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Synthesis and modification of beta zeolite for use in toluene disproportionation reaction

Santiago Mesa Espinal、Johana Arboleda、Adriana Echavarrı́a2016-04-20DYNA

In this paper zeolite Beta was synthesized and characterized by XRD, ATG, ATD, XRF and SEM. Subsequently various modifications were made using a surface passivation process in liquid phase with tetraethylorthosilicate (TEOS), using two loads of TEOS and three passivation cycles, in order to obtain six catalysts. These…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

NOVEL SYNTHESIS, CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF SILVER NANOPARTICLES USING LEAF EXTRACT OF MELOTHRIA MADERASPATANA (LINN) CONG

Subramani Srinivasan、Dhananjayan Indumathi、Mathiyazhagan Sujatha 等 5 位作者2016-04-20International Journal of Pharmacy and Pharmaceutical Sciences

Objective : This study aims to investigate the green synthesis of silver nanoparticles (AgNPs) Melothria maderaspatana (MM), and evaluation of their antibacterial activities for the first time. It is observed that MM leaf extract can reduce silver ions into AgNPs. Methods: The obtained particles were analyzed by UV-vi…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsMedicinal Plants and Neuroprotection

Uncertainty Quantification with the Event-by-Event Fission Model FREYA

Richard H. Vogt、Andrew Nicholson、J. Randrup 等 5 位作者2016-04-20OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)

Abstract not provided

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studiesTechnology Assessment and Management

Photoluminescence properties of LiTi2 − xEux(PO4)3 phosphor

R. Ramaraghavulu、V. Naresh、V. Eswaraiah2016-04-20Luminescence

Abstract A solid‐state reaction route‐based LiTi2 − xEux(PO4)3 was phosphor synthesized for the first time to evaluate its luminescence performance by excitation, emission and lifetime (τ) measurements. The LiTi2 − xEux(PO4)3 phosphor was excited at λexci. = 397 nm to give an intense orange–red (597 nm) emission attri…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesMicrowave Dielectric Ceramics Synthesis

Hamiltonian-based ray-tracing method with triangular-mesh representation for a large-scale cloaking device with an arbitrary shape

Tatsuo Tanaka、Osamu Matoba2016-04-20Applied Optics

Hamiltonian-based ray-tracing technique with mesh representation is presented for designing large-scale cloaking devices with three-dimensional arbitrary shapes, which have inhomogeneity and anisotropy in their electric permittivity and magnetic permeability. In order to deal with arbitrary shapes, the surfaces of the…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Modelling of starve fed single-screw extrusion of polyblends using non-conventional screws

Krzysztof J. Wilczyński、Andrzej Nastaj2016-04-20Polimery

A computer model has been developed for starve fed single-screw extrusion with non-conventional screws. Simulation and experimentation for extrusion of PE-LD/PS blend have been carried out. Non-conventional screw equipped with Maddock shearing element has been applied. Melting of polymer, pressure, temperature profile…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Embedded macroporous elastomers by hydrostatic fracturing for flexible strain‐sensor applications

Kumar Phanishwar、Shama Perween、Neelam Saurakhiya 等 4 位作者2016-04-20Journal of Applied Polymer Science

ABSTRACT A method is proposed for fabricating flexible materials embedded with macroporous regions by inducing fractures under point loading. Possible use of these structures in strain sensing is demonstrated. Injecting air at high pressure through a needle‐tip generates 3‐dimensional fractures in homogeneously crossl…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsSmart Materials for Construction

One-to-One Correspondence Growth Mechanism of Gourd-like SiOx Nanotubes

Han Gil Na、Sun‐Woo Choi、Suyoung Park 等 9 位作者2016-04-20Crystal Growth & Design

In contrast with conventional thermal evaporation-based semiconducting oxide growth methods, gourd-like SiO x nanotubes (NTs) grown from Si substrates were achieved with incorporated Sn-embedded structures through the precontaminated SnO 2 film surroundings. Interestingly, when Sn aggregations assembled as Sn nanopart…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsNanowire Synthesis and Applications

A First‐Principles Study on the Electronic, Vibrational, and Thermodynamic Properties of Jadeite and its Tentative Low‐Density Polymorph

Ralf P. Stoffel、Katharina Philipps、Reinhard Conradt 等 4 位作者2016-04-20Zeitschrift für anorganische und allgemeine Chemie

Abstract The high‐pressure clinopyroxene mineral jadeite (chemical composition NaAlSi2O6) was studied by density‐functional theory with respect to its electronic, vibrational, and thermodynamic properties, correctly reproducing the available experimental data. At a larger‐than‐normal volume, however, a low‐density alu…

High-pressure geophysics and materialsGlass properties and applicationsCrystal Structures and Properties

Insight into the spin state at the surface of LaCoO3 revealed by photoemission electron microscopy

Alexander Yaroslavtsev、M. Izquierdo、Robert Carley 等 9 位作者2016-04-20Physical review. B./Physical review. B

The evolution of the spin transition in ${\mathrm{LaCoO}}_{3}$ has been investigated with photoemission electron microscopy (PEEM) as a function of temperature. The investigated temperature range spanned from a predominantly low spin configuration (125 K) to the proposed percolation limit for metallization (413 K). Th…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Influence of isomorphous substitution of metal ion on the low-frequency dielectric dispersion in NH2(CH3)2Al1−xCrx(SO4)2⋅6H2O ferroelectrics

V. Kapustianyk、Yu. Eliyashevskyy、Z. Czapla 等 7 位作者2016-04-20Phase Transitions

This paper is devoted to the study of the influence of metal ion isomorphous substitution on the ferroelastic-ferroelectric phase transition and dispersion caused by the motion of domain walls in dimethylammonium metal sulfate hexahydrate DMAAl1−xCrxS ferroelectric crystals (x = 0, 0.065, 0.2). It is shown that such a…

Acoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Spiral structures in the rotor-router walk

Vl V Papoyan、V S Poghosyan、V B Priezzhev2016-04-20Journal of Statistical Mechanics Theory and Experiment

We study the rotor-router walk on the infinite square lattice with the outgoing edges at each lattice site ordered clockwise. In the previous paper (Papoyan et al 2015 J. Phys. A: Math. Theor . 48 285203), we considered the loops created by rotors and labeled the sites where the loops become closed. The sequence of la…

Stochastic processes and statistical mechanicsQuasicrystal Structures and PropertiesCellular Automata and Applications

Substitution of W5+in monophosphate tungsten bronzes by combinationsMn+/W6+

Subrata Chandra Roy、Wilfried Assenmacher、Thomas Lindén 等 6 位作者2016-04-20Zeitschrift für Naturforschung B

Abstract A series of hitherto unknown mixed-metal phosphates of the monophosphate tungsten bronze structure family [MPTB; (WO3)2m(PO2)4] have been obtained by solution combustion synthesis followed by annealing (ϑ= 850°C) at appropriate oxygen pressures. These new phosphates show substitution of W5+by eitherM3+1/3W6+2…

Metal-Organic Frameworks: Synthesis and ApplicationsTransition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and Applications

Cross-linked epoxy-isocyanate blends containing Epidian-6 modified by glycols

Michael Bratychak、Ostap Ivashkiv、Piotr Bruździak 等 5 位作者2016-04-20Polimery

Polymeric films of cross-linked structure may be formed using epoxy-isocyanate blends composed of Epidian-5 epoxy resin, 4,4'-diphenylmethanediisocyanate (MDI), Z-1 polyamine hardener and Epidian-6 epoxy resin modified by glycols. The effect of the component natures and ratio, process temperature and time on the gel-f…

Polymer composites and self-healingSynthesis and properties of polymers

Facile Synthesis and Proposed Mechanism of α,ω‐Oxetanyl-Telechelic Poly(3-nitratomethyl-3-methyl oxetane) by an SN2(i) Nitrato Displacement Method in Basic Media

Hemant Desai、Daniel O. Acheampong、R. F. Hudson 等 11 位作者2016-04-20Journal of Energetic Materials

The synthesis of a novel heterocyclic–telechelic polymer, α,ω-oxetanyl-telechelic poly(3-nitratomethyl-3-methyl oxetane), is described. Infrared spectroscopy (IR), gel permeation chromatography (GPC), and nuclear magnetic resonance (NMR) spectroscopy have been used to confirm the successful synthesis, demonstrating th…

Synthesis and properties of polymersSilicone and Siloxane ChemistryChemical Reactions and Mechanisms

CHETAH 10.0, the ASTM Computer Program for the Prevention of Reactive and Flammability Hazards

B. Keith Harrison2016-04-20Journal of Testing and Evaluation

Abstract The uses of the ASTM computer program CHETAH were described. The recently released version 10 is capable of accomplishing five different kinds of calculations related to chemical thermodynamics. The program enables the prediction of chemical reactive hazards, heats of reaction for combustion and other types o…

Combustion and Detonation ProcessesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

The influence of parameters of manufacturing hybrid flame retardant additives containing graphite on their effectiveness

Piotr Jankowski、Dorota Kijowska2016-04-20Polimery

Syntheses of hybrid flame retardant (HFR) additives were done on a semi-industrial scale. HFRs were obtained by in situ synthesis of melamine cyanurate in the presence of expandable graphite. HFRs have been used to reduce the flammability of selected polymers: polyester, epoxide, polystyrene. Compositions characterize…

Recycling and utilization of industrial and municipal waste in materials productionMaterial Properties and ApplicationsAdvanced Theoretical and Applied Studies in Material Sciences and Geometry

Effect of additional electron acceptor in hybrid P3HT:PCBM:ZnO spin‐coated films for photovoltaic application

T.F.G. Muller、Thinavhuyo Albert Ramashia、David E. Motaung 等 7 位作者2016-04-20physica status solidi (a)

Concerted efforts need to be undertaken to overcome limited efficiencies and instability issues in order to ensure a niche for organic photovoltaics (OPVs) in the PV market. Recent improvements on tandem structures aside, in order to achieve further improvements it is sensible to construct test‐case scenarios on bulk…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

SYNTHESIS AND STRUCTURE-ACTIVITY RELATIONSHIP OF 1-ALLYL-3-(2-CHLOROBENZOYL) THIOUREA AS ANALGESIC

Alvan Febrian Shalas、Siswandono、Marcellino Rudyanto2016-04-20International Journal of Pharmacy and Pharmaceutical Sciences

Objective: The research was aimed to synthesize 1-allyl-3-(2-chlorobenzoyl) thiourea and determine its analgesic activity in mice ( Mus musculus ). Methods: The synthesis was carried out by modified Schotten-Baumann reaction, via nucleophilic substitution reaction of allylthiourea on 2-chlorobenzoyl chloride. The anal…

Synthesis and biological activityPhenothiazines and Benzothiazines Synthesis and ActivitiesPolymer Synthesis and Characterization

The impact of medium frequency pulsed magnetron discharge power on the single probe Langmuir measurements and resulted plasma parameters

Artur Wiatrowski、W. M. Posadowski2016-04-20Materials Science-Poland

Abstract The resonant type power supplies of medium frequency designed for magnetron sputtering processes often use pulse density modulation to regulate the average discharge power level. While the output power level changes then number of pulses in a group changes, but the discharge current pulses are the same from p…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchPlasma Diagnostics and Applications