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Polyelectrolyte multilayer capsules: nanostructure and visualisation of nanopores in the wall

Vladislav Krzyžánek、Nora Sporenberg、Ulrike Keller 等 6 位作者2011-01-01Soft Matter

Hollow polymeric capsules prepared from Layer-by-Layer coating of colloidal templates with polyelectrolyte multilayers are promising materials for drug delivery and release applications. Details of the wall structure arising from the core dissolution process are investigated by high resolution scanning electron micros…

Polymer Surface Interaction StudiesBlock Copolymer Self-AssemblyDendrimers and Hyperbranched Polymers

Equilibrium State of Anatase to Rutile Transformation for Titanium Dioxide Film Prepared by Ultrasonic Spray Pyrolysis Technique

Ghassem Kavei、Auppatham Nakaruk、Charles Chris Sorrell2011-01-01Materials Sciences and Applications

Titanium dioxide thin films were deposited on (0001) α-quartz substrate by spray pyrolysis method. The method which an aerosol of Titanium Butoxide, generated ultrasonically, was sprayed on the substrate at temperature of 400°C, kept at this temperature for periods of 3, 13, 19 and 39 hours. The developed films at a c…

Catalytic Processes in Materials ScienceChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Linking [Fe III 3 ] triangles with “double-headed”phenolic oximes

Kevin Mason、John Chang、Elena Garlatti 等 10 位作者2011-01-01Chemical Communications

The use of "double-headed" phenolic oximes produces a trigonal antiprismatic [Fe(III)(3)](2) cluster with an "internal cavity" filled with an additional Fe(3+) ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Studying electronic transport in polyazulene–ionic liquid systems using infrared vibrational spectroscopy

Anna M. Österholm、Pia Damlin、Carita Kvarnström 等 4 位作者2011-01-01Physical Chemistry Chemical Physics

This paper presents an in situ spectroelectrochemical characterization of polyazulene (PAz) and PAz-C(60) composite films using Fourier Transform Infrared Attenuated Total Reflection (FTIR-ATR) spectroscopy. In situ FTIR-ATR spectra were recorded simultaneously as the films were charged and discharged electrochemicall…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Comment on “Transport and Electrochemical Properties and Spectral Features of Non-Aqueous Electrolytes Containing LiFSI in Linear Carbonate Solvents” [J. Electrochem. Soc., 158, A74 (2011)]

Johan Scheers、Patrik Johansson2011-01-01Journal of The Electrochemical Society

Comment on “Transport and Electrochemical Properties and Spectral Features of Non-Aqueous Electrolytes Containing LiFSI in Linear Carbonate Solvents” [J. Electrochem. Soc., 158, A74 (2011)], Scheers, J., Johansson, P.

Ionic liquids properties and applicationsConducting polymers and applicationsChemical and Physical Properties in Aqueous Solutions

The effect of the stretching of PLA extruded films on their crystallinity and gas barrier properties

Alain Guinault、Gary Menary、Cécile Courgneau 等 7 位作者2011-01-01AIP conference proceedings

Driven by environmental concerns, new polymers based on renewable resources are arriving on the market to replace conventional polymers, obtained from petroleum, for different applications like food packaging. One of the most prominent polymers among these materials is poly(lactic acid) (PLA), a biodegradable, thermop…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionAdditive Manufacturing and 3D Printing Technologies

Tuning the frustration between SmA- and SmC-promoting elements in liquid crystals with ‘de Vries-like’ properties

Qingxiang Song、Dorothee Nonnenmacher、Frank Gießelmann 等 4 位作者2011-01-01Chemical Communications

Smectic liquid crystals with 'de Vries-like' properties are characterized by a maximum layer contraction of ≤1% upon transition from the non-tilted SmA phase to the tilted SmC phase. We show herein that one can systematically increase the 'de Vries-like' character of a smectic liquid crystal by tuning the frustration…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationPlant Reproductive Biology

Polymerization of polycarbosilanes in high internal phase emulsions for the synthesis of macroporous silicon carbide catalysts (polyHIPE-SiC)

Robert Frind、Martin Oschatz、Stefan Kaskel2011-01-01Journal of Materials Chemistry

A new method for the preparation of macroporous silicon carbide using a polyHIPE approach is presented (polyHIPE = polymerized High Internal Phase Emulsion). A liquid preceramic precursor is copolymerized with styrene and the crosslinker divinylbenzene in different ratios and two different initiators. The resulting PC…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisPickering emulsions and particle stabilization

Bio-based plastic a way for reduce municipal solid waste

Shahrzad Khoramnejadian、Shahrzad Khoramnejadian、Jamileh Jamali Zavareh 等 5 位作者2011-01-01Procedia Engineering

There are many ways to reduce plastic waste in the environment. Bio-based plastic could be a best solution for sustainable environment. In this article bio-based plastic were prepared. Potato starch and corn starch as a biopolymer blending with polyethylene. Samples buried into soil for eight months and put in aerated…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionGraphene and Nanomaterials Applications

Precipitation behavior of highly Sr-doped LaPO4 in phosphoric acid solutions

Naoyuki Hatada、Yoshitaro Nose、Akiko Kuramitsu 等 4 位作者2011-01-01Journal of Materials Chemistry

