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New Route to the Introduction of Axial and Helical Chiral Units into Poly(arylene ether)s

Zhi Yuan Wang、Judy E. Douglas1997-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTNew Route to the Introduction of Axial and Helical Chiral Units into Poly(arylene ether)sZhi Yuan Wang and Judy E. DouglasView Author Information Department of Chemistry, Ottawa-Carleton Chemistry Institute, Carleton University, 112…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsSynthesis and properties of polymers

Use of carbon-coated particle fuels in PWR assemblies

Myung-Hyun Kim、Kang-Mog Bae、Young-Jin Kim1997-12-01Transactions of the American Nuclear Society

Pyro-carbon-coated fuel particles used in modular high-temperature gas-cooled reactor fuel rods have the potential to enhance fuel rod safety when they are packed in pressurized water reactor (PWR) fuel pellets. A fuel assembly design concept with new fuel pellets was introduced and its nuclear feasibility on PWR appl…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear and radioactivity studies

Clay minerals in recent sediments of the continental shelf and the Bay of Cádiz (SW Spain)

José Manuel Gutiérrez Mas、Alberto López-Galindo、F. Lopez-Aguayo1997-12-01Clay Minerals

Abstract The distribution of clay minerals in recent sediments on the continental shelf and in the Bay of Cádiz has been analysed as part of a wider study of sedimentary exchange between the continent and the continental margin. The clay minerals included in the muddy sediments consist mainly of illite, kaolinite, sme…

Geology and Paleoclimatology ResearchClay minerals and soil interactionsGeological and Geophysical Studies Worldwide

Investigation of the Solution Behavior of Organosoluble Aromatic Polyimides

Edward P. Savitski、Fuming Li、Sheng‐Hsien Lin 等 13 位作者1997-12-01International Journal of Polymer Analysis and Characterization

Two high-molecular-weight organosoluble aromatic polyimides having the same diamine, 2,2′-(trifluoromethyl)-4,4′-diaminobiphenyl diamine (PFMB), but different dianhydrides, 2,2′-bis(trifluoromethyl)-4,4′,5,5′-biphenyltetracarboxylic dianhydride (HFBPDA) and 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersTribology and Wear Analysis

Synthesis, structure and magnetic susceptibility of KCrP2O7, a potential antiferromagnetic magnetoelectric

Solène Gentil、Daniel Andreica、Marcos Luján 等 6 位作者1997-12-01Ferroelectrics

During the synthesis by flux evaporation in KC1 at 930°C of KCrIIPO4 an oxidation of chromium II was observed, leading to the formation of chromium pyrophophate KCrIIIP2O7. The crystal lattice of KCrIIIP2O7, was found to be of monoclinic centrosymmetric space group P21/c with a=7.3470(7), b=9.9090(10), c=8.1730(8)Å, β…

Crystal structures of chemical compoundsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Texture Analysis of LiF Thin Films Evaporated onto Amorphous Substrates at Different Temperatures

Paolo Emilio Di Nunzio、L. Fornarini、S. Martelli 等 4 位作者1997-12-01physica status solidi (a)

Polycrystalline thin LiF films thermally evaporated on amorphous substrates show different crystallite orientations depending on the substrate temperature during evaporation. The recording of direct diffraction pole figure shows that the LiF crystallites present a single crystal texture, which can be described as a 〈5…

ZnO doping and propertiesThin-Film Transistor TechnologiesGa2O3 and related materials

The two-step phase transition of titanite, CaTiSiO5: a Synchrotron radiation study

S. Kek、M. I. Aroyo、U. Bismayer 等 6 位作者1997-12-01Zeitschrift für Kristallographie - Crystalline Materials

Article The two-step phase transition of titanite, CaTiSiO5: a Synchrotron radiation study was published on December 1, 1997 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 212, issue 1).

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Thermische Zersetzung und Lösungskalorimetrie von Ammoniumsamariumchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Samarium Chlorides

C. Hennig、H. Oppermann1997-12-01Zeitschrift für Naturforschung B

Abstract We determined the decomposition equilibria of ammonium samarium chlorides (NH 4 ) 2 SmCl 5 and NH 4 Sm 2 Cl 7 by total pressure measurements and derived their thermody­ namical data from the decomposition functions. The enthalpies of formation were compared with the results of the solution calorimetry. The he…

Chemical and Physical Properties in Aqueous SolutionsThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Powder diffraction of cubic α-brass

J. H. L. Voncken、Th. W. Verkroost1997-12-01Powder Diffraction

X-ray powder diffraction data are reported for α-brass with the composition Cu: 63.44±0.04 wt %, Zn: 36.45±0.06 wt %. No valid reference card for this material is present in the JCPDS-ICDD database. The investigated brass composition is cubic ( Fm 3 m ) with a 0 : 3.69612±0.00014 Å, unit cell volume: 50.4938±0.0058 Å…

Advanced ceramic materials synthesisAdvanced materials and compositesX-ray Diffraction in Crystallography

Ozone Passivation Technique for Corrosive Gas Distribution System

Kunihiko Koike、Goichi Inoue、T Takata 等 4 位作者1997-12-01Japanese Journal of Applied Physics

A passivation technique using highly concentrated ozone has been developed for electropolished stainless steel tubings that supply corrosive gases. The strong oxidizing ability of ozone enables the inner surface to form an anticorrosive passivation film with thickness up to 60 Å under room temperature and atmospheric…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsAnodic Oxide Films and Nanostructures

Increasing filler concentrations in PVC compounds using CPE

Don A. Ventresca、Mark T. Berard1997-12-01Journal of Vinyl and Additive Technology

Abstract During times of rising resin prices, the PVC processor is forced to optimize his operations in order to reduce manufacturing costs. One option the processor has is to increse the filler concentration in order to reduce formulation costs. Chlorinated polyethylene (CPE), an uncrosslinked rubber impact modifier…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Viscous Sintering and Mechanical Properties of 3Y‐TZP‐Reinforced LAS Glass‐Ceramic Composites

Se Young Choi、Joon M. Ahn1997-12-01Journal of the American Ceramic Society

The densification of lithium aluminosilicate glass‐ceramic composites strongly depended on dispersed 3‐mol%‐Y 2 O 3 ‐tetragonal‐ZrO 2 ‐polycrystal (3Y‐TZP) content, rather than the crystallization of a parent glass phase. Because of the reaction between 3Y‐TZP and the glass phase, tetragonal‐ZrO 2 transformed to monoc…

Advanced ceramic materials synthesisGlass properties and applicationsNuclear materials and radiation effects

Secondary nucleation of sodium chlorate studied with the aid of asymmetric crystallization

Christoph Oliver Mayer、R. Lacmann1997-12-01Chemical Engineering & Technology

Abstract The size‐dependent breeding of sodium chlorate crystals can be determined by carrying out experiments with seed crystals of optical antipodes of different sizes that undergo absolutely identical experimental conditions. Small portions of right‐ and left‐handed seed crystals of different sizes were used. The n…

Enzyme Structure and FunctionCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Heat‐resistant anti‐corrosive paint from epoxy‐silicone vehicles

L. Mathivanan、S. Radhakrishna1997-12-01Anti-Corrosion Methods and Materials

Describes the preparation and properties of heat‐resistant paints based on an epoxy blended with rhodorsil silicone resin. Studies the heat‐resistant properties as per ASTM standard (D 2485‐91). Also determines the properties of the liquid paint and coated metal panels. Assesses the thermal degradation of the coating…

Corrosion Behavior and InhibitionHigh voltage insulation and dielectric phenomenaConcrete Corrosion and Durability

Structural Diversity in Monomeric Cadmium Phenoxides

Donald J. Darensbourg、Sharon A. Niezgoda、Joseph H. Reibenspies 等 4 位作者1997-12-01Inorganic Chemistry

Three monomeric Cd(II) phenoxide complexes have been prepared by reacting Cd[N(SiMe(3))(2)](2) with 2 equiv of 2,6-disubstituted phenols bearing sterically bulky tert-butyl or phenyl groups. The strongly coordinating solvents THF, tetrahydrothiophene (THT), and pyridine used for these reactions were incorporated into…

Organometallic Complex Synthesis and CatalysisPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Characteristics of U3Si and U3Si2 Powders Prepared by Centrifugal Atomization

Ki Hwan Kim、Don Bae Lee、Chang Kyu Kim 等 5 位作者1997-12-01Journal of Nuclear Science and Technology

The characteristics, that is, morphology, size distribution, alloy phase and microstructure of U3Si and U3Si2 powders, solidified rapidly by a centrifugal atomization, were investigated. The atomized powders consist of spherical particles with a relatively narrow size distribution independent of the alloy composition.…

Radioactive element chemistry and processingIntermetallics and Advanced Alloy PropertiesNuclear Materials and Properties

Dynamics of foam films in constricted pores

Gurmeet Singh、G. J. Hirasaki、Clarence A. Miller1997-12-01AIChE Journal

Abstract Hydrodynamics of foam films in a porous medium depend strongly on the pore geometry, foam quality, foam flow rate, surfactant formulation, rheological properties of the film, and the capillary pressure in the medium. These dynamics were studied numerically by simulating the behavior of a foam film as it trave…

Innovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilizationFluid Dynamics and Thin Films

New rapid diamond synthesis technique; using multiplexed pulsed lasers in laboratory ambients

P. Mistry、M.C. Turchan、G. Granse 等 4 位作者1997-12-01Materials Research Innovations

QQC, Inc. has developed a revolutionary diamond deposition technique which does not require a vacuum, or H2, or “chemical” or physical pre-treatment of surfaces. The process utilizes a combination of various pulsed lasers and is performed at the laboratory p-t conditions: with CO2 and N2 as shrouding gases. Crystallin…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Magnetoelectric effect of Mn3B7O13I boracite

O. Crottaz、J.‐P. Rivera、B. Revaz 等 4 位作者1997-12-01Ferroelectrics

Magnetization measurements with a SQUID magnetometer have been carried out on a ferroelectric single domain sample along the three orthorhombic directions. The Néel (Curie) temperature was found at 26 ± 0.5 K and the spontaneous magnetization of the weakly ferromagnetic phase to lie along the orthorhombic b direction…

Multiferroics and related materialsIron oxide chemistry and applicationsMagneto-Optical Properties and Applications

Acetate acts as a protonophore and differentially affects bead movement and cell migration of the gliding bacterium Cytophaga johnsonae (Flavobacterium johnsoniae)

JoAnn Dzink-Fox、Edward R. Leadbetter、Walter Godchaux1997-12-01Microbiology

Cells of Cytophaga johnsonae (now Flavobacterium johnsoniae) are able to translocate on solid surfaces but are unable to swim in liquid media. Organelles that may be involved in this gliding motility have not been detected, and the mechanism(s) responsible remains unknown. The movement of latex beads attached to the c…

Bacterial biofilms and quorum sensingPolymer Surface Interaction StudiesDiatoms and Algae Research