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Electron correlation in tetrapyrroles: ab initio calculations on porphyrin and the tautomers of chlorin

Jan Almløf、Thomas Fischer、Paul G. Gassman 等 5 位作者1993-10-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron correlation in tetrapyrroles: ab initio calculations on porphyrin and the tautomers of chlorinJan Almlof, Thomas H. Fischer, Paul G. Gassman, Abhik Ghosh, and Marco HaeserCite this: J. Phys. Chem. 1993, 97, 42, 10964–10970Publication Date (Print):October 1, 1993Publ…

Porphyrin and Phthalocyanine ChemistryElectrochemical Analysis and ApplicationsSurface Chemistry and Catalysis

Phosphorylation and activation of human tyrosine hydroxylase in vitro by mitogen‐activated protein (MAP) kinase and MAP‐kinase‐activated kinases 1 and 2

Calum Sutherland、Janine ALTERIO、David G. CAMPBELL 等 7 位作者1993-10-01European Journal of Biochemistry

Mitogen-activated protein-kinase (MAP) kinase-activated protein kinases 1 and 2 (MAPKAP kinase-1, MAPKAP kinase-2), were found to phosphorylate bacterially expressed human tyrosine hydroxylase in vitro at comparable rates to other proteins thought to be physiological substrates of these protein kinases. The phosphoryl…

Microbial Metabolic Engineering and BioproductionEnzyme Structure and FunctionBiochemical and biochemical processes

Bacillus subtilis genome project: cloning and sequencing of the 97 kb region from 325° to 333deg;

Philippe Glaser、Frank Kunst、M Arnaud 等 17 位作者1993-10-01Molecular Microbiology

In the framework of the European project aimed at the sequencing of the Bacillus subtilis genome the DNA region located between gerB (314°) and sacXV (333°) was assigned to the Institut Pasteur. In this paper we describe the cloning and sequencing of a segment of 97 kb of contiguous DNA. Ninety-two open reading frames…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Tailoring Thermoplastic Olefin Elastomers for Automotive Applications through Intensive Mixing

Edmund Lau、John Goodman1993-10-01Journal of Elastomers & Plastics

Use of thermoplastic olefin elastomers (TPO) is expected to enjoy a 12% annual growth worldwide through 1996. The majority of growth is in au tomotive applications such as bumper fascia, claddings, exterior panels, airbag covers and instrument panels, etc. This healthy forecast is fueled by the overall cost/performanc…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTransport Systems and Technology

Collagen type VI in neural crest development: Distribution in situ and interaction with cells in vitro

Roberto Perris、Heuy‐Ju Kuo、Robert W. Glanville 等 4 位作者1993-10-01Developmental Dynamics

We have examined the spatio-temporal distribution of collagen type VI (Col VI) during neural crest development in vivo and its ability to promote neural crest cell attachment and migration in vitro. An affinity purified antiserum and chain-specific monoclonal antibodies against chicken Col VI were employed to immunolo…

TGF-β signaling in diseasesSkin and Cellular Biology ResearchCollagen: Extraction and Characterization

High‐Pressure Synthesis of LiSi: Three‐Dimensional Network of Three‐Bonded Si− Ions

Jürgen Evers、Gilbert Oehlinger、Gerhard Sextl1993-10-01Angewandte Chemie International Edition in English

4 GPa pressure, 600 °C, and a reaction time of 5 minutes—under these conditions LiSi can be prepared from the elements. Like the homologous silicides MSi (M  NaCs), which have been known for a long time, LiSi also belongs to the Zintl phases. The Si− ions form a three-dimensional network in a structure comprising pu…

Crystal Structures and PropertiesInorganic Chemistry and MaterialsX-ray Diffraction in Crystallography

Dielectric permittivity of antiferroelectric liquid crystals

P. Gisse、J. Pavel、H. T. Nguyen 等 4 位作者1993-10-01Ferroelectrics

The complex dielectric permittivity has been measured as a function of the frequency, the temperature and the biasing field for the antiferroelectric liquid crystal tolan C8 and C10. At the transition from the ferrielectric phase to the antiferroelectric one the remarkable maximum has been observed for low frequencies…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

Constituent Migration Model for U-Pu-Zr Metallic Fast Reactor Fuel

Masayoshi Ishida、Takanari Ogata、Motoyasu Kinoshita1993-10-01Nuclear Technology

A model for constituent migration behavior in U-Pu-Zr metallic fast reactor fuel is proposed. It is based on diffusion equations for the ternary system under a radial temperature gradient, and it takes into account the alloy phase decomposition, assuming a quasi-binary U-Zr phase diagram with a constant plutonium cont…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys

Simple passivation and depassivation model for pitting corrosion

Paul Meakin、Torstein Jøssang、Jens Feder1993-10-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

A simple two-dimensional passivation and depassivation model for pitting corrosion has been developed. This model describes corrosion processes that are limited by the diffusion of either a corrosive agent or the diffusion of corrosion products that inhibit the corrosion process. Despite its simplicity, this model exh…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Influence of Sodium Salts of Organic Acids as Additives on Localized Corrosion of Aluminum and Its Alloys

I. Raspini1993-10-01CORROSION

Localized pitting is best described by a characteristic parameter called the pitting potential value (Ep). Although Ep is governed by a number of factors, including alloy composition, metallurgical history, and the corrosive environment, the strongest effect on Ep is produced by certain additives that differ from the…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Further neighbor magnetic exchange interaction in a novel pseudolinear tetramer of copper(II)

B. Chiari、O. Piovesana、T. Tarantelli 等 4 位作者1993-10-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFurther neighbor magnetic exchange interaction in a novel pseudolinear tetramer of copper(II)B. Chiari, O. Piovesana, T. Tarantelli, and P. F. ZanazziCite this: Inorg. Chem. 1993, 32, 22, 4834–4838Publication Date (Print):October 1, 1993Publication History Published online1…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchElectron Spin Resonance Studies

Computation of Microstructure Utilizing Young Measure Representations

R. A. Nicolaides、Noel J. Walkington1993-10-01Journal of Intelligent Material Systems and Structures

An algorithm is proposed for the solution of non-convex variational problems. In order to avoid representing highly oscillatory functions on a mesh, an associated Young measure, which characterizes such oscillations, is also approximated. Sample calculations demonstrate the viability of this approach.

Shape Memory Alloy TransformationsTopology Optimization in EngineeringComposite Material Mechanics

Pitting Corrosion of Electrodeposited Aluminum‐Manganese Alloys

Thomas P. Moffat、Gery R. Stafford、Daniel E. Hall1993-10-01Journal of The Electrochemical Society

The corrosion behavior of a series of electrodeposited Al‐Mn alloys has been investigated. Three different microstructures were examined. A supersaturated face‐centered cubic (fcc) structure was produced with up to 5 atomic percent (a/o) Mn. Deposits containing 5–22 a/o Mn were composed of a glassy phase in combinatio…

Electrodeposition and Electroless CoatingsAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Residual Stresses in Fiber‐Reinforced Ceramics due to Thermal Expansion Mismatch

Meinhard Kuntz、Bernhard Meier、Georg Grathwohl1993-10-01Journal of the American Ceramic Society

Principles for the calculation of residual stresses due to thermal expansion mismatch and previous solutions are reviewed. A general model for this subject is proposed. Considering the effective thermoelastic properties of a unidirectional composite in axial and transverse directions allows a more comprehensive treatm…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesComposite Material Mechanics

Fabrication of organic nanocrystals for electronics and photonics

Hari Singh Nalwa、Atsushi Kakuta、Akio Mukoh 等 8 位作者1993-10-01Advanced Materials

Abstract We have presented a simple technique for the fabrication of nanocrystals of organic molecules and polymers and have shown that it is possible, using the liquid‐phase technique, to fabricate organic nanocrystals ranging in size from 10 nm to 1 μm by manipulating the preparative conditions. In particular, nanoc…

Organic Electronics and PhotovoltaicsQuantum Dots Synthesis And PropertiesLuminescence and Fluorescent Materials

Fluoride-bridged dimers: binuclear copper(II) complexes and iron(III)-copper(II) assemblies

Sonny C. Lee、R. H. Holm1993-10-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFluoride-bridged dimers: binuclear copper(II) complexes and iron(III)-copper(II) assembliesSonny C. Lee and R. H. HolmCite this: Inorg. Chem. 1993, 32, 22, 4745–4753Publication Date (Print):October 1, 1993Publication History Published online1 May 2002Published inissue 1 Octo…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesInorganic Fluorides and Related Compounds

An EAM simulation of the alpha - gamma iron interface

Zhan Yang、R. A. Johnson1993-10-01Modelling and Simulation in Materials Science and Engineering

The embedded atom method was used for the design of an atomic potential model for the simulation of the alpha - gamma iron interface. The model takes the form of three cubic expressions covering different ranges, and is normalized to give equilibrium to the two-body potential as well as to the embedding function at th…

Fusion materials and technologiesNuclear Materials and Propertiesnanoparticles nucleation surface interactions

Fatigue of AZ91E-T6 Cast Magnesium Alloy

D. L. Goodenberger、R. I. Stephens1993-10-01Journal of Engineering Materials and Technology

The purpose of this research was to obtain room temperature fatigue behavior of AZ91E-T6 cast magnesium alloy and to determine if commonly used models that depict fatigue behavior are applicable to this cast alloy. Axial strain-controlled fatigue behavior using cylindrical specimens were employed to determine low cycl…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Determination of attenuation lengths of photoelectrons in aluminium and aluminium oxide by angle‐dependent x‐ray photoelectron spectroscopy

Philippe Marcus、C. Hinnen、I. Olefjord1993-10-01Surface and Interface Analysis

Abstract Angle‐dependent x‐ray photoelectron spectroscopy (AD‐XPS) measurements have been carried out on thin aluminium oxide layers formed on pure aluminium by oxidation in oxygen at 25°C and at 250°C. The amounts of oxygen of the oxide overlayers were measured by nuclear reaction analysis (NRA). The equipment thickn…

Corrosion Behavior and InhibitionX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Polarization response of crystals with structural and ferroelectric instabilities

Е. В. Балашова、A. K. Tagantsev1993-10-01Physical review. B, Condensed matter

A simple phenomenological model with two coupled structural and ferroelectric order parameters is under consideration. The small-signal dielectric response, dielectric response to a strong electric field (hysteresis phenomena included), and the phase diagram in the presence of the bias field are analyzed in the framew…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSolid-state spectroscopy and crystallography