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Evaporation Behavior of SiO<SUB>2</SUB> in N<SUB>2</SUB>-O<SUB>2</SUB>-H<SUB>2</SUB>O Atmospheres

Takao Nakagiri、Kazuya Kurokawa2004-01-01MATERIALS TRANSACTIONS

In order to clarify the influence of water vapor on evaporation and crystallization of an amorphous SiO2 scale formed on SiO2-formers, fused silica was exposed for up to 49 h at 1373—1673 K in N2-O2-H2O atmospheres. The water vapor concentration was regulated to 19.6 and 46.7% (vol%). Under conditions of low water vap…

Advanced ceramic materials synthesisGlass properties and applicationsSilicon Nanostructures and Photoluminescence

Electrochemical Behavior of Gallium Hexacyanoferrate Film Directly Modified Electrode in a Cool Environment

Ali Eftekhari2004-01-01Journal of The Electrochemical Society

Electrochemistry of gallium hexacyanoferrate (GaHCF) as an analogue of prussian blue having a high-potential redox system was studied. A thin film of GaHCF was directly generated on a Ga substrate surface to fabricate a modified electrode. Electrochemical behavior of the modified electrode was studied at a typical coo…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

The Effect of pH on the Topography of Porphyrins in Lipid Membranes

I. N. Bronshtein、Kevin M. Smith、Benjamin Ehrenberg2004-01-01Photochemistry and Photobiology

The effect of the acidity of the environment on the topography and photophysics of sensitizer molecules in homogeneous solutions, and when embedded in a lipid microenvironment, was studied. Four hematoporphyrin (HP) analogs were studied, which have chemical "spacers" of varying lengths between the chromophoric tetrapy…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesProtein Interaction Studies and Fluorescence Analysis

Dielectric Properties of a Nematic Binary Mixture

Shila Garg、Tom Spears2004-01-01Molecular Crystals and Liquid Crystals

In this paper, a phase diagram is developed for the molar mixtures of nematic liquid crystals of 5CB and MBBA. In order to understand the interaction of the two systems, dielectric permittivities ˜‖ and ˜⊥ were measured for mixtures of various concentrations. The usual assumption is that in the absence of chemical rea…

Cold Atom Physics and Bose-Einstein CondensatesMaterial Dynamics and PropertiesTheoretical and Computational Physics

Grain Boundary Energy and Atomic Structure of <110> Symmetric Tilt Boundaries in Copper

Naoki Takata、Ken‐ichi Ikeda、Fuyuki Yoshida 等 5 位作者2004-01-01Journal of the Japan Institute of Metals and Materials

In order to clarify the correlation between the grain boundary energy and its atomic structure in copper, energy and atomic structure of ‹110› symmetric tilt boundaries in copper were simulated by molecular dynamics method. From the calculations, it was revealed that the grain boundary energy of ‹110› symmetric tilt b…

Microstructure and mechanical propertiesCopper Interconnects and ReliabilitySurface and Thin Film Phenomena

Fluorescence from fluorescent dye‐based polyurethane ionomer(II)

C. L. Wang、Z. J. Zhang、Y. M. Kuo 等 4 位作者2004-01-01Polymers for Advanced Technologies

Abstract The reaction of 6‐amino‐2(2‐hydroxy‐2‐phenyl‐ethyl)benzo[de]isoquinoline‐1,3‐dione with toluene diisocyanate and other additives to form the structure of the fluorescent dye‐based polyurethane (PU) ionomer has been proven by infrared (IR) spectroscopy. In aqueous solution, the fluorescence performance for the…

Polymer composites and self-healingOxidative Organic Chemistry ReactionsSynthesis of Indole Derivatives

Formation, Absorption and Emission Spectra of Cr4+ Ions in Li2O-SiO2 System Transparent Glass-Ceramics

Shigeki MORIMOTO2004-01-01Journal of the Ceramic Society of Japan

The formation mechanism, optical absorption and emission spectra of Cr4+ ions-containing Li2O-SiO2 system transparent glass-ceramics were investigated. In this material, the main crystalline phase was Li2O•2SiO2, and the percent crystallinity and crystal size were 67-72 and 20-33 nm, respectively. The remarkable chang…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPigment Synthesis and Properties

Synthesis and Characterization of Nanocomposite of Multi-Walled Carbon Nanotube and Polyaniline Nanoparticle

S. J. Park、Sung Young Park、M. S. CHO 等 5 位作者2004-01-01Molecular Crystals and Liquid Crystals

We synthesized multi-walled carbon nanotube(MWNT)/polyaniline(PANI)nanocomposites from an oxidative dispersion polymerization using poly(vinyl alcohol)(PVA)as a polymeric stabilizer. Purified MWNT whose metallic catalysts have been removed in acidic media was applied. The formation of nanocomposites and their morpholo…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesConducting polymers and applications

Magnetostriction of Fe-Ga-B Alloys in Amorphous and Crystallized States

Takeshi Kubota、Akihisa Inoue2004-01-01MATERIALS TRANSACTIONS

A ternary (Fe0.82Ga0.18)85B15 alloy was vitrified by melt spinning at wheel velocities of over 28.5 m/s. Two exothermic peaks were observed at onset temperatures of 692 K and 787 K. The melt-spun amorphous alloy ribbon exhibits saturation magnetostriction of +30 × 10−6 at the field of 80 kA/m. The magnetostriction inc…

Microstructure and Mechanical Properties of SteelsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

UPS of Boron-Sulfur Co-Doped, n-Type Diamond

Sreeram Vaddiraju、Sally Eaton‐Magaña、John A. Chaney 等 4 位作者2004-01-01Electrochemical and Solid-State Letters

The band structure of n-type diamond samples co-doped with boron and sulfur was studied using ultraviolet photoelectron spectroscopy (UPS) and Mott-Schottky analysis. The results show that the Fermi energy of the co-doped diamond is about 0.8-1.9 eV above the Fermi level of boron-doped diamond. The electron affinities…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Effect of Partial Substitutions of Rare-earth Metals for Na-site on the Thermoelectric Properties of Na<SUB><i>x</i></SUB>Co<SUB>2</SUB>O<SUB>4</SUB> Prepared by the Polymerized Complex Method

Tomoya Nagira、Mikio Ito、Shigeta Hara2004-01-01MATERIALS TRANSACTIONS

Polycrystalline (Na1−yMy)xCo2O4 (M=Nd, Sm, Dy and Yb; y = 0.01∼0.05) samples were synthesized by a polymerized complex method. The effects of partial substitution of rare-earth metals for a Na-site on the thermoelectric properties of NaxCo2O4 were investigated, and their differences with the sample prepared by a conve…

Advanced Thermoelectric Materials and DevicesTransition Metal Oxide NanomaterialsThermal Expansion and Ionic Conductivity

High pressure–high temperature phase diagram of InSe

G. Ferlat、D. Martínez‐García、A. San Miguel 等 5 位作者2004-01-01High Pressure Research

By combining X-ray diffraction and X-ray absorption spectroscopy, the structural evolution of the InSe alloy has been explored up to 3.3 GPa and 1500 K with the use of the Paris–Edinburgh large volume cell. These conditions allowed us to study the solid and the liquid states and to measure the pressure evolution of th…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Model Experiment of Particle Engulfment into the Solidifying Shell under Fluid Flow

Hideyuki Yasuda、Itsuo Ohnaka、Hideaki Jozuka2004-01-01ISIJ International

A model experiment was performed to investigate movement of inclusions near the solid wall and engulfment into the solidifying front. Polystyrene particles (100 μm in diameter) were suspended in flowing melts (water, 20 mass% NaCl aqueous solution and succinonitrile). As the average flow velocity increased, number of…

Textile materials and evaluations

A General Thermo-Mechanical Shape Memory Alloy Model: Formulation and Applications

Sanjay Choudhry2004-01-01AIP conference proceedings

A general purpose shape memory alloy model has been developed and implemented in MSC.Marc 2003. This model is based on a phenomenological model that provides a description of a wide range of the observed behavior, which is tractable from both analytical and computational viewpoint. The present model describes the deve…

Shape Memory Alloy Transformations

XPS Study of Carbyne-Like Carbon Films

Teruaki Danno2004-01-01AIP conference proceedings

X‐ray photoelectron spectra (XPS) of carbyne‐like carbon (CLC) film obtained by the polymer reaction route were measured and analysed. Dehydrohalogenation reaction was carried out effectively regardless of the starting precursors. Cls core‐level spectrum of CLC film shows the anomalous lowest peak maxima at 282.6 eV c…

Diamond and Carbon-based Materials ResearchFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

The Definitive Guide to Plone

Andy McKay2004-01-01Apress eBooks

This unique guide to Plone covers everything from installing Plone (on Mac OS X, Windows, and Linux) to writing code for the system. As part of the Apress library of Python programming and content man

Engineering and Material Science ResearchChemical and Environmental Engineering Research

Reconstruction of the trophic development of lake krakower obersee (mecklenburg, germany) by means of sediment- diatom- and pollen-analysis

Thomas Hübener、Walter Dörfler2004-01-01OpenAlex

Changes in composition of diatom (Bacillariophyceae) communities and pollen content were analyzed in two cores from the lake Krakower See, Mecklenburg-Vorpommern, Northern Germany. Based on the pollen stratigraphy, a time-depth-curve was built that allowed an estimate of the rate of sedimentation. The pollen curves, e…

Geology and Paleoclimatology ResearchAquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae Research

Influence of Reformed Gas Composition on HCCI Combustion Engine System fueled with DME and H2-CO-CO2 which are Onboard-reformed from Methanol Utilizing Engine Exhaust Heat

Toshio Shudo、Takehiro TAKAHASHI2004-01-01TRANSACTIONS OF THE JAPAN SOCIETY OF MECHANICAL ENGINEERS Series B

One of the authors has proposed an HCCI combustion engine system that was fueled with dimethyl ether (DME) with a high cetane number and methanol-reformed gas (MRG) with a high anti-knock property in the previous research. In the system, both DME and MRG are to be produced from methanol by onboard-reformers utilizing…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Characterization of Ceramic Matrix Composite Fasteners Exposed in a Combustor Linear Rig Test

Michael J. Verrilli、David N. Brewer2004-01-01Journal of Engineering for Gas Turbines and Power

Combustion tests on SiC/SiC CMC components were performed in an aircraft combustion environment using the rich-burn, quick-quench, lean-burn (RQL) sector rig. SiC/SiC fasteners were used to attach several of these components to the metallic rig structure. The effect of combustion exposure on the fastener material was…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesHigh-Velocity Impact and Material Behavior

Effect of Impurities on Interfacial Void Formation in Aluminum

Renchun Huang、Kurt R. Hebert、Thomas Gessmann 等 4 位作者2004-01-01Journal of The Electrochemical Society

The effect of impurities on formation of interfacial metallic voids, during uniform dissolution of aluminum in 1 M NaOH, was investigated. These voids are thought to act as initiation sites for pitting corrosion, and were previously shown to be formed by NaOH dissolution. Samples of three different bulk purities were…

Semiconductor materials and devicesCopper Interconnects and Reliability