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Influence of the Cyclic Hydriding-Dehydriding Treatment on Pressure-Composition-Temperature Relations of the LaNi5 — H System*

Hirohisa Uchida、Yasuo Naragaki1993-01-01Zeitschrift für Physikalische Chemie

Article Influence of the Cyclic Hydriding-Dehydriding Treatment on Pressure-Composition-Temperature Relations of the LaNi5 — H System* was published on January 1, 1993 in the journal Zeitschrift für Physikalische Chemie (volume 179, issue 1-2).

Rare-earth and actinide compoundsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Mechanical Properties of Alumina-Mullite Whisker Composites

Nobuyuki Tamari、Isao KONDOH、Takahiro Tanaka 等 4 位作者1993-01-01Journal of the Ceramic Society of Japan

Composite alumina ceramics with a mullite whisker content of up to 30vol% were fabricated by hot-pressing at 1400 to 1600°C under 30MPa for 30min. The bending strength, hardness, elastic modulus and fracture toughness of the hot-pressed bodies were investigated. Considerably dense alumina-mullite whisker composite cer…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesIntermetallics and Advanced Alloy Properties

The influence of oxide surface layers on bulk electron probe microanalysis of oxygen—application to Ti‐Si‐O compounds

J. I. Goldstein、SK Choi、F.J.J. van Loo 等 6 位作者1993-01-01Scanning

Abstract This paper discusses a generalized method to measure with the electron probe microanalyzer (EPMA) the oxygen in a material containing a surface oxide layer. The continuum background is the most difficult to measure, particularly for materials in which oxygen‐free samples cannot be produced. The method depends…

Electron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysisAdvanced Materials Characterization Techniques

Mellin transform solution for the static line-source excitation of a dielectric wedge

R.W. Scharstein1993-01-01IEEE Transactions on Antennas and Propagation

An integral transform analysis of the static scattering of the two-dimensional potential radiated by a line source in the vicinity of a penetrable wedge is presented. The Mellin transform is used to derive the exact static solution to Laplace's equation for the dielectric wedge, in the form of a modal series. The impo…

Fire effects on concrete materialsStructural mechanics and materials

Performance of Hybrid Reinforcements in PVC Composites: Part I—Use of Surface-Modified Mica and Wood Pulp as Reinforcements

D. Maldas、BV Kokta1993-01-01Journal of Testing and Evaluation

Abstract In the present study, the hybird behavior of surfacetreated mica and hardwood chemithermomechanical pulp (CTMP) in PVC composites was investigated. In order to improve the compatibility of wood fibers with PVC and surface-coated mica, CTMP was subjected to different surface modifications by pretreating the fi…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesPolymer Science and PVC

NMR spectra of the porphyrins. Part 42. The synthesis and aggregation behaviour of some chlorophyll analogues

Raymond J. Abraham、Alan E. Rowan、Norman W. Smith 等 4 位作者1993-01-01Journal of the Chemical Society Perkin Transactions 2

The synthesis of three analogues of pyrochlorophyll a with the selective removal of the carbonyl functions is described; 7-despropionate-7-propyl-mesopyrochlorophyllide a (DPC), methyl 9-desoxo-mesopyrochlorophyllide a (DOC) and 9-desoxo-7-despropionate-7-propyl-mesopyrochlorophyllide a (DODPC), were prepared from met…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Debye-type dielectric behavior of Bi-Sr-Ca-Cu-O-based transition-metal oxide glasses: Precursors for oxide superconductors

K. K. Som、S. Mollah、K. Bose 等 4 位作者1993-01-01Physical review. B, Condensed matter

Detailed measurements of the frequency- (50 Hz to 10 kHz) and temperature (80 loss (\ensuremath{\epsilon}'') have been performed for the ${\mathrm{Bi}}_{4}$${\mathrm{Sr}}_{3}$${\mathrm{Ca}}_{3}$${\mathrm{Cu}}_{\mathit{y}}$${\mathrm{O}}_{\mathit{x}}$ (y=0 to 5) glasses. Some of these glasses become high-temperature sup…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsAdvanced Condensed Matter Physics

Skinfold Compressibility in Japanese University Students

Komei Hattori、Wakako OKAMOTO1993-01-01Okajimas Folia Anatomica Japonica

It is well known that caliper readings decline after the initial application of the caliper to the skinfold (dynamic compressibility). In addition to this compressibility, there is also a variability of skinfold compressibility at different body sites (static compressibility). To investigate this static variability, a…

Thermoregulation and physiological responsesTextile materials and evaluationsBody Composition Measurement Techniques

Effect of Moisture and Heat on Mechanical Properties of Wood and Wood-Plastic Composite

Mubarak A. Khan、K. M. Idriss Ali1993-01-01Polymer-Plastics Technology and Engineering

Wood-plastic composite (WPC) has been made by impregnating methylmethacrylate (MMA) monomer into simul, a native timber of Bangladesh, under Co-60 γ radiation. The effect of moisture and heat and humidity on simul and its WPC is investigated as a simulating phenomenon of the sunlight, rain, and moisture to which timbe…

Wood Treatment and PropertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Demonstration of a novel method for the controlled deposition of metals onto surfaces by preparation of a Pd–Hg/SiO 2 catalyst for the selective hydrogenation of alkynes to alkenes

Durgesh V. Nadkarni、James L. Fry1993-01-01Journal of the Chemical Society Chemical Communications

Treatment of silica gel that has SiH functional groups bonded to the surface, with methanolic PdCI2 and then aqueous Hg2S04 affords a new catalytic material for the chemo- and stereo-selective partial hydrogenation of alkynes to Z-alkenes with a high degree of functional group compatibility.

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Examination of the conformational dynamics of photoregulated Concanavalin A by time-resolved light scattering

Eran Zahavy、Shai Rubin、Itamar Willner1993-01-01Journal of the Chemical Society Chemical Communications

Spiropyran-modified Concanavalin A (Con-A) displays photoregulated binding towards α-D-mannopyranoside, the photostimulated binding of the substrate originating from a structural perturbation of the protein upon photoisomerization of spiro-Con-A to the zwitterionic Con-A; time-resolved light scattering reveals that th…

Light effects on plantsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Studies on π-acceptor molecules containing the dicyanomethylene group. X-Ray crystal structure of the charge-transfer complex of tetramethyltetrathiafulvalene and 2,3-dicyano-1,4-naphthoquinone: (TMTTF) 3 –(DCNQ) 2

Andrei S. Batsanov、Martin R. Bryce、Stephen Davies 等 6 位作者1993-01-01Journal of the Chemical Society Perkin Transactions 2

The reaction of tetramethyltetrathiafulvalene (TMTTF, 7) with 2-dicyanomethyleneindane-1,3-dione (DCID, 1) leads to isomerisation of DCID to 2,3-dicyanonaphthoquinone (DCNQ, 3) to yield the charge-transfer complex [(TMTTF)3]2˙+–(DCNQ˙–)28. The X-ray crystal structure of complexe 8 reveals stacks of TMTTF molecules alo…

Magnetism in coordination complexesNonlinear Optical Materials ResearchOrganic and Molecular Conductors Research

Polarized Light Microscopy (PLM) of Ferroelectric and Ferroelastic Domains in Transmitted and Reflected Light

H. Schmid1993-01-01Birkhäuser Basel eBooks

The importance of polarized light microscopy (PLM) for the study of the domains and phase transitions of ferroelectric and ferroelastic single crystals is pin-pointed and the experimental set-ups for observations and measurements between 4 and 1600K are outlined. The contrast formation between domains by spontaneous b…

Acoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Polymethylmethacrylate by XPS

S. W. Rosencrance、Wayne K. Way、Nicholas Winograd 等 4 位作者1993-01-01Surface Science Spectra

X-ray photoelectron spectroscopy was used to analyze a thin film of polymethylmethacrylate (PMMA) which was spin cast from a 2% weight solution of PMMA in toluene onto a gold substrate. A Hewlett Packard 5950A ESCA spectrometer was used for this investigation.

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Computational studies of the structure of monolayers of chlorine physisorbed on the basal plane of graphite

Kenton D. Hammonds、Ian R. McDonald、Dominic J. Tildesley1993-01-01Molecular Physics

Results are reported of energy minimizations and molecular-dynamics calculations for chlorine physisorbed on the basal plane of graphite. The dispersion-repulsion component of the intermolecular potential is modelled by an anisotropic site-site potential and the permanent electrostatic potential is represented by dist…

Graphene research and applicationsAdvanced Thermodynamics and Statistical MechanicsQuantum Electrodynamics and Casimir Effect

Microstructure of Zinc-Bonded Sm<SUB>2</SUB>Fe<SUB>17</SUB>N<SUB>3</SUB> Permanent Magnet Studied by Transmission and Analytical Electron Microscopy

Kenji Hiraga、Kensuke Okamoto、Takahiko Iriyama1993-01-01Materials Transactions JIM

Microstructure of the Zn-bonded Sm2Fe17N3 permanent magnet having high magnetic coercivity of 11.8 kOe was studied by transmission and analytical electron microscopy. Three phases, α-Fe including 20 to 30 at%Zn, Fe3Zn7, and Sm2(Fe, Zn)17Nx, were found in addition to the matrix Sm2Fe17N3 phase. The Sm2(Fe, Zn)17Nx phas…

Magnetic and transport properties of perovskites and related materialsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Dielectric properties of amorphous cellulose acetate‐butyrate polymer films

N. Venugopal Reddy、C. Ramesh Kumar、V. V. R. Narasimha Rao1993-01-01Polymer International

Abstract The dielectric constant, loss tangent and AC conductivity of solution grown cellulose acetate‐butyrate films of 5μm thickness were studied as a function of temperature (300‐450 K) in the frequency range 10 Hz‐10 MHz. The decrease in dielectric constant was observed with the increase in frequency as well as wi…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesDielectric materials and actuators

Group 15–azamacrocyclic chemistry. Reactions of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (L) with MCl 3 (M = As or Sb): crystal and molecular structures of [H 2 L][As 4 O 2 Cl 10 ] and [H 2 L][Sb 2 OCl 6 ]

Gerald R. Willey、A. Asab、Miles T. Lakin 等 4 位作者1993-01-01Journal of the Chemical Society Dalton Transactions

The reactions of MCl3(M = As or Sb) and 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (tetramethylcyclam, L) have been studied under controlled hydrolysis conditions as a route to anionic bridging chlorooxo arsenic- or antimony-(III) species. With M = As, the ionic complex [H2L][As4O2Cl10]1 has been isolated…

Crystal structures of chemical compoundsSynthesis and characterization of novel inorganic/organometallic compoundsLanthanide and Transition Metal Complexes

Dielectric Properties of Beta Barium Borate and Potassium Pentaborate Single Crystals

C. Ramachandra Raja、R. Gobinathan、F. D. Gnanam1993-01-01Crystal Research and Technology

Abstract Single crystals of beta barium borate and potassium pentaborate (commonly known as β‐BaB 2 O 4 or BBO and KB 5 O 8 . 4 H 2 O or KB5) were grown by high and low temperature solution growth methods, respectively. The dielectric constant and loss tangent were determined as a function of temperature. Frequency re…

Crystal Structures and PropertiesAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography