Materials Literature
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A pulse-modulated plasma irradiation technique was applied to hydrogenation of ZnO. Three kinds of ZnO samples were employed to investigate the electronic state of hydrogen in ZnO. Secondary-ion-mass-spectroscopy analysis using isotope tracer revealed that the surface layer to 100 nm was doped with hydrogen after the…
Preface.Introduction, Safety and Instrumentation. The Chemical Dissolution of Silicon. The Semiconductor--Electrolyte Junction. The Electrochemical Dissolution of Silicon. Anodic Oxidation. Electrochemical Pore Formation. Microporous Silicon. Mesoporous Silicon. Macroporous Silicon. Applications.AppendicesSupplier Ref…
Polymer Science and Technology, Chonbuk National University, Chonju, Chonbuk 561-756, KoreaDepartment of Chemistry, Kunsan National University, Kunsan, Chonbuk 573-701, KoreaReceived November 27, 2001Keywords : Raman, Liquid crystal, Intermolecular interaction, Coil effect, Hydrogen bonding.IntroductionLiquid crystall…
Carbon nanotubes were placed in magnetic fields of 80.0 kOe at temperatures of 231 K and 314 K. Scanning electron microscopy showed that nanotubes were oriented with the tube axis parallel to the fields. It was also observed that the probability of the orientation became higher, when the temperature was raised from…
Photocrosslinkable chalcone-epoxy compound comprising 1,3-bis-(4-hydroxy-phenyl)-propenone was synthe-sized for fabricating the photo-alignment layer of liquid crystals. Chalcone group was introduced into the main chain unit of the epoxy oligomer. We observed a photodimerization behavior and an optical anisotropy of t…
The development of the dynamic glass transition in styrene-butadiene copolymers has been investigated by dielectric spectroscopy in the frequency range from 10 -2 to 10 6 Hz. Two processes were detected and attributed to the α - and β - relaxations. The α relaxation time has a non-Arrhenius temperature behavior that i…
Time-resolved infrared spectral measurements were made successfully for studying the microscopic mechanism of water-induced solid-state phase transitions of poly(ethylene imine) (PEI) in the hydration process at room temperature. The initial sample, obtained by cooling the melt under a dry atmosphere, showed the infra…
We have used ab initio quantum chemical techniques to compute the (13)C(alpha) and (13)C(beta) shielding surfaces for the 14 amino acids not previously investigated (R. H. Havlin et al., J. Am. Chem. Soc. 1997, 119, 11951-11958) in their most popular conformations. The spans (Omega = sigma(33) - sigma(11)) of all the…
Negatively charged polystyrene latex was synthesized, and a copolymer shell of 2-(methyl-2‘-chloropropionato)ethyl acrylate (HEA-Cl) and styrene was added, from which poly( N, N -dimethylacrylamide) (PDMA) was polymerized by atom transfer radical polymerization in aqueous suspension at room temperature. Increasing mon…
We actuated poly(vinyl chloride) (PVC) gel by applying a do field, and found localized creeping deformation, which induced swift, huge bending like a joint. The bending angle reached ca.150° at maximum at the field of 1000 V mm-1 with the velocity of ca. 90° s-1. The electric current was very small and in the range of…
Novel binary-phase WS 2 −C nanotubes were generated by pyrolyzing WO 3 -coated multiwalled carbon nanotubes in an H 2 S/N 2 atmosphere at 900 °C. The WS 2 coating acts as an anti-oxidizing agent.
We have prepared a new discotic nematogen, bearing one functional tail and five methoxy substituents. The corresponding side chain polymers, prepared via a polymer analogous esterification reaction, exhibited N D phases from 50 °C until degradation above 200 °C. Addition of equimolar amounts of various trinitrofluoren…
New heterospin complexes of Cu(hfac)2 (hfac, hexafluoroacetylacetonate) with pyrazole-substituted nitronyl nitroxides have been found that in the solid state exhibit thermally induced spin transitions analogous to spin crossover. For the first complex, [Cu(hfac)2Li-Pr], at room temperature, the Cu—OL distances, where…
Bimetallic monolayer-protected nanoparticles have been synthesized by the core metal galvanic exchange reaction of dodecylthiolate monolayer-protected metal (Ag, Pd, Cu) clusters with the more noble metal metal thiolate complexes Au I [SCH 2 (C 6 H 4 )C(CH 3 ) 3 ] and Pd II [S(CH 2 ) 11 CH 3 ) 2 ]. The bimetal nanopar…
Exchanger-OsO(4) catalysts are prepared by an ion-exchange technique using layered double hydroxides and quaternary ammonium salts covalently bound to resin and silica as ion-exchangers. The ion-exchangers with different characteristics and opposite ion selectivities are specially chosen to produce the best heterogene…
X-ray diffraction, resistivity, ac susceptibility and magnetization studies on La0.67Ca0.33Mn1-xRuxO3 (0 x < 0.1) were carried out. A significant increase in the lattice parameters indicated the presence of mixed valance state of Ru: Ru3+ and Ru4+. The resistivity of the doped compounds exhibited two features: a broad…
We present an experimental study of the polarization-dependent scattering of light from homogeneous and multisegment silver, gold, and nickel nanowires. The metallic nanowires are prepared within a polycarbonate membrane template by a combination of electroplating (gold and nickel) and electroless (silver) growth proc…
Methacryloyl end-functionalized block copolymers consisting of styrene and vinyl-2-pyridine were polymerized to poly(block co-macromonomer)s with a much higher main chain than side chain degree of polymerization. Like homo-polymacromonomers these molecules exhibit the structure of cylindrical brushes. Since the vinylp…
Single living yeast cells have been encapsulated by the alternate adsorption of oppositely charged polyelectrolytes. Exploiting fluorescence techniques, we provide evidence of the shell and cell integrity after the coating procedure. The most relevant result, however, is that, after encapsulation, cells preserve their…
Extensive simulations of PAMAM dendrimer generation 2 were performed at several pH conditions with explicit water molecules, to obtain proper conditions and validity for additional simulations without explicit water. Within the range of validity, simulation without water greatly extends the size and duration of practi…