Materials Literature
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An "electrostatic" eigenmode method based on the coupling of evanescent electric fields is presented for modeling the hybridization of localized surface plasmon resonances in metallic nanoparticles of arbitrary shape. The method yields simple analytical expressions for the hybridized energies and excitation amplitudes…
La(0.7)Sr(0.3)MnO(3) is a conducting ferromagnet at room temperature. Combined with thin SrTiO(3) layers, the resulting heterostructures could be used as highly spin-polarized magnetic-tunnel-junction memories. However, when shrunk to dimensions below an apparent critical thickness, the structures become insulating an…
A series of polycrystalline pyrochlore rare-earth titanate Ho2−xCrxTi2O7 are synthesized in order to enhance the ferroelectricity of pyrochlore Ho2Ti2O7. A giant enhancement of polarization P from 0.54 μC/m2 at x=0 up to ∼660 μC/m2 at x=0.4 is obtained, accompanied with an increment of ferroelectric transition point T…
Dimensionality cross-over is a classical topic in physics. Surprisingly it has not been searched in micromagnetism, which deals with objects such as domain walls (2D) and vortices (1D). We predict by simulation a second-order transition between these two objects, with the wall length as the Landau parameter. This was…
Using high resolution neutron diffraction and capacitance dilatometry we show that the thermal evolution of the helimagnetic state in CoMnSi is accompanied by a change in interatomic distances of up to 2%, the largest ever found in a metallic magnet. Our results and the picture of competing exchange and strongly aniso…
The temperature dependence of the electrical resistivity in insulator systems with a Coulomb gap in the density of states is expressed by a very simple function which coincides with the Efros-Shklovskii T^(-1/2)result, at temperatures lower than some value Tlim. Above this limit it consists of the product of the Mott…
To demonstrate the effect of donor (D) and acceptor (A) units on the structure−property relationships of electrochromic polymers, design, synthesis, characterization and polymerization of a series of D−A type systems, 1 − 5, based on thiophene, 3,4-ethylenedioxythiophene, and 3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1…
We review the mechanisms and pathways whereby nanoparticles might cause genotoxicity. Primary and secondary mechanisms are discussed in relation to the general particle toxicology paradigm. We also discuss how we might improve genotoxicity assays for nanoparticles. In this context we describe the role of the dispersio…
Concentration dependence of Mn(2+) luminescence in NaCaPO(4)/Mn(2+) is investigated by structural analyses and optical and laser excitation spectroscopies in the temperature range 19-300 K. NaCaPO(4)/Mn(2+) forms solid solution over the Mn(2+) concentration range 1.0-22 mol %. We observe the red shift and unusual band…
High-frequency ultrasound at 211 kHz is effective in developing graphene-based nanoarchitectures. Both simultaneous and sequential reduction steps have been employed to reduce the graphene oxide (GO) and a gold precursor, HAuCl 4 . Characterization of the composites by transmission electron microscopy following the re…
The evolution of electronic energy levels of controlled air and oxygen exposed molybdenum trioxide (MoO3) films has been investigated with ultraviolet photoemission spectroscopy, inverse photoemission spectroscopy, and x-ray photoemission spectroscopy. We found that while most of the electronic levels of as deposited…
Nanotechnology, a promising field of research opens up in the present decade a wide array of opportunities in the present decade and is expected to give major impulses to technical innovations in a variety of industrial sectors in the future. The potential uses and benefits of nanotechnology are enormous. These includ…
The use of Raman scattering techniques to study the mechanical properties of graphene films is reviewed here. The determination of Grüneisen parameters of suspended graphene sheets under uni- and bi-axial strain is discussed, and the values are compared to theoretical predictions. The effects of the graphene−substrate…
Halloysite is a clay mineral with stoichiometry Al 2 Si 2 O 5 (OH) 4 · n H 2 O that can grow into long tubules and is chemically similar to kaolinite. In this work we present a systematic study on the stability, electronic, and mechanical properties of zigzag and armchair single-walled halloysite nanotubes by means of…
Well-defined periodic mesostructures of hydrophilic ultrathin Te nanowires with aspect ratios of at least 10(4) can be produced by the Langmuir-Blodgett technique without any extra hydrophobic pretreatment or functionalization. Packing the arrayed nanowire monolayers will allow construction of nanomesh-like mesostruct…
Nanoparticles have diverse applications in electronics, medical devices, therapeutic agents and cosmetics. While the commercialization of nanoparticles is rapidly expanding, their health and environmental impact is not well understood. Toxicity assays of silver, gold, and platinum nanoparticles, using zebrafish embryo…
Polymers are considered to be good hosting matrices for composite materials because they can easily be tailored to yield a variety of bulk physical properties. Moreover, organic polymers generally have long-term stability and good processability. Inorganic nanoparticles possess outstanding optical, catalytic, electron…
ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTCurrent Progress on the Chemical Modification of Carbon NanotubesNikolaos Karousis*, Nikos Tagmatarchis, and Dimitrios Tasis*View Author Information Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, 116 35 A…
Abstract During recent years, major progress has been made in the understanding of the adsorption, pore condensation and hysteresis behavior of fluids in novel ordered nanoporous materials with well defined pore structure. This has led to major advances in the structural characterization by physical adsorption, also b…
Thin-film thermoelectric cooling is a promising technology for mitigating heat dissipation in high performance chips. In this paper, we present an optimization framework for an active cooling system that is comprised of an array of thin-film thermoelectric coolers. We observe a set of constraints of the cooling system…