Materials Literature
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Two planktonic species of diatoms, Chaetoceros bacteriastroides and C. seychellarus , have been studied by light and electron microscopy. Important features that may be used as taxonomic characters are described. A new subgenus, Bacteriastroidea, is proposed to include C. bacteriastroides, because of its unique charac…
A 2 × 2 propagation-matrix formalism for finding the obliquely propagating electromagnetic fields in layered inhomogeneous uniaxial structures is presented. The 2 × 2 propagation matrix was produced by our generalized geometrical-optics approximation method. A 2 × 1 field vector for the transverse electric field is de…
Kaempferol 3-O-[alpha-L-rhamnopyranosyl (1-->6)-beta-D-glucopyranoside] and kaempferol 3-O-[beta-D-glucopyranoside] were isolated from the leaves of Hedyosmum bonplandianum H.B.K. (Chloranthaceae), which is used in Colombian folk medicine as an analgesic. The n-butanol extract and the glycosyl flavonoids isolated exhi…
Abstract Bisupported catalysts for olefin polymerization were prepared by mixing a butyl alcoholate solution of MgCI 2 with pretreated SiO 2 in heptane, and further treating with TiCI 4 solution. The silica pretreating conditions and their effects on the composition of the catalysts were studied. The interaction mecha…
Scanning electron microscopy has been used to observe the details of the apical structure of the theca in 46 species belonging to 10 genera (Boreadinium, Diplopsalis, Diplopsalopsis, Dissodium, Lebouraia, Oblea, Peridiniopsis, Peridinium, Protoperidinium, Zygabikodinium) in the family Peridiniaceae (Dinophyceae). The…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemical and spectroelectrochemical characterization of (5,10,15,20-tetrakis(1-methyl-4-pyridyl)porphinato)manganese(III) chloride, [(TMpyP)MnIIICl]4+(Cl-)4, in N,N-dimethylformamideEric Van Caemelbecke, Wlodzimierz Kutner, and Karl M. KadishCite this: Inorg. Chem. 19…
The synthesis and mesomorphic behavior of 3,5-bis-(p-n-alkoxyphenyl)isoxazole (series I) and 3,5-bis-(p-n-alkoxyphenyl)pyrazole (series II) are reported for the number of carbon atoms (n) in the alkoxy chains varying from three to eight. Series I shows an enantiotropic nematic phase for all n and an enantiotropic smec…
Measurements of tilt bias angles of a nematic liquid crystal were carried out, by using several alkylene polyimides synthesized from 3,3′,4,4′-biphenyltetracarboxylic dianhydrides and diamines with different chain lengths as alignment layers. The tilt bias angle dependence on the alkylene chain length of polyimides sh…
The mesogenic behaviour of a series of thirty-one 1-alkyl-4-(or 2-)alkylpyridinium salts and of a homologous series of four 1-methyl-4-n-alkoxycarbonylpyridinium iodides is described. The occurrence and stability range of the thermotropic phases depend dramatically on the structure of the surfactants. Mesophases are o…
This paper considers the dynamics of a gas bubble in response to either a pressure pulse or a pressure step at t = 0, both in the presence and absence of a mean flow. Our work utilizes small-deformation, domain perturbation analysis carried to second and higher order in the amplitude of deformation, ε. In the absence…
Critical points that do not involve any symmetry change are shown to define a set of new universality classes in layered systems. Extension of this problem to higher dimensions may be made in an infinite number of ways which define continuously varying upper critical dimensions. This allows us to estimate uncertaintie…
In most models of anodically formed salt films, the concentrations of the ionic components of the salt are assumed to be at their saturation values at the film/electrolyte interface. The consequences of also imposing the saturation condition inside a porous film are compared to results of the more commonly employed mo…
In order to study the dynamic behavior of conoscopic images with high precision and high efficiency, we constructed a conoscope observation system using a CCD (charge coupled device) camera and an image processor. We can analyze biaxiality and apparent tilt angle by means of a homeotropic cell operated at 0.1 Hz. We d…
Abstract The mesophase (lyotropic liquid crystal) of the inorganic rod‐like polymer, imogolite, displays a typical fingerprint texture under a polarized optical microscope (POM), although the mesophase reveals no circular dichroism. The scanning electron microscope revealed a honeycomb structure of thin sheets having…
Abstract A series of studies of uncatalyzed and catalyzed polyesterification experiments have been investigated using different glycols at different temperatures. The experimental results for uncatalyzed reactions agreed quite well with the kinetic equation as proposed by P. J. Flory. However, Flory proposed a second‐…
Abstract Boxwork fabric in which numerous thin or thick halloysite walls are interconnected into a microscopically porous cellular pattern is widely developed in the halloysite-rich kaolin formed by weathering of anorthosite in Sancheong, Korea. Studies using optical microscopy, scanning electron microscopy, and trans…
The critical moisture content of cottonseed flakes extracted with an aqueous alcohol solvent can be defined as that flake moisture level at which the flakes lose no moisture during extraction. This study shows that the critical moisture content for aqueous ethanol (92%, w/w) is 3%. For aqueous isopropanol (88%, w/w) t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption of palladium-ammino-aquo complexes on .gamma.-alumina and silicaD. Spielbauer, H. Zeilinger, and H. KnoezingerCite this: Langmuir 1993, 9, 2, 460–466Publication Date (Print):February 1, 1993Publication History Published online1 May 2002Published inissue 1 February…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSwinging of the bent nitrosyl ligand in (nitrosyl- 15N)(meso-tetraphenylporphinato)cobalt: a solid-state motion detected by nitrogen-15 CPMAS NMR spectroscopyChristopher J. Groombridge, Leslie F. Larkworthy, and Joan MasonCite this: Inorg. Chem. 1993, 32, 4, 379–380Publicati…
It is known that the backbone conformation of a protein can be reproduced with precision once a correct contact map (two-dimensional representation showing residue pairs in contact) is given as geometrical constraints. There is, however, no way to infer the correct contact map for a protein of unknown structure. We st…