Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The structure of crystalline porcine mitochondrial NADP-dependent isocitrate dehydrogenase (IDH) has been determined in complex with Mn2+-isocitrate. Based on structural alignment between this porcine enzyme and seven determined crystal structures of complexes of NADP with bacterial IDHs, Arg83, Thr311, and Asn328 wer…
Abstract The crystallization behavior of homogeneous and heterogeneous linear low‐density polyethylenes (LLDPE) was investigated by evaluating the characteristics of melting traces obtained by differential scanning calorimetry (DSC). Based on the isothermal experimental results, the concept of the effective nucleation…
Abstract Empirical formulas, which describe the air velocity and air temperature decays along the spinline of a dual slot die, are improved by introducing the influence of the ratio of die end width to air slot width. The thus‐improved empirical formulas include more die geometry parameters and are more accurate than…
The concepts of fracture mechanics that were derived prior to 1960 are applicable only to materials that obey Hooke’s law. Although corrections for small-scale plasticity were proposed as early as 1948, these analyses are restricted to structures whose global behavior is linear elastic.
The enzyme dienelactone hydrolase (DLH) has undergone directed evolution to produce a series of mutant proteins that have enhanced activity towards the non-physiological substrates alpha-naphthyl acetate and p-nitrophenyl acetate. In terms of steady-state kinetics, the mutations caused a drop in the K(m) for the hydro…
Abstract The crystallization behavior and morphology of polyoxymethylene (POM) and POM with polyamide (PA) were studied by polarized light microscopy (PLM), isothermal and nonisothermal differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). The isothermal crystallization kinetics were analyze…
We have investigated the partial densities of states of Sr 2 FeMoO 6 by applying soft x-ray emission spectroscopy (XES) to the Fe L, the Mo M and the O K edges. We discuss the results in the light of complementary measurements of the valence band by means of x-ray photoelectron spectroscopy (XPS) and first-principles…
Abstract Crystal growth rates of paracetamol (4‐hydroxyacetanilide) have been determined by seeded isothermal desupersaturation experiments at 16 °C in 23 different solvent mixtures of water + acetone + toluene. Parameters of different growth rate equations have been estimated by direct nonlinear optimization. At equa…
Abstract An in‐line capillary rheometer nozzle equipped to a conventional reciprocating 55‐ton injection molding machine was used to study the viscosity of single phase low density polyethylene (LDPE)/chemical blowing agent (CBA) solutions under high shear rate in the concentration range of 0 to 5 wt%. The steady shea…
Overpoling phenomenon has been observed in flux-grown Pb(Mg1∕3Nb2∕3)O3–(31–32)%PbTiO3 single crystals when poled above 0.4kV∕mm at room temperature. This leads to increased property variations at intermediate poling fields (0.6–0.8kV∕mm) and to the degradation of piezoelectric properties at high poling fields (⩾1.0kV∕…
In this letter, we report on the study of nanoscale polarization relaxation phenomena in polycrystalline PbZr0.4Ti0.6O3 films. Piezoresponse force microscopy (PFM) images of the as-grown sample reveal grains with a range of contrast, from fully white to gray to fully black. It is shown that this local change in the co…
Photopyroelectric high resolution ac calorimetry has been used to study the nematic-isotropic phase transition in octylcyanobiphenyl liquid crystal incorporating an aerosil soft gel. We have found that the sample is not in thermodynamic equilibrium in the two phase coexistence region, as shown by the frequency depende…
We perform experiments on two different dense colloidal suspensions with confocal microscopy to probe the relationship between local structure and dynamics near the glass transition. We calculate the Voronoi volume for our particles and show that this quantity is not a universal probe of glassy structure for all collo…
Reproduzierbar und einfach ist die hier beschriebene Synthese von mesoporösen dünnen Aluminiumoxidfilmen mit einem Polymertemplat. Die Filme haben eine Porosität von über 50 %, eine enge Porengrößenverteilung, eine hohe Zugänglichkeit und sind bis über 900°C thermisch stabil. Das anorganische Netzwerk besteht aus gesi…
Organic solvents are known to bring about dehydration of proteins, the molecular basis of which has remained uncharacterized. The dehydration effect in many cases leads to eventual unfolding of proteins through the macroscopic solvent effect. In some cases, the organic solvent molecules also bind to protein surfaces,…
Abstract Chemical bath deposition (CBD), a direct low cost technique that involves a cadmium salt solution, a complexing agent and a chalcogen source, was used to prepare CdSe semiconductor films. The most favourable conditions for acceptable quality CdSe films grown on glass were obtained. Commercially available micr…
Abstract The steady shear viscosity and dynamic viscoelastic properties of glass beads (GB) filled polycarbonate (PC) melts were studied at varying filler diameters and concentrations. The PC/GB composites containing small amounts of GB bore lower melt viscosity and dynamic modulus than those of pure PC at studied fre…
Pore and surface diffusion of carbon dioxide (CO(2)) and ethylene (C(2)H(4)) in the nanopores of ordered mesoporous silica fibers about 200 microm in length was measured by the transient gravimetric method. The experimentally determined pore diffusivity data, coupled with the porosity, pore size, and fiber length, are…
Abstract The influence of a new processing additive (particles of organically modified nanoclays) on the processibility of polyolefins in extrusion is studied. The equipment used includes an Instron capillary rheometer with two types of dies, namely capillary dies and special annular dies (Nokia Maillefer wire coating…
The synthesis, dual fluorescence, and fluoroionophoric behavior of two donor-sigma spacer-acceptor (D-s-A) compounds, trans-4-(N,N-bis(2-pyridyl)amino)methylstilbene (1H) and trans-4-(N,N-bis(2-pyridyl)amino)methyl-4'-cyanostilbene (1CN), are reported and compared to that of trans-4-(N,N-bis(2-pyridyl)amino)methyl-4'-…