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Long Distance Enhancement of Nonlinear Optical Properties Using Low Concentration of Plasmonic Nanostructures in Dye Doped Monolithic Sol–Gel Materials

Denis Château、Adrien Liotta、Hampus Lundén 等 11 位作者2016-05-31Advanced Functional Materials

Monolithic sol–gel silica composites incorporating platinum‐based chromophores and various types of gold nanoparticles (AuNPs) are prepared and polished to high optical quality. Their photophysical properties are investigated. The glass materials show well‐defined localized surface plasmon resonance (SPR) absorbance f…

Gold and Silver Nanoparticles Synthesis and ApplicationsPhotochemistry and Electron Transfer StudiesNonlinear Optical Materials Studies

Modeling Defects, Shape Evolution, and Programmed Auto-Origami in Liquid Crystal Elastomers

Andrew Konya、Vianney Gimenez‐Pinto、Robin L. B. Selinger2016-05-31Frontiers in Materials

Liquid crystal elastomers represent a novel class of programmable shape-transforming materials whose shape change trajectory is encoded in the material’s nematic director field. Using three-dimensional nonlinear finite element elastodynamics simulation, we model a variety of different actuation geometries and device d…

Liquid Crystal Research AdvancementsAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Tailored synthesis of macroporous Pt/WO3 photocatalyst with nanoaggregates via flame assisted spray pyrolysis

Osi Arutanti、Aditya Farhan Arif、Ratna Balgis 等 6 位作者2016-05-31AIChE Journal

High‐surface‐area macroporous WO3 particles with deposited Pt (Pt/WO3) were successfully synthesized for the first time, using flame‐assisted spray pyrolysis. Nanoparticle aggregates‐like structures (nanoaggregates) were formed, although a salt precursor was used for the synthesis. The macroporous structure was tailor…

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Polarization Energies at Organic–Organic Interfaces: Impact on the Charge Separation Barrier at Donor–Acceptor Interfaces in Organic Solar Cells

Sean M. Ryno、Yao‐Tsung Fu、Chad Risko 等 4 位作者2016-05-31ACS Applied Materials & Interfaces

We probe the energetic landscape at a model pentacene/fullerene (C60) interface to investigate the interactions between positive and negative charges, which are critical to the processes of charge separation and recombination in organic solar cells. Using a polarizable force field, we find that polarization energy, i.…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsFullerene Chemistry and Applications

Harnessing Fluorescence versus Phosphorescence Ratio via Ancillary Ligand Fine-Tuned MLCT Contribution

Ilya Kondrasenko、Kun‐You Chung、Yi‐Ting Chen 等 8 位作者2016-05-31The Journal of Physical Chemistry C

A series of gold(I) alkynyl-diphosphine complexes (XC 6 H 4 C 2 Au)PPh 2 — spacer —PPh 2 (AuC 2 C 6 H 4 X); spacer = —C 2 (C 6 H 4 ) n C 2 — ( A1, n = 2, X = CF 3; A2, n = 2, X = OMe; A3, n = 3, X = CF 3; A4, n = 3, X = OMe), —(C 6 H 4 ) n — ( B5, n = 3, X = OMe; B6, n = 4, X = OMe) were prepared, and their photophysi…

Catalytic Cross-Coupling ReactionsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Transport properties of small molecules in zwitterionic polymers

Shawreen Shah、Junyi Liu、Siucheung Ng 等 7 位作者2016-05-31Journal of Polymer Science Part B Polymer Physics

ABSTRACT Despite great interests in using zwitterionic polymers for membrane surface modification to enhance antifouling properties, there lacks fundamental understanding of the relationship between polymer structure and water/salt separation properties. In this study, two series of zwitterionic polymers were prepared…

Membrane Separation TechnologiesPolymer Surface Interaction StudiesMembrane Separation and Gas Transport

Low-temperature co-pyrolysis behaviours and kinetics of oily sludge: effect of agricultural biomass

X.Y. Zhou、Hanzhong Jia、Chengtun Qu 等 5 位作者2016-05-31Environmental Technology

Pyrolysis is potentially an effective treatment of oily sludge for oil recovery, and its kinetics and efficiency are expected to be affected by additives. In the present study, the pyrolysis parameters, including heating rate, final pyrolysis temperature, and pyrolysis time of oily sludge in the presence of agricultur…

