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Effect of Particle Size and Size Distribution on Particulate Fouling in Enhanced Tubes

Ralph L. Webb、Louay M. Chamra1993-01-01Enhanced heat transfer/Journal of enhanced heat transfer

This paper describes the results of accelerated particulate fouling tests performed on different enhanced tubes and a plain tube. The key purpose of the tests was to investigate particulate fouling in practical heat exchanger systems where a mixture of particles exists in a flowing water stream. The applications consi…

Calcium Carbonate Crystallization and InhibitionMagnetic and Electromagnetic Effects

New lanthanide–hydrogen–transition metal compounds: [{(PMe 3 ) 3 WH 5 } 2 Yb·L 3 ] and [{(η-C 5 H 5 ) 2 NbH 2 } 2 Yb·L 3 ] where L 3 =(MeOCH 2 CH 2 ) 2 O

Malcolm L. H. Green、A.K. Hughes、Despo M. Michaelidou 等 4 位作者1993-01-01Journal of the Chemical Society Chemical Communications

The new lanthanide–hydrogen–transition metal compounds [{[PMe3)3WH5}2Yb·L3] and [{(η-C5H5)2NbH2}2Yb·L3], where L3=(MeOCH2CH2)2O, are prepared and their crystal structures determined.

Hydrogen Storage and MaterialsNuclear Materials and PropertiesInorganic Fluorides and Related Compounds

Force and Static Pressure Resulting From Airflow Through Screens

S. R. Kosmos、G. L. Riskowski、L. L. Christianson1993-01-01Transactions of the ASAE

Several clean agricultural screens were tested to determine force and static pressure drop across the screen created by airflow through the screen. Wind pressures on screens and static pressure drop across screens increased exponentially with increases in apparent air velocity. Fabric density, configuration, and dimen…

Textile materials and evaluationsGreenhouse Technology and Climate Control

Comparison of the species formed upon base hydrolyses of gallium(III) and iron(III) aqueous solutions: the possibility of existence of an [FeO4Fe12(OH)24(H2O)12]7+ Polyoxocation

Susan M. Bradley、Ronald A. Kydd1993-01-01Journal of the Chemical Society Dalton Transactions

The hydrolytic behaviour of iron(III) has been investigated. The infrared spectrum of the sulfate salt of a hydrolysed iron(III) solution was found to match that of a gallium sulfate that had been shown through magic angle spinning NMR spectroscopy in combination with powder X-ray diffraction studies to contain the Ga…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsChemical Synthesis and Characterization

Sorption and diffusion of water vapour in hydrogen-bonded polymer blends

Wen‐Ping Hsu、Raksha Li、Allan S. Myerson 等 4 位作者1993-01-01Polymer

Water vapour was used as a diffusional probe to study segmental mobility in hydrogen-bonded polymer blends. Modified polystyrenes containing 4-hydroxystyrene as comonomer units were blended with poly(methyl methacrylate). The diffusion coefficient of water decreased with increasing concentration of the diffusant. Clus…

Polymer crystallization and propertiesMembrane Separation and Gas TransportAdsorption, diffusion, and thermodynamic properties of materials

Application of the minimal principle to peptide structures

Charles M. Weeks、George T. DeTitta、Russ Miller 等 4 位作者1993-01-01Acta Crystallographica Section D Biological Crystallography

A new direct-methods procedure has been devised which consists of phase refinement via the minimal function, R(phi), alternated with Fourier summation and real space filtering. All phases are initially assigned values by computing structure factors for a randomly positioned set of atoms. These phases are then refined…

Crystallography and molecular interactionsChemical Synthesis and AnalysisEnzyme Structure and Function

Development of a Natural Degradable Polymer for Orthopaedic Use

Jonathan C. Knowles1993-01-01Journal of Medical Engineering & Technology

Currently, there are a large variety of degradable polymers available for use in surgery, which are generally based on blends and copolymers of poly(L-lactide) (PLLA) and poly(L-glycolide) (PGA). The major demand for these materials is for suturing of wounds, but the materials are also being developed for use in ortho…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and properties

The synthesis and first X-ray structures of nickel complexes of 1,2,5-thiadiazole-3,4-dithiolate

O.A. Dyachenko、С. В. Коновалихин、A. I. Kotov 等 7 位作者1993-01-01Journal of the Chemical Society Chemical Communications

The (R4N)2[Ni(tdas)2] complexes (tdas2–= 1,2,5-thiadiazole-3,4-dithiolate and R = Bu, Et) are prepared and characterized by X-ray crystallography, which reveals differences in their structure dependant on the size of the R4N cation.

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Partial discharge pattern classification using multilayer neural networks

L. Satish、Bharathi Gururaj1993-01-01IEE Proceedings A Science Measurement and Technology

Partial discharge measurement is an important means of assessing the condition and integrity of insulation systems in high voltage power apparatus. Commercially available partial discharge detectors display them as patterns by an elliptic time base. Over the years, experts have been interpreting and recognising the na…

Neural Networks and ApplicationsHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Mesomorphic polyelectrolytes based on side-chain liquid-crystalline polymers containing side-on fixed mesogens and oligooxyethylenic spacers

Virgil Percec、Dimitris Tomazos1993-01-01Journal of Materials Chemistry

The synthesis and characterization of side-chain liquid-crystalline polysiloxanes based on 4′-cyanobiphenyl-4-yl 2-(2-allyloxyethoxy)-4-(4-methoxybenzyloxy)benzoate (11-1), 4′-cyanobiphenyl-4-yl 2-[2-(2-allyloxyethoxy) ethoxy]-4-(4-methoxybenzyloxy) benzoate (11-2) and 4′-cyanobiphenyl-4-yl 2-{2-[2-(2-allyloxyethoxy)e…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationSynthesis and properties of polymers

Synthesis of AlN Powder by Carbothermal Reduction-Nitridation Method

Katsutoshi Komeya、Etsuo MITSUHASHI、Takeshi Meguro1993-01-01Journal of the Ceramic Society of Japan

The effect of additives on carbothermal reduction-nitridation was investigated for the preparation of AlN powders from the Al2O3-C-N2 system. According to the role of additives in nitridation, they were divided into three categories: “promote”, “have no effect” and “disturb”. In particular, CaF2 was an excellent nitri…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsSemiconductor materials and devices

Lanthanide β-diketonate glyme complexes exhibiting unusual co-ordination modes

Simon R. Drake、Abigail Lyons、David J. Otway 等 5 位作者1993-01-01Journal of the Chemical Society Dalton Transactions

The reaction of the hydrated β-diketonate complexes [Ln(tmhd)3(H2O)] with triglyme (2,5,8,11-tetraoxadodecane, L1) in hexane yielded the eight-coordinate triglyme-bridged dimeric complexes, [{Ln(tmhd)3}2L1](Ln = Eu 1 or Tb 2; tmhd = ButCOCHCOBut). In contrast, the reaction of [La(tmhd)3(H2O)] with tetraglyme, (2,5,8,1…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Polymer brush in contact with a mixture of solvents

John F. Marko1993-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymer brush in contact with a mixture of solventsJ. F. MarkoCite this: Macromolecules 1993, 26, 2, 313–319Publication Date (Print):January 1, 1993Publication History Published online1 May 2002Published inissue 1 January 1993https://pubs.acs.org/doi/10.1021/ma00054a010https…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Synthesis of Novel Water Soluble Phthalocyanines for Use in the Photosensitized Inactivation of Cancer Cells and Viruses

Ross W. Boyle、Johan E. van Lier1993-01-01Synlett

All articles of this category Syntheses of two novel classes of water soluble phthalocyanines substituted with propionic acid or O-ethyl, methyl-phosphonic acid groups are described. These compounds have applications in the field of photodynamic inactivation of cancer cells and viruses.

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Transformation of a kinetically controlled nematic phase of a linear polymer into one which is thermodynamically controlled via cyclization [1]

Virgil Percec、Masaya Kawasumi1993-01-01Liquid Crystals

The synthesis and characterization of cyclic main chain liquid-crystalline oligomers based on 1-(4-hydroxy-4′-biphenyl)-2-(4-hydroxyphenyl)butane (TPB) with 1,7-dibromoheptane (TPB-7(c)] are described. These oligomers were synthesized by the phase transfer catalysed polyetherification of TPB with 1,7-dibromoheptane un…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsSynthesis and properties of polymers

Shear-induced homogenization of semidilute solution of polymer mixture. II. Composition dependence

Kiyotoshi Fujioka、Tomoaki Takebe、Takeji Hashimoto1993-01-01The Journal of Chemical Physics

Shear-induced homogenization of semidilute solutions of polybutadiene (PB) and polystyrene (PS) with dioctylphthalate as a solvent was studied as a function of temperature T, polymer compositions at a fixed total polymer concentration of 3.3 wt%. The drop of homogenization temperature ΔTc(S) as measured in the increas…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

The dithiooxalate-bridged complex [Cr(C 2 O 2 S 2 ) 3 (NiL) 3 ][ClO 4 ] 3 (L = racemic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane): synthesis, crystal structure and magnetism

Minoru Mitsumi、Hisashi Ōkawa、Hiroshi Sakiyama 等 7 位作者1993-01-01Journal of the Chemical Society Dalton Transactions

The reaction of KCa[Cr(C2O2S2)3]·6H2O (C2O2S2= dithiooxalate) and [NiL][ClO4]2(L = racemic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) in the 1:3 molar ratio gave a chromium(III)trinickel(II) complex [Cr(C2O2S2)3(NiL)3][ClO4]3. It crystallizes with two dimethylformamide and two PriOH molecules in the…

Metal complexes synthesis and propertiesMagnetism in coordination complexesOrganometallic Compounds Synthesis and Characterization

Rietveld Analysis of Mechanically Activated Powdered Zinc Ferrite

V. Šepelák、K. Tkáčová、Alexandre I. Rykov1993-01-01Crystal Research and Technology

Abstract The mechanically induced changes in structure and magnetic properties of zinc ferrite were investigated by using the Rietveld analysis and Mössbauer spectroscopy. The formation of the spin arrangement in mechanically activated zinc ferrite is connected with a redistribution of the cations in the close‐packed…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsMagneto-Optical Properties and Applications

Defect structure of Y[sub 1-y]Ca[sub y]MnO[sub 3] and La[sub 1-y]Ca[sub y]MnO[sub 3]

Jeffry W. Stevenson、M. M. Nasrallah、H.U. Anderson 等 4 位作者1993-01-01IEEE Journal of Solid-State Circuits

Electrical conductivity and the Seebeck coefficient of compositions in the system Y[sub 1-y]Ca[sub y]MnO[sub 3] and La[sub 1-y]Ca[sub y]MnO[sub 3] were studied to determine the mechanism of electrical transport and defect structure. Electrical conduction appeared to occur via a small polaron hopping mechanism for comp…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

PSPICE computer modeling of hysteresis effects

S. Prigozy1993-01-01IEEE Transactions on Education

Recent versions of PSPICE, a personal computer implementation of the SPICE circuit simulation computer software program, have the capability of simulating the hysteresis loops of magnetic materials. In order to model the hysteresis loop of a particular manufacturer's magnetic core material, the values of five paramete…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques