization where a weakly cross-linked seed is swollen with monomer that phase separates at the reaction temperature resulting in a protrusi…
A demonstration of magnetization reversal via the application of electric field across a multiferroic heterostructure, consisting of a FeCoV ribbon bonded to a lead magnesium niobate-lead titanate crystal, is presented. The magnetization switching occurs by an abrupt change in magnetization near ferromagnetic coercivi…
Channel your energy: Bodipy dyes were linked covalently by a method involving three key steps, including a carboformylation reaction. All multichromophoric dyes exhibited highly efficient photoinduced energy transfer to the terminal Bodipy modules, which fluoresced at 652 nm with 57 % quantum efficiency (see absorptio…
The formation of a shish kebab (SK) structure, where carbon nanotubes (CNTs) serve as shish and polymer lamellae serve as kebab, is particularly interesting and provides a novel way to enhance the polymer-CNT interface. A fine SK structure is achieved through melt spinning. High density polyethylene and pristine CNTs…
We propose a model to calculate the electronic structure of hydrotalcite-like compounds by using periodic boundary conditions and ab initio density functional theory (DFT). The proposed method to build up layered double hydroxides (LDHs) was tested for Zn 2/3 Al 1/3 (OH) 2 Cl 1/3 · 2 / 3 H 2 O, Zn 2/3 Al 1/3 (OH) 2 (C…
This Perspective describes studies aimed at effective excitation of molecules by localized surface plasmon polaritons. Recently developed bottom-up and top-down techniques allow the controlled fabrication of well-defined metal structures exhibiting desirable localization of plasmon energy. Under certain conditions, mo…
Boron-doped diamond is a promising transducer material for numerous devices which are designed for contact with electrolytes. For optimized electron transfer the surface of diamond needs to be hydrogen terminated. Up to now H-termination of diamond is done by plasma chemical vapor deposition techniques. In this paper,…
This paper presents a "one-spot" procedure to fabricate polystyrene/silica (PS/SiO(2)) hybrid hollow spheres. In this approach, when poly(vinylpyrrolidone)-stabilized PS colloids were deposited by sol-gel derived silica layer under acidic medium, it was interesting to find that the PS/SiO(2) core-shell colloids gradua…
Thin films of polyaniline (PANi) and PANi:titanium oxide (TiO2) composites have been synthesized by sol—gel spin coating technique. The TiO2 powder of particle size 50–60 nm was synthesized by sol–gel technique and the polyaniline was synthesized by chemical oxidative polymerization of aniline. The composite films wer…
We accomplished a facile and scalable route to linearly stacked, one-dimensional metal nanowire assembly via soft graphoepitaxy of block copolymers. A one-dimensional nanoscale lamellar stack could be achieved by controlling the block copolymer film thickness self-assembled within the disposable topographic confinemen…
Wechselwirkungen auf allen Ebenen: Ein supramolekulares Polymer mit hohem Polymerisationsgrad wurde auf der Basis mehrfacher wirtstabilisierter Charge-Transfer-Wechselwirkungen konstruiert (siehe Bild; DADV: ein Dianthracenylbis(bipyridiniumbromid), CB[8]=Cucurbit[8]uril). Wechselwirkungen zwischen Ketten des supramol…
Temperature- and bias voltage-dependent transport measurements of magnetic tunnel junctions (MTJs) with perpendicularly magnetized Co/Pd electrodes are presented. Magnetization measurements of the Co/Pd multilayers are performed to characterize the electrodes. The effects of the Co layer thickness in the Co/Pd bilayer…
We report on terahertz (THz) radiation under electrical pumping from a degenerate semiconductor possessing an electron accumulation layer. In InN, the random grating formed by topographical defects provides high-efficiency coupling of surface plasmon polaritons supported by the accumulation layer to the THz emission.…
Recent experiments on hydrogenated amorphous silicon using infrared absorption spectroscopy have indicated the presence of mono- and divacancy in samples for concentration of up to 14\% hydrogen. Motivated by this observation, we study the microstructure of hydrogen in two model networks of hydrogen-rich amorphous sil…
Stable cross sections of multiwalled carbon nanotubes subjected to electron-beam irradiation are investigated in the realm of the continuum mechanics approximation. The self-healing nature of $s{p}^{2}$ graphitic sheets implies that selective irradiation of the outermost walls causes their radial shrinkage with the re…
Breast cancer remains one of the world's most devastating diseases. However, better understanding of tumor biology and improved diagnostic devices could lead to improved therapeutic outcomes. Nanotechnology has the potential to revolutionize cancer diagnosis and therapy. Various nanocarriers have been introduced to im…
An interesting morphological evolution from single nanoflakes to nanoflake assemblies, flower-like structures, and hollow microspheres is reported for the first time for boehmite prepared from Al(NO 3 ) 3 ·9H 2 O with addition of urea and different amounts of KAl(SO 4 ) 2 ·12H 2 O under hydrothermal conditions. The mi…
We use a string of confined $^{40}$Ca$^+$ ions to measure perturbations to a trapping potential which are caused by light-induced charging of an anti-reflection coated window and of insulating patches on the ion-trap electrodes. The electric fields induced at the ions' position are characterised as a function of dista…
The transverse and longitudinal magnetoelectric susceptibilities (MES) were quantitatively determined for (001) heteroepitaxial BiFeO3–CoFe2O4 nanostructures. Both of these MES values were sharply enhanced at magnetic fields below 6 kOe and revealed asymmetric line shapes with respect to the dc magnetic field, demonst…
We assumed that significant enlargement of the functional properties of the family of quaternary ZrCuSiAs-like pnictide-oxides, often called also as 1111 phases, which are known now first of all as parent phases for new FeAs superconductors, may be achieved by replacement of nonmagnetic ions by magnetic ions in semico…