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Polytetrafluoroethylene (Teflon) Films Deposited by Pulsed Electron Deposition Technique for Use in Spintronics Devices

Vimlesh Chandra、S. Sundar Manoharan2008-06-26Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry

Thin films of polytetrafluoroethylene (PTFE) were deposited by pulsed electron deposition (PED) technique. X‐ray diffraction of the room temperature deposited film shows crystalline nature. The molecules are oriented with chain axis parallel to the substrate surface, and the film had preferential crystal orientation w…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Particle-swarm optimization of axially superresolving binary-phase diffractive optical elements

Toufic G. Jabbour、Stephen M. Kuebler2008-06-26Optics Letters

A particle-swarm optimization (PSO) algorithm was developed for designing binary-phase-only diffractive optical elements (DOEs) that superresolve the axially focused point-spread function. The method is based on vector diffraction theory to ensure solutions are valid under high-NA conditions. A DOE is identified that…

Orbital Angular Momentum in OpticsAdvanced optical system designOptical Coatings and Gratings

Model of plasmon excitations in a bundle and a two-dimensional array of nanotubes

Tibab McNeish、Godfrey Gumbs、Antonios Balassis2008-06-26Physical Review B

We calculate the plasma excitations in a bundle as well as a two-dimensional (2D) periodic array of aligned parallel multishell nanotubes on a substrate. The carbon nanotubes are oriented perpendicular to the substrate. The model we use for the system is an electron gas confined to the surface of an infinitely long cy…

Carbon Nanotubes in CompositesGraphene research and applicationsSilicon Nanostructures and Photoluminescence

G-band Variation of Individual Single-Walled Carbon Nanotubes under Torsional Strain

Bo Gao、Xiaojie Duan、Jin Zhang 等 6 位作者2008-06-26The Journal of Physical Chemistry C

Strain can effectively modulate the structure and properties of single-walled carbon nanotubes (SWNTs), and hence is an important aspect in their researches and applications. In this article, the effect of torsional strain on the G -band modes of individual SWNTs is reported. When torsional strain is induced by atomic…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

High Spin Polarizaion of Ferrimagnetic Heusler-type Alloys in Mn–Cr–Z System (Z = IIIb, IVb, Vb Elements)

Shinpei Fujii、M. Okada、Shoji Ishida 等 4 位作者2008-06-26Journal of the Physical Society of Japan

First-principle total-energy calculations show that a ferrimagnetic state is most stable in Mn 2 YZ (Y = Cr and Mn) with the Heusler structure and that among them there are highly spin-polarized ones with magnetic moments of 0, 1, and 2µ B per formula unit. Electronic structures of nonstoichiometric alloys suggest tha…

Magnetic Properties and ApplicationsMagnetic Properties of AlloysHeusler alloys: electronic and magnetic properties

Miniemulsion Copolymerization of Styrene and γ-Methacryloxypropyltrimethoxysilane: Kinetics and Mechanism

Zheng Cao、Guorong Shan、Gilles Févotte 等 5 位作者2008-06-26Macromolecules

The kinetics of the miniemulsion copolymerization of styrene (St) and γ-methacryloxypropyltrimethoxysilane (MPS) was investigated by studying the effects of the MPS/St weight ratio, the nature and amount of initiator, the suspension pH, and the surfactant concentration on the overall and individual monomer conversions…

Advanced Polymer Synthesis and CharacterizationSilicone and Siloxane ChemistryChemical Synthesis and Characterization

Molecular models for the smectic A–smectic C phase transition in a system of biaxial molecules

M. V. Gorkunov、M. A. Osipov2008-06-26Journal of Physics A Mathematical and Theoretical

A molecular theory of the smectic A–smectic C transition in a system of biaxial molecules is developed in the mean-field approximation. The influence of molecular biaxiality on the transition is considered in detail and it is demonstrated how the biaxial order parameters are induced by the tilt. It is shown that the o…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

A Rayleigh number based dendrite fragmentation criterion for detachment of solid crystals during solidification

Arvind Kumar、Pradip Dutta2008-06-26Journal of Physics D Applied Physics

Movement of solid crystals in the form of dendrite fragments causes severe macro-segregation in solidified products. Dendrite fragmentation in the developing mushy zone occurs as a result of remelting (causing dissolution) and subsequent breakage of dendritic side arms from the
\ndendritic stalks. An understanding…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaCrystallization and Solubility Studies

Stable Structures and Electronic Properties of the Oriented Bi Nanowires and Nanotubes from First-Principle Calculations

Jingshan Qi、Daning Shi、Jijun Zhao 等 4 位作者2008-06-26The Journal of Physical Chemistry C

We report the results of first-principle calculations on Bi nanowires and nanotubes oriented along the [012] direction. The shapes of the cross section have an important effect on the stability of Bi nanowires resulting from different reconstructions. Among the Bi nanowires studied, the most stable ones have the core−…

Graphene research and applications2D Materials and ApplicationsAdvanced Thermoelectric Materials and Devices

Construction of PbSe Hierarchical Superstructures via an Alkaline Etching Method

Shudong Zhang、Changzheng Wu、Zhengcui Wu 等 6 位作者2008-06-26Crystal Growth & Design

Various PbSe hierarchical superstructures, including the PbSe octopod hierarchitectures densely/loosely stacked by cubic building units, and PbSe windowlike hierarchitectures, have been achieved from the PbSe cubes by the alkaline etching methodology. This work indicates that the complicated hierarchical superstructur…

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Triangular PbS Nano-Pyramids, Square Nanoplates, and Nanorods Formed at the Air/Water Interface

Chang-Wei Wang、Hong-Guo Liu、Xiangtao Bai 等 8 位作者2008-06-26Crystal Growth & Design

PbS nanocrystals with different shapes were synthesized at the air/PbCl 2 aqueous solution interface via reaction between Pb 2+ and H 2 S gas under poly(9-vinylcarbazole) (PVK) thin films and characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), electron dif…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

The thickness evolution of orthorhombic lattice distortions in heteroepitaxial La0.67Ca0.33MnO3/NdGaO3(110)Orobserved by x-ray reciprocal space mapping

Guanyin Gao、Zhizhen Yin、Zhen Huang 等 5 位作者2008-06-26Journal of Physics D Applied Physics

La 0.67 Ca 0.33 MnO 3 (LCMO) films of 6–60 nm thickness were grown epitaxially on orthorhombic NdGaO 3 (1 1 0) Or (NGO) substrates by the pulsed laser deposition method. Like NGO, the films when relaxed should also have an orthorhombic structure that can be described by a pseudocubic perovskite unit, with the angle β…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

UV radiation effects on pigments, photosynthetic efficiency and DNA of an Antarctic marine benthic diatom community

Angela Wulff、MY Roleda、Katharina Zacher 等 4 位作者2008-06-26Aquatic Biology

The impact of ultraviolet radiation (UVR) on a semi-natural, soft-bottom diatom community from Potter Cove, King Georg Island, Antarctica, was investigated. The objective was to estimate the impact of UV-B (280 to 320 nm) and UV-A (320 to 400 nm) on photosynthetic efficiency, pigments, DNA damage and repair. The diato…

Marine and coastal ecosystemsMicrobial Community Ecology and PhysiologyDiatoms and Algae Research

Spectroscopic Analysis of Ligand Binding to Lanthanide−Macrocycle Platforms

James Kirby、Morgan L. Cable、Dana J. Levine 等 5 位作者2008-06-26Analytical Chemistry

A high-affinity, binary Eu(3+) receptor site consisting of 1,4,7,10-tetraazacyclododecane-1,7-diacetate (DO2A) was constructed with the goal of improving the detection of dipicolinic acid (DPA), a major component of bacterial spores. Ternary Eu(DO2A)(DPA)(-) complex solutions (1.0 microM crystallographically character…

Molecular Sensors and Ion DetectionRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Ferromagnetic Ge1−xMx (M = Mn, Fe, and Co) Nanowires

Yong Jae Cho、Chang‐Hyun Kim、Han Sung Kim 等 10 位作者2008-06-26Chemistry of Materials

We synthesized Ge and Ge 1− x M x (M = Mn, Co, and Fe, x ≤ 0.4) nanowires using the thermal vapor transport method. All of the nanowires consisted of single-crystalline Ge nanocrystals grown uniformly with the [111] direction. High-resolution X-ray diffraction showed no metal cluster formation for any of the Ge 1− x M…

ZnO doping and propertiesNanowire Synthesis and ApplicationsGa2O3 and related materials

Rheological Behavior of Immiscible PS/PMMA Blends during Dynamic Plasticating Extrusion

Weihua Luo、N. Q. Zhou、Xiangfang Peng2008-06-26International Polymer Processing

Abstract PS/PMMA blends were prepared using a twin screw extruder and then extruded using an electromagnetic dynamic plasticating extruder equipped with a specially designed split die. During dynamic plasticating extrusion, the dynamic rheological behavior of PS/PMMA blends was investigated. The extrudates were cooled…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Developing metal mesh filters for mid-infrared astronomy of 25 to 40 micron

Shigeyuki Sako、Takashi Miyata、Tomohiko Nakamura 等 6 位作者2008-06-26Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

We have developed bandpass filters for long mid-infrared astronomy in 25 to 40μm. Most of materials become opaque in wavelengths longer than 25μm. We have applied the metal mesh method to make filters of non-transparent materials. The mesh patterns are designed based on the FDTD calculations and fabricated by th…

Microwave Engineering and WaveguidesOptical Coatings and GratingsSuperconducting and THz Device Technology

The Zero Emission Carbon Concept (ZECA): Extents of Reaction with Different Coals in Steam/Hydrogen, Tar Formation and Residual Char Reactivity

Lu Gao、N. Paterson、Paul S. Fennell 等 5 位作者2008-06-26Energy & Fuels

A high pressure wire mesh reactor has been modified to investigate the reactions underlying the zero emission carbon concept (ZECA) process. This is a novel power generation concept that involves producing hydrogen from coal. An earlier paper has described the concept, the wire mesh reactor used for laboratory scale t…

Advanced Battery Technologies ResearchFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

Challenges to the Formation of Nano-cells in Foaming Processes

Zexiu Zhu、Chul B. Park、Jingbo Zong2008-06-26International Polymer Processing

Abstract This paper uses a finite element analysis to investigate the morphological changes of nano-cells in a polystyrene (PS) – CO 2 foaming system. The system was composed of a finite polymer melt with a central cell and eight surrounding cells. The computational domain was discretized using linear triangular eleme…

Phase Equilibria and ThermodynamicsInjection Molding Process and PropertiesPolymer Foaming and Composites

Synthesis, Structure, and Characteristics of Hyperbranched Polyterpene Alcohols

Toshifumi Satoh、Yuki Kinugawa、Masaki Tamaki 等 6 位作者2008-06-26Macromolecules

A novel series of bio-based hyperbranched polymers, i.e., hyperbranched polyterpene alcohols, were prepared by the cationic ring-opening polymerizations of citronellol oxide ( 1 ) and nopol epoxide ( 2 ) using boron trifluoride diethyl etherate (BF 3 ·OEt 2 ) as the catalyst. The polymerizations of 1 and 2 homogeneous…

RNA Interference and Gene DeliverySynthetic Organic Chemistry MethodsDendrimers and Hyperbranched Polymers