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Isothermal crystallization of high density polyethylene and nanoscale calcium carbonate composites

Jiann‐Wen Huang2007-11-26Journal of Applied Polymer Science

Abstract High density polyethylene (HDPE) and calcium carbonate (CaCO 3 ) nanocomposites with maleic anhydride grafted HDPE (manPE) as a compatibilizer were prepared via compounding in a twin‐screw extruder. The CaCO 3 are well dispersed in the HDPE matrix from the observation of transmission electron microscope. The…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Concurrent substitutional and displacive phase transformations in Al-Mg-Si nanoclusters

Marijn A. van Huis、Marcel H. F. Sluiter、J. H. Chen 等 4 位作者2007-11-26Physical Review B

Al-Mg-Si nanoclusters embedded in aluminum transform through a delicate interplay of two characteristically distinct phase transformations: a diffusion-controlled substitutional transformation associated with solute enrichment and a swift displacive transformation involving collective shifts of columns of atoms once a…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Polarization Studies of Resonant Forbidden Reflections in Liquid Crystals

Paulo Fernandes、P. Barois、S. T. Wang 等 9 位作者2007-11-26Physical Review Letters

We report the results of resonant x-ray diffraction experiments performed on thick films of a biaxial liquid crystal made of achiral bent-core molecules. Polarization properties of forbidden reflections are observed as a function of the sample rotation angle phi about the scattering vector Q for the first time on a fl…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsMolecular spectroscopy and chirality

Surface segregation in CuPt alloys by means of an improved modified embedded atom method

M Schurmans、Jeroen Luyten、Claude Creemers 等 5 位作者2007-11-26Physical Review B

We present a procedure to investigate surface structures in CuPt alloys by combining the modified embedded atom method (MEAM) and the cluster expansion method (CEM). While the MEAM provides structural information for the description of extended anisotropic defects, the CEM improves the ability to correctly reproduce t…

Microstructure and mechanical propertiesQuasicrystal Structures and Propertiesnanoparticles nucleation surface interactions

The quest for secondary structure in chiral dendrimers

Susan E. Gibson、Jacob T. Rendell2007-11-26Chemical Communications

This review highlights important developments in the pursuit of chiral conformational order in dendritic structures. To be able to create and control chiral secondary structure necessitates a thorough understanding of how chiral subunits influence the macroscopic structure. Recent studies involve highly sophisticated…

Synthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers

Generation and detection of broadband airborne ultrasound with cellular polymer ferroelectrets

M. Dansachmüller、Ivan R. Minev、Petr Bartu 等 6 位作者2007-11-26Applied Physics Letters

Cellular polypropylene ferroelectrets are useful for broadband airborne ultrasound generation and detection up to the fundamental thickness extension resonance. The authors show that the coupling of ferroelectrets to air alters the electromechanical resonance of the foam. In an acoustical cavity, Fabry-Perot resonance…

High voltage insulation and dielectric phenomenaDielectric materials and actuatorsAerosol Filtration and Electrostatic Precipitation

Efficient Synthesis of Transition-Metal Phthalocyanines in Functional Ionic Liquids

S. M. S. Chauhan、Pratibha Kumari、Shweta Agarwal2007-11-26Synthesis

The synthesis of transition-metal phthalocyanines by the reaction of substituted and unsubstituted phthalonitriles in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and metal salts in functional imidazolium, pyridinium and ammonium ionic liquids at 100-140 °C, is reported. The best yields of metallated phtha…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Kondo effect and impurity band conduction inCo:TiO2magnetic semiconductor

Rajesh Ramaneti、J.C. Lodder、R. Jansen2007-11-26Physical Review B

The nature of charge carriers and their interaction with local magnetic moments in an oxide magnetic semiconductor is established. For cobalt-doped anatase $\mathrm{Ti}{\mathrm{O}}_{2}$ films, we demonstrate conduction in a metallic donor-impurity band. Moreover, we observe a clear signature of the Kondo effect in ele…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Synthesis and Characterization of Maize Starch Acetates and its Biodegradable Film

Junfeng Zhu、Guanghua Zhang、Lai Zhi-chao 等 4 位作者2007-11-26Polymer-Plastics Technology and Engineering

Starch acetates (SA) were synthesized by maize starch reacting with acetic acid/acetic anhydride, using sulfuric acid as catalyst. The biodegradable films were produced by thermal gelatinization of starch suspensions blending raw starch or SA with different degree of esterification (DS) and polyvinyl alcohol (PVA). Fo…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesPolysaccharides Composition and Applications

Vibrational study of auto‐assembling oligopeptides for biomedical applications

Anna Tinti、Michele Di Foggia、Paola Taddei 等 6 位作者2007-11-26Journal of Raman Spectroscopy

Abstract Eight alternating polar/non‐polar peptides derived from β‐sheet EAK‐16 were studied for their possible use as biomimetic materials, due to their self‐assembling properties. IR and Raman spectroscopies were used to investigate the influence of the sequence on the prevailing conformation of the peptide and its…

Chemical Synthesis and AnalysisAntimicrobial Peptides and ActivitiesSupramolecular Self-Assembly in Materials

Correlation between compositional fluctuation and magnetic properties of Tm-doped AlGaN alloys

Neeraj Nepal、S. M. Bedair、N. A. El-Masry 等 6 位作者2007-11-26Applied Physics Letters

The magnetic properties of Tm-doped AlxGa1−xN (0⩽x⩽1) alloys grown by solid-source molecular beam epitaxy were studied by hysteresis measurements and shown to exhibit ferromagnetic behavior at room temperature. The measured magnetization was strongly dependent on the Al content and reached a maximum for x=0.62. Previo…

ZnO doping and propertiesGaN-based semiconductor devices and materialsMetal and Thin Film Mechanics

Microstructural and Chemical Evolution of –CH[sub 3]-Incorporated (Low-k) SiCO(H) Films Prepared by Dielectric Barrier Discharge Plasma

Abhijit Majumdar、Gobind Das、N. Patel 等 6 位作者2007-11-26Journal of The Electrochemical Society

The present work focuses on the incorporation of radicals in organic SiCO(H) films with low dielectric constant . The SiCO(H) films were deposited by dielectric barrier discharge plasma method using a mixture of and Ar gases at different conditions (varying the frequency and pressure). The evolution of the film micros…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchCopper Interconnects and Reliability

Mechanical characterization of toughened polyamide‐6 blends with metallocene copolymers

S. López‐Quintana、C. Rosales、I. Gobernado‐Mitre 等 5 位作者2007-11-26Journal of Applied Polymer Science

Abstract The effectiveness as impact modifier of two in situ maleated metallocene copolymers, a metallocene polyethylene, (mPE1) and a metallocene ethylene‐propylene (mEPDM) and three commercial maleated copolymers (mPE2‐ g ‐MA, EPDM‐ g ‐MA, and mEPR‐ g ‐MA) were studied in binary and ternary blends carried out in an…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Effects of Volatility of Etch By-products on Surface Roughness During Etching of Metal Gates in Cl[sub 2]

Wan Sik Hwang、Byung Jin Cho、D.S.H. Chan 等 5 位作者2007-11-26Journal of The Electrochemical Society

The evolution of surface roughening during etching of TaN, TiN, Si, HfN, and IrO 2 in Cl 2 was studied.It was observed that surface roughness depended on self-bias voltage and pressure; lower surface roughness was obtained at higher bias voltage and lower pressure during etching of TaN, TiN, and Si in Cl 2 whose boili…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

Evidence for charge disproportionation in monoclinicEuNiO3fromFe57Mössbauer spectroscopy

Alexander Caytuero、H. Micklitz、M. M. Abd-Elmeguid 等 6 位作者2007-11-26Physical Review B

$^{57}\mathrm{Fe}$ M\"ossbauer spectra of $\mathrm{Eu}\mathrm{Ni}{\mathrm{O}}_{3}$ and doped with $1\phantom{\rule{0.3em}{0ex}}\mathrm{at.}\phantom{\rule{0.2em}{0ex}}%$ $^{57}\mathrm{Fe}$ recorded in the temperature range $300\phantom{\rule{0.3em}{0ex}}\mathrm{K}\ensuremath{\leqslant}T\ensuremath{\leqslant}480\phantom…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Quantum transport properties of carbon nanotube field-effect transistors with electron-phonon coupling

Hiroyuki Ishii、Nobuhiko Kobayashi、Kei Hirose2007-11-26Physical Review B

We investigated the electron-phonon coupling effects on the electronic transport properties of metallic (5,5)- and semiconducting (10,0)-carbon nanotube devices. We calculated the conductance and mobility of the carbon nanotubes with micron-order lengths at room temperature, using the time-dependent wave-packet approa…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Study on thermal expansion in injection‐molded isotactic polypropylene and thermoplastic elastomer blends

Michio Ono、K. Nakajima、Toshio Nishi2007-11-26Journal of Applied Polymer Science

Abstract The linear thermal expansion coefficients (CLTEs) along flow direction (FD) for the injection‐molded blends composed of isotactic polypropylene (iPP) and various ethylenic thermoplastic elastomers (TPEs) were investigated using a thermo‐mechanical analyzer. The iPP/TPE blends with higher comonomer contents in…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Foaming and Composites

On deformation and perforation of ship structures under ballistic impacts

Jeom Kee Paik、Su Hee Won2007-11-26Ships and Offshore Structures

This paper investigates the characteristics of the deformation and perforation on thin-walled structures under ballistic impacts based on the DYNA3D numerical simulations. Perforation mechanisms of plates and numerical modelling techniques to simulate the response of thin-walled structures under ballistic impacts are…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsElectromagnetic Launch and Propulsion Technology

Dimension of the spectrum of one-dimensional discrete Schrödinger operators with Sturmian potentials

Qinghui Liu、Jacques Peyrière、Zhi‐Ying Wen2007-11-26Comptes Rendus Mathématique

Damanik and collaborators (2007) gave the behavior for large coupling constant of the box dimension of the spectrum of a one-dimensional discrete Schrödinger operator whose potential is a Sturm sequence associated with the golden ratio. They also show that in this case the Hausdorff and box dimensions coincide (i.e. t…

Spectral Theory in Mathematical PhysicsGraph theory and applicationsQuasicrystal Structures and Properties

Effects of microcompounding process parameters on the properties of ABS/polyamide‐6 blends based nanocomposites

Güralp Özkoç、Göknur Bayram、Martin Quaedflieg2007-11-26Journal of Applied Polymer Science

Abstract Melt intercalation method was applied to produce acrylonitrile‐butadiene‐styrene/polyamide‐6 (ABS/PA6) blends based organoclay nanocomposites using a conical twin‐screw microcompounder. The blend was compatibilized using a maleated olefinic copolymer. The effects of microcompounding conditions such as screw s…

Polymer crystallization and propertiesPolymer Nanocomposites and Properties