Materials Literature
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A mechanistic investigation on the photocatalytic reduction of CO 2 with hexagonal CdS nanocrystallites prepared in N, N -dimethylformamide (DMF) was carried out from the standpoint of surface structures of the nanocrystallites. A remarkable increase of photocatalytic activity could be achieved by addition of excess C…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTChemistry Induced by Hydrodynamic CavitationKenneth S. Suslick, Millan M. Mdleleni, and Jeffrey T. RiesView Author Information Department of Chemistry University of Illinois at Urbana-Champaign 601 South Goodwin Avenue, Urbana, Illinois 61801 Cite this: J. Am. Chem. So…
Two effective computational approaches for the study of magnetic exchange interactions in large molecules are discussed and tested on a number of model systems, namely, broken-symmetry (BS) and single-determinant (SD) models. Both methods are based on the density functional theory (DFT) but exploit different approxima…
ADVERTISEMENT RETURN TO ISSUEPREVFeaturesNEXTPeer Reviewed: Boron-Doped Diamond Thin-Film Electrodes Diamond thin films could be an electrochemist's best friend. Jishou Xu, Michael C. Granger, Qingyun Chen, Jerzy W. Strojek, Tedd E. Lister, and Greg M. SwainCite this: Anal. Chemi. 1997, 69, 19, 591A–597APublication Da…
Thermogravimetric data for the decomposition of ammonium dinitramide (ADN) have been obtained under isothermal and nonisothermal conditions in order to determine the efficacy of different methods for analyzing the kinetics of solid-state reactions. A widely used model-fitting method gives excellent fits to the experim…
The crystallographic origins leading to the formation of polymer single crystals with highly unusual triangular shapes are analyzed. Triangular crystals are obtained: (a) for stereocomplexes of poly( l -lactide) (PLLA) and poly( d -lactide) (PDLA) crystallizing in a trigonal unit cell with R 3 c (or R -3 c ) symmetry.…
The oxidation of hydrogen on Ni/yttria‐stabilized zirconia (Ni/YSZ) is studied by impedance spectroscopy. The active thickness obtained is 20 μm or less. Conditions such as temperature, anodic overvoltage, electrode potential, and partial pressure are varied. Three distinct arcs are identified in impedance spectra, re…
Helical structures were confirmed for both the SmA b and SmBlue phases of banana-shaped molecular systems from observations of the microscopic fringe pattern and the selective reflection of blue color, respectively. X-ray and optical microscopy indicate that the helical axes in the SmA b and SmBlue phases are normal a…
The synthesis, characterization, thermal stability, optical spectroscopic, electronic structure, and second-order nonlinear optical (NLO) response of a series of donor−acceptor bis(salicylaldiminato)nickel(II) Schiff base complexes and the free ligand precursors are reported. The effect of the metal center in such com…
The geometrical and resolution corrections are derived that occur in the measurement of the integrated intensities of surface diffraction rods for the case of a six-circle diffractometer. Since the six-circle geometry entails as special cases the five-circle and the z-axis diffractometers, the results are valid for th…
We report on implementation and performance of the program IMD, designed for short range molecular dynamics simulations on massively parallel computers. After a short explanation of the cell-based algorithm, its extension to parallel computers as well as two variants of the communication scheme are discussed. We provi…
Series‐stacked, double‐layer carbon capacitors are slated to be used in electric vehicles for power management as well as in consumer electronics for memory backup and burst power. Nonaqueous electrolytes are preferred over aqueous electrolytes, since a wider voltage window can be accessed in the former electrolytes,…
A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N -hydroxyphthalimide (NHPI) and Co(OAc) 2 was developed. For instance, the oxidation of toluene was completed by NHPI combined…
The grain-size-dependent transport properties in the granular perovskite ${\mathrm{La}}_{0.85}{\mathrm{Sr}}_{0.15}{\mathrm{MnO}}_{3}$ have been investigated. A giant magnetoresistance (GMR) effect, similar to that observed in granular transition metals, and a crystal intrinsic colossal magnetoresistance (CMR) have bee…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUltrafast Studies of Electron Dynamics in Semiconductor and Metal Colloidal Nanoparticles: Effects of Size and SurfaceJin Z. ZhangView Author Information Department of Chemistry, University of California, Santa Cruz, California 95064 Cite this: Acc. Chem. Res. 1997, 30, 10,…
A purification procedure for single-wall carbon nanotubes (SWNTs) prepared by pulsed laser ablation is discussed, which separates coexisting carbon nanospheres (CNS), metal nanoparticles, polyaromatic carbons, and fullerenes from the SWNT fraction. The process involves the suspension of CNS, metal nanoparticles, and S…
Self-diffusion coefficients, D, have been measured in the glass forming liquids salol, glycerol, phenolphthaleine dimethyl ether (PDE), cresolphthaleine dimethyl ether (CDE), and ααβ-trinaphthylbenzene (TNB) in the supercooled regime. The NMR static magnetic field gradient technique was applied where D >10 -14 m 2 s -…
Abstract Nanocomposites obtained by casting a mixture of a latex and an aqueous suspension of cellulose whiskers have been studied. Their mechanical properties (e.g. shear modulus) are found to increase by more than three orders of magnitude in the rubbery state of the polymer matrix, when the whisker content is 6 wt%…
EPR spectra have been recorded in very high fields up to 25 T, and at high frequency up to 525 GHz, on a polycrystalline sample of $[{\mathrm{Mn}}_{12}{\mathrm{O}}_{12}{(\mathrm{C}\mathrm{H}}_{3}{\mathrm{C}\mathrm{O}\mathrm{O})}_{16}{(\mathrm{H}}_{2}{\mathrm{O})}_{4}{]\mathrm{\ensuremath{\cdot}}2\mathrm{C}\mathrm{H}}_…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron Spectroscopy Using Metastable Atoms as Probes for Solid SurfacesYoshiya Harada, Shigeru Masuda, and Hiroyuki OzakiView Author Information Department of Materials Science, Faculty of Engineering, Chiba University, Inage, Chiba 263, Japan, Department of Chemistry, Gra…