The precipitation condition of LaPO4 in phosphoric acid solution was investigated under both atmospheric and humidified conditions. The crystal morphology, Sr doping level, H2O incorporation, and high temperature stability of Sr-doped LaPO4 precipitates were also analyzed. Increasing pH2O from 0.01 to 1 atm extends th…

Luminescence Properties of Advanced MaterialsThermal and Kinetic AnalysisNuclear materials and radiation effects

Influence of backbone rigidity on the surface rheology of acrylic Langmuir polymer films

Laura R. Arriaga、Francisco Monroy、D. Langévin2011-01-01Soft Matter

We present an experimental study on the surface rheology of ultrathin films of poly(tert-butylacrylate) (PTBA) and poly(tert-butylmethacrylate) (PTBMA) for which steric hindrance imposed by the methyl group leads to a large intrinsic rigidity of the polymer chain. Whilst PTBA films show weak temperature dependence, PT…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Comparative assembly of colloidal quantum dots on surface templates patterned by plasma lithography

Yongliang Yang、Justin Volmering、Michael Junkin 等 4 位作者2011-01-01Soft Matter

Plasma lithography is a template-guided self-assembly nanomanufacturing strategy for creating functional engineering devices using nanoscale and molecular building blocks. To elucidate the plasma lithography manufacturing process, the comparative binding of colloidal quantum dots on plasma patterned surface templates…

Gold and Silver Nanoparticles Synthesis and ApplicationsPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

A Biodegradable and Biocompatible Drug-Delivery System Based on Polyoxalate Microparticles

Eunyong Lee、Se-Ho Kim、Kyeongyeol Seong 等 7 位作者2011-01-01Journal of Biomaterials Science Polymer Edition

Drug delivery using biodegradable polymeric microparticles is becoming an important means of delivering therapeutic agents. In this work, we describe polyoxalate microparticles as a biodegradable and biocompatible protein drug-delivery system. Polyoxalate was synthesized from a polycondensation reaction between oxalyl…

biodegradable polymer synthesis and propertiesRNA Interference and Gene DeliveryElectrospun Nanofibers in Biomedical Applications

Controlled nanostructures for applications in catalysis

Ferdi Schüth2011-01-01Physical Chemistry Chemical Physics

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Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Aspects of the Electrocaloric Behavior of Ferroelectric Thin Films: A Review of the Predictions of the Landau-Ginzburg Theory

J. Zhang、A. A. Heitmann、S. P. Alpay 等 4 位作者2011-01-01Integrated ferroelectrics

A thermodynamic model is used to investigate the electrocaloric response of thin film perovskite ferroelectrics under the influence of differing electrical, thermal and mechanical boundary conditions including bias and driving field, temperature, lateral clamping and misfit strain. A comparison of the electrothermal p…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Ordered deposition of Pd nanoparticles on sodium dodecyl sulfate-functionalized single-walled carbon nanotubes

Zhenquan Tan、Hiroya Abe、Satoshi Ohara2011-01-01Journal of Materials Chemistry

We report here a novel chemical solution method to site-selectively deposit and arrange palladium (Pd) nanoparticles (NPs) on single-walled carbon nanotubes (SWCNTs). Sodium dodecyl sulfate (SDS) formed supramolecular self-assemblies on the SWCNTs. The SDS then acted as adsorption sites for Pd(II) ions. Pd(II) was red…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

A Poloxamine–Polylysine Acrylate Scaffold for Modular Tissue Engineering

Ema C. Ciucurel、Michael V. Sefton2011-01-01Journal of Biomaterials Science Polymer Edition

A new polymer, poloxamine-polylysine acrylate (PPA), was synthesized for tissue-engineering applications. Polylysine was used to confer endothelial cell attachment properties to the poloxamine-based polymer, while the acrylate groups made it photo-cross-linkable. The PPA polymer was synthesized in three reaction steps…

Advanced Polymer Synthesis and CharacterizationElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

The growth of single crystal silver wires at the nitrobenzene|water interface

Ulrich Hasse、Gottfried J. Palm、Winfried Hinrichs 等 5 位作者2011-01-01Physical Chemistry Chemical Physics

Single crystal silver wires can be grown at the nitrobenzene|water interface when silver ions dissolved in the aqueous phase are reduced by decamethyl ferrocene dissolved in the nitrobenzene phase. The successful growth of these wires depends on a number of experimental conditions, most prominently on the concentratio…

Gold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Filtration-assembling colloidal crystal templates for ordered macroporous nanoparticle films

Qing Yu、Hongwen Huang、Ru Chen 等 6 位作者2011-01-01Journal of Materials Chemistry

Ordered macroporous nanoparticle thin films are achieved on porous substrates by combining ultrathin metal hydroxide nanostrands, colloidal crystal templates and the advantage of filtration technique. The preformed nanostrands layer plays two key roles for both uniform formation of hexagonal close-packed latex colloid…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing TechnologiesPickering emulsions and particle stabilization

Structural and Optical Properties of Annealed Porous Silicon Bragg Reflector for Thin-Film Crystalline Silicon Solar Cells

M. Grau、Nhat-Tai Nguyen、A. Straboni 等 4 位作者2011-01-01Energy Procedia

Implementing an annealed porous silicon Bragg reflector between a crystalline silicon thin-film solar cell and its cheap silicon substrate improves greatly its performance. Such a multilayer features indeed a high reflectivity, allowing the optical confinement which is essential for these cells. Annealing the porous s…

Thin-Film Transistor TechnologiesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence