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Polymer-Derived Ceramic Fibers

Hiroshi Ichikawa2016-03-01Annual Review of Materials Research

SiC-based ceramic fibers are derived from polycarbosilane or polymetallocarbosilane precursors and are classified into three groups according to their chemical composition, oxygen content, and C/Si atomic ratio. The first-generation fibers are Si-C-O (Nicalon) fibers and Si-Ti-C-O (Tyranno Lox M) fibers. Both fibers c…

Advanced materials and compositesAdvanced ceramic materials synthesisMetal and Thin Film Mechanics

Guided Self‐Propelled Leaping of Droplets on a Micro‐Anisotropic Superhydrophobic Surface

Jie Liu、Haoyuan Guo、Bo Zhang 等 11 位作者2016-03-01Angewandte Chemie International Edition

By introducing anisotropic micropatterns on a superhydrophobic surface, we demonstrate that water microdroplets can coalesce and leap over the surface spontaneously along a prescribed direction. This controlled behavior is attributed to anisotropic liquid-solid adhesion. An analysis relating the preferential leaping p…

Adhesion, Friction, and Surface InteractionsSurface Modification and SuperhydrophobicityFluid Dynamics and Heat Transfer

Few-layer HfS2 transistors

Toru Kanazawa、Tomohiro Amemiya、Atsushi Ishikawa 等 7 位作者2016-03-01Scientific Reports

HfS2 is the novel transition metal dichalcogenide, which has not been experimentally investigated as the material for electron devices. As per the theoretical calculations, HfS2 has the potential for well-balanced mobility (1,800 cm(2)/V·s) and bandgap (1.2 eV) and hence it can be a good candidate for realizing low-po…

Semiconductor materials and devicesMXene and MAX Phase Materials2D Materials and Applications

Graphene Spheres-CuO Nanoflowers Composites for Use as a High Performance Photocatalyst

Bin Zeng、Hui Long2016-03-01Nanomaterials and Nanotechnology

Graphene spheres decorated with CuO nanoflowers were successfully synthesized via a spray-drying method. Scanning-electron and transmission-electron microscopy were used to confirm that the graphene formed spherical structures and that the CuO nanoflowers were well dispersed on the surface of these graphene spheres. T…

Spectroscopic Properties of AlSb Nanocrystals Using Diamondoid Structures: A Density Functional Theory Study

Mudar Ahmed Abdulsattar、Hayder M. Abduljalil、Noor Al-Huda Talib Al-Aaraji2016-03-01Nanomaterials and Nanotechnology

AlSb diamondoids are used as building blocks to investi‐ gate AlSb nanocrystal properties using density functional theory. Energy differences between the HOMO and LUMO of AlSb diamondoids vary according to confinement theory, along with shape fluctuations. AlSb diamondoids’ vibrational force constant reaches 0.82 mDyn…

Performance Improvement of CH3NH3PbI3 Perovskite Solar Cell by CH3SH Doping

Hong Li、Yingguo Yang、Xiao Feng 等 8 位作者2016-03-01Nanomaterials and Nanotechnology

Organometal halide perovskites have recently emerged as an appealing candidate in photovoltaic devices due to their excellent properties. Therefore, intense efforts have been devoted to find the ideal organics for perovskite solar cells. In response, we investigate the doping effect of CH3SH organic on the structure a…

The Fabrication and Characterization of Piezoelectric PZT/PVDF Electrospun Nanofiber Composites

Ji Sun Yun、Chun Kil Park、Young Hun Jeong 等 7 位作者2016-03-01Nanomaterials and Nanotechnology

Piezoelectric nanofiber composites of polyvinylidene fluoride (PVDF) polymer and PZT (Pb(Zr0.53Ti0.47)O3) ceramics were fabricated by electrospinning. The micro‐ structure of the PZT/PVDF electrospun nanofiber compo‐ sites was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmis…

Fabrication of Nanostructured TiO2 Using a Solvothermal Reaction for Lithium-ion Batteries

Jicai Liang、Ziyi Wang、Zhisen Li 等 5 位作者2016-03-01Nanomaterials and Nanotechnology

Nanostructured TiO2 was successfully synthesized via a facile one-pot solvothermal reaction followed by calcina‐ tion. Hydrolysis and polycondensation of titanium butox‐ ide (Ti(OR)4) were performed in the presence of sodium dodecylbenzenesulfonate (SDBS). The morphologies, crystallinity and compositions of obtained s…

Exploration of Wettability and Optical Aspects of ZnO Nano Thin Films Synthesized by Radio Frequency Magnetron Sputtering

Kartik H. Patel、Sushant K. Rawal2016-03-01Nanomaterials and Nanotechnology

This paper aims to explore structural, optical and wettabil‐ ity aspects of zinc oxide (ZnO) nano thin films prepared by radio frequency (RF) magnetron sputtering. The deposition time is varied from 10 to 50 minutes and sputtering pressure from 0.5 to 8.0 Pa. The increase of deposition time from 10 to 50 minutes leads…

One-step Synthesis of Stable, Nontoxic, Orange Quantum Dots Fluorescent Powder

Shuhong Xu、Jin Shen、Zhaochong Wang 等 7 位作者2016-03-01Nanomaterials and Nanotechnology

Stable, nontoxic, and aqueous Cu:ZnInSe quantum dots (QDs) have been synthesized using one-step method. Through controlling pH, the amount of 3-mercaptopro‐ pionic acid (MPA), and impurities Cu and In, high-quality Cu:ZnInSe QDs have been obtained. First, as-prepared Cu:ZnInSe QDs have better thermal stability. The ph…

Catalysis of a Nanometre Solid Super Acid of SO42-/TiO2 on the Thermal Decomposition of Ammonium Nitrate

Xiaolan Song、Yi Wang、Dan Song 等 5 位作者2016-03-01Nanomaterials and Nanotechnology

Raw TiO2 nanoparticles were prepared using the hydroly‐ sis of TiCl4. The nanoparticles were subjected to a surface treatment in diluted sulphuric acid and, subsequently, calcined at different temperatures. Then, a type of super solid acid (SO42-/TiO2) with particle sizes of 20∼30 nm was fabricated. The catalysis of S…

Modifying the Fluorescence of CdTe Quantum Dots by Silica-coated Gold Nanorods

Ning Zhou、Tao Liu、Dongsheng Li 等 4 位作者2016-03-01Nanomaterials and Nanotechnology

The influence of Au nanorods coated with a silica layer on the photoluminescence (PL) of CdTe quantum dots (QDs) was investigated. The Au nanorods were prepared using a seed-mediated method. They were coated with a silica layer on the surface and CdTe QDs were connected to the surface of the silica layers. The PL spec…

Platinum Nanoparticles Supported on Activated Carbon Catalysts for the Gas- phase Hydrodechlorination of Dichloromethane: Influence of Catalyst Composition and Operating Conditions

María Ariadna Álvarez-Montero、Juan Jose Rodriguez、Luisa María Gómez-Sainero2016-03-01Nanomaterials and Nanotechnology

DCM is classified among the most hazardous atmospheric pollutants and therefore, the development of safe methods for the disposal of residual DCM is of great importance. Activated carbon- supported catalysts containing platinum nanoparticles as the active phase, with a high proportion of metal in the zero-valent state…

Formation of Mn-doped SnO2 Nanoparticles Via the Microwave Technique: Structural, Optical and Electrical Properties

Numan Salah、Sami Habib、Ameer Azam 等 5 位作者2016-03-01Nanomaterials and Nanotechnology

Ultrafine pure and Mn-doped SnO2 nanoparticles (NPs) were synthesized via the microwave technique. They were produced using tin chloride and hexamethylenetetramine at the molar ratio of 1:20. The concentrations of Mn in the SnO2 matrix were in the range of 0.1–5 mol%. These nanomaterials were characterized using diffe…

Review of Multifarious Applications of Poly (Lactic Acid)

Yuan Yuan Chen、Luke M. Geever、John A. Killion 等 6 位作者2016-03-01Polymer-Plastics Technology and Engineering

Poly (lactic acid) is considered to be a promising alternative to petroleum-based polymers due to its renewability, biodegradability, biocompatibility, and good mechanical properties. Because of the high cost, the applications of poly (lactic acid) were limited to the medical field. Over the past decade, improvements…

Electrospun Nanofibers in Biomedical Applicationsbiodegradable polymer synthesis and propertiesBone Tissue Engineering Materials

Supramolecular Approaches to Graphene: From Self‐Assembly to Molecule‐Assisted Liquid‐Phase Exfoliation

Artur Ciesielski、Paolo Samorı́2016-03-01Advanced Materials

Graphene, a one-atom thick two-dimensional (2D) material, is at the core of an ever-growing research effort due to its combination of unique mechanical, thermal, optical and electrical properties. Two strategies are being pursued for the graphene production: the bottom-up and the top-down. The former relies on the use…

2D Materials and ApplicationsGraphene research and applicationsCovalent Organic Framework Applications

Stress Relaxation and Self-Adhesion of Rubbers with Exchangeable Links

Lucie Imbernon、Sophie Norvez、Ludwik Leibler2016-03-01Macromolecules

To get intrinsic adhesion or healing properties in a cross-linked rubber, two levers are possible: the inherent relaxation in permanently but lightly cross-linked elastomers or the relaxation due to exchange reactions as recently reported in the case of vitrimers. The former is associated with dangling chain motion an…

Advanced Sensor and Energy Harvesting MaterialsPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Thermal Conductivity of Wurtzite Zinc-Oxide from First-Principles Lattice Dynamics – a Comparative Study with Gallium Nitride

Xufei Wu、Jonghoon Lee、Vikas Varshney 等 6 位作者2016-03-01Scientific Reports

Wurtzite Zinc-Oxide (w-ZnO) is a wide bandgap semiconductor that holds promise in power electronics applications, where heat dissipation is of critical importance. However, large discrepancies exist in the literature on the thermal conductivity of w-ZnO. In this paper, we determine the thermal conductivity of w-ZnO us…

Advanced ceramic materials synthesisThermal Expansion and Ionic ConductivityThermal properties of materials

Lysosome triggered near-infrared fluorescence imaging of cellular trafficking processes in real time

Marco Grossi、Marina Morgunova、Shane Cheung 等 10 位作者2016-03-01Nature Communications

Bioresponsive NIR-fluorophores offer the possibility for continual visualization of dynamic cellular processes with added potential for direct translation to in vivo imaging. Here we show the design, synthesis and lysosome-responsive emission properties of a new NIR fluorophore. The NIR fluorescent probe design differ…

Luminescence and Fluorescent MaterialsPhotoreceptor and optogenetics researchMolecular Sensors and Ion Detection