Thermochemical Biomass Conversion ProcessesFlame retardant materials and propertiesThermal and Kinetic Analysis

Non-Temperature Induced Effects of Magnetized Iron Oxide Nanoparticles in Alternating Magnetic Field in Cancer Cells

Sudath Hapuarachchige、Yoshinori Katō、Ethel J. Ngen 等 6 位作者2016-05-31PLoS ONE

This paper reports the damaging effects of magnetic iron-oxide nanoparticles (MNP) on magnetically labeled cancer cells when subjected to oscillating gradients in a strong external magnetic field. Human breast cancer MDA-MB-231 cells were labeled with MNP, placed in the high magnetic field, and subjected to oscillatin…

Nanoparticle-Based Drug DeliveryMicrofluidic and Bio-sensing TechnologiesCharacterization and Applications of Magnetic Nanoparticles

Angular momentum and topology in semiconducting single-wall carbon nanotubes

Wataru Izumida、Rin Okuyama、Ai Yamakage 等 4 位作者2016-05-31Physical review. B./Physical review. B

Semiconducting single-wall carbon nanotubes are classified into two types by means of the orbital angular momentum of the valley state, which is useful to study their low-energy electronic properties in finite length. The classification is given by an integer $d$, which is the greatest common divisor of two integers $…

Carbon Nanotubes in CompositesGraphene research and applicationsTopological Materials and Phenomena

Enhanced Actuation Response of Nafion-Based Ionic Polymer Metal Composites by Doping BaTiO3 Nanoparticles

Kan Bian、Hongguang Liu、Guòan Tai 等 5 位作者2016-05-31The Journal of Physical Chemistry C

Nafion-based composite membranes by doping BaTiO 3 nanoparticles were prepared to fabricate high-performance ionic polymer metal composite (IPMC) actuators. BaTiO 3 /Nafion nanocomposites were evaluated in terms of their static mechanical properties, water uptake, surface resistivity, electrochemical impedance, and ac…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Recovery of Proteins from Rohu Processing Waste Using pH Shift Method: Characterization of Isolates

Vijay Kumar Reddy Surasani、Anuj Tyagi、Tanaji G. Kudre2016-05-31Journal of Aquatic Food Product Technology

Yield and physicochemical characteristics of protein isolates recovered from rohu processing waste by acid- and alkali-aided protein solubilization methods were studied. pH 2.0 from acidic side and pH 13.0 from alkaline side resulted in maximum protein solubility, whereas minimum solubility was observed at pH 5.5. Exc…

Proteins in Food SystemsEnzyme Production and CharacterizationPickering emulsions and particle stabilization

Determination of Oxytetracycline by a Graphene—Gold Nanoparticle-Based Colorimetric Aptamer Sensor

Fang Yuan、Huimin Zhao、Xiaodan Wang 等 4 位作者2016-05-31Analytical Letters

A colorimetric aptamer sensor for the determination of oxytetracycline was developed based on the controllable peroxidase-like catalysis of a graphene/gold nanoparticle hybrid and the high affinity between oxytetracycline aptamers and oxytetracycline. The oxytetracycline aptamer was a single-stranded DNA sequence that…

Advanced biosensing and bioanalysis techniquesBiosensors and Analytical DetectionAdvanced Nanomaterials in Catalysis

Impact of doping on InAs/GaAs quantum-dot solar cells: A numerical study on photovoltaic and photoluminescence behavior

Federica Cappelluti、Mariangela Gioannini、Arastoo Khalili2016-05-31Solar Energy Materials and Solar Cells

We investigate the effect of doping on quantum dot (QD) solar cells by analysing their behavior in terms of photovoltaic characteristic, external quantum efficiency, and photoluminescence (PL) at room temperature. The analysis addresses the two most widespread methods for QD selective doping, namely modulation and dir…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Discrimination of orbital angular momentum modes of the terahertz vortex beam using a diffractive mode transformer

Changming Liu、Xuli Wei、Liting Niu 等 6 位作者2016-05-31Optics Express

We present an efficient method to discriminate orbital angular momentum (OAM) of the terahertz (THz) vortex beam using a diffractive mode transformer. The mode transformer performs a log-polar coordinate transformation of the input THz vortex beam, which consists of two 3D-printed diffractive elements. A following len…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

Surface and Antimicrobial Activity of Sulfobetaines

Daria Wieczorek、Daniela Gwiazdowska、Katarzyna Staszak 等 5 位作者2016-05-31Journal of Surfactants and Detergents

Abstract Sulfobetaines belong to the group of zwitterionic surfactants. They are electroneutral salts, which have in the same molecule, two ionic centers with different charge. Due to the specific structure they exhibit excellent properties such as good solubility in water and detergency. In this paper we present surf…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesEnvironmental Chemistry and Analysis

Theoretical insight into the influence of molecular ratio on the binding energy and mechanical property of HMX/2-picoline-N-oxide cocrystal, cooperativity effect and surface electrostatic potential

Zhaobian Xie、Shuangqi Hu、Xiong Cao2016-05-31Molecular Physics

Molecular dynamics method was employed to study the binding energies and mechanical properties of the selected crystal planes of the energetic/nonenergetic 1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane (HMX)/2-picoline-N-oxide cocrystal in different molecular ratios. The solvent effect in HMX:2-picoline-N-oxide (1:1)…

Crystallography and molecular interactionsEnergetic Materials and CombustionThermal and Kinetic Analysis

Rational Design of an Ultrasensitive and Highly Selective Chemodosimeter by a Dual Quenching Mechanism for Cysteine Based on a Facile Michael‐Transcyclization Cascade Reaction

Xiangmin Li、Y. Zheng、Hongjuan Tong 等 10 位作者2016-05-31Chemistry - A European Journal

Differentiation of biologically important thiols, such as cysteine (Cys), homocysteine (Hcy), and glutathione (GSH) is still a challenging task. Herein, we present a novel fluorescent chemodosimeter capable of selectively detecting Cys over other biothiols including Hcy and GSH and other amino acids by a facile thiol-…

Molecular Sensors and Ion DetectionLanthanide and Transition Metal ComplexesSulfur Compounds in Biology

Slow Organic‐to‐Inorganic Sub‐Lattice Thermalization in Methylammonium Lead Halide Perovskites Observed by Ultrafast Photoluminescence

Angela Y. Chang、Yi‐Ju Cho、K.C. Chen 等 10 位作者2016-05-31Advanced Energy Materials

Carrier dynamics in methylammonium lead halide (CH3NH3PbI3–xClx) perovskite thin films, of differing crystal morphology, are examined as functions of temperature and excitation wavelength. At room temperature, long‐lived (>nanosecond) transient absorption signals indicate negligible carrier trapping. However, in measu…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesSolid-state spectroscopy and crystallography

Somatostatin Receptor-Mediated Tumor-Targeting Nanocarriers Based on Octreotide-PEG Conjugated Nanographene Oxide for Combined Chemo and Photothermal Therapy

Xuyuan Zhang、Chongyin Yang、Jianping Zhou 等 4 位作者2016-05-31Small

Nano-sized in vivo active targeting drug delivery systems have been developed to a high anti-tumor efficacy strategy against certain cancer-cells-specific. Graphene based nanocarriers with unique physical and chemical properties have shown significant potentials in this aspect. Here, octreotide (OCT), an efficient bio…

Graphene research and applicationsNanoplatforms for cancer theranosticsGraphene and Nanomaterials Applications

Transcriptional Regulation of the Outer Membrane Porin Gene ompW Reveals its Physiological Role during the Transition from the Aerobic to the Anaerobic Lifestyle of Escherichia coli

Minfeng Xiao、Yong Lai、Jian Sun 等 5 位作者2016-05-31Frontiers in Microbiology

Understanding bacterial physiology relies on elucidating the regulatory mechanisms and cellular functions of those differentially expressed genes in response to environmental changes. A widespread Gram-negative bacterial outer membrane protein OmpW has been implicated in the adaptation to stresses in various species.…

Bacterial Genetics and BiotechnologyBacteriophages and microbial interactionsEnzyme Structure and Function