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Driving Forces for Covalent Assembly of Porphyrins by Selective C–H Bond Activation and Intermolecular Coupling on a Copper Surface

Andrea Floris、Sam Haq、Mendel In’t Veld 等 6 位作者2016-04-20Journal of the American Chemical Society

Recent synthesis of covalent organic assemblies at surfaces has opened the promise of producing robust nanostructures for functional interfaces. To uncover how this new chemistry works at surfaces and understand the underlying mechanisms that control bond-breaking and bond-making processes at specific positions of the…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

Random lasing in a colloidal quantum dot-doped disordered polymer

Mingxuan Cao、Yating Zhang、Xiaoxian Song 等 8 位作者2016-04-20Optics Express

. Through the investigation on the spectral characteristics of random laser, the wavelengths of random lasers strongly depend on pump position, which confirms that random laser modes originate from spatially localized resnonators. According to power Fourier transform of emission spectrum, the average size of equivalen…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsRandom lasers and scattering media

A New XRD Method to Quantify Plate and Lath Martensites of Hardened Medium-Carbon Steel

Quanshun Luo2016-04-20Journal of Materials Engineering and Performance

This paper introduces a new technique to separately measure the volume fraction and tetragonal ratio of co-existing lath and plate martensites in ultrahigh strength steel, and to calculate their different carbon contents. First, the two martensites are assumed to have body-centered tetragonal lattice structures of dif…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsMetal Alloys Wear and Properties

Cytotoxic Induction and Photoacoustic Imaging of Breast Cancer Cells Using Astaxanthin-Reduced Gold Nanoparticles

Subramaniyan Bharathiraja、Panchanathan Manivasagan、Nhat Quang Bui 等 7 位作者2016-04-20Nanomaterials

Astaxanthin, a kind of photosynthetic pigment, was employed for gold nanoparticle formation. Nanoparticles were characterized using Ulteraviolet-Visible (UV-Vis) spectroscopy, transmission electron microscopy, and X-ray diffraction, and the possible presence of astaxanthin functional groups were analyzed by Fourier tr…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranosticsPhotoacoustic and Ultrasonic Imaging

Engineering Interfacial Silicon Dioxide for Improved Metal–Insulator–Semiconductor Silicon Photoanode Water Splitting Performance

Peter F. Satterthwaite、Andrew G. Scheuermann、Paul K. Hurley 等 5 位作者2016-04-20ACS Applied Materials & Interfaces

Silicon photoanodes protected by atomic layer deposited (ALD) TiO2 show promise as components of water splitting devices that may enable the large-scale production of solar fuels and chemicals. Minimizing the resistance of the oxide corrosion protection layer is essential for fabricating efficient devices with good fi…

Advanced Photocatalysis TechniquesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Impact of Serine/Threonine Protein Kinases on the Regulation of Sporulation in Bacillus subtilis

Frédérique Pompeo、Elodie Foulquier、Anne Galinier2016-04-20Frontiers in Microbiology

Bacteria possess many kinases that catalyze phosphorylation of proteins on diverse amino acids including arginine, cysteine, histidine, aspartate, serine, threonine, and tyrosine. These protein kinases regulate different physiological processes in response to environmental modifications. For example, in response to nu…

Bacterial Genetics and BiotechnologyBacteriophages and microbial interactionsEnzyme Structure and Function

100k Cycles and Beyond: Extraordinary Cycle Stability for MnO2 Nanowires Imparted by a Gel Electrolyte

Mya Le Thai、Girija Thesma Chandran、Rajen K. Dutta 等 5 位作者2016-04-20ACS Energy Letters

We demonstrate reversible cycle stability for up to 200 000 cycles with 94–96% average Coulombic efficiency for symmetrical δ-MnO 2 nanowire capacitors operating across a 1.2 V voltage window in a poly(methyl methacrylate) (PMMA) gel electrolyte. The nanowires investigated here have a Au@δ-MnO 2 core@shell architectur…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Surface Structure of Hydroxyapatite from Simulated Annealing Molecular Dynamics Simulations

Hong Wu、Dingguo Xu、Mingli Yang 等 4 位作者2016-04-20Langmuir

The surface structure of hydroxyapatite (HAP) is crucial for its bioactivity. Using a molecular dynamics simulated annealing method, we studied the structure and its variation with annealing temperature of the HAP (100) surface. In contrast to the commonly used HAP surface model, which is sliced from HAP crystal and t…

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesCalcium Carbonate Crystallization and Inhibition

Chitosan-Based Thermosensitive Hydrogel for Controlled Drug Delivery to the Temporomandibular Joint

Wael Talaat、Mohamed Haider、Sausan Al Kawas 等 5 位作者2016-04-20Journal of Craniofacial Surgery

Intra-articular injections of hyaluronic acid (HA) and corticosteroids have been extensively used in treating temporomandibular disorders. However, rapid clearance from the site of injection is a major concern that is commonly managed by frequent dosing, which is not without complications. This study aimed to determin…

Hydrogels: synthesis, properties, applicationsTemporomandibular Joint DisordersSilk-based biomaterials and applications

Cellular Internalization of Therapeutic Oligonucleotides by Peptide Amphiphile Nanofibers and Nanospheres

Didem Mumcuoglu、Melis Şardan Ekiz、Gökhan Günay 等 6 位作者2016-04-20ACS Applied Materials & Interfaces

Oligonucleotides are promising drug candidates due to the exceptionally high specificity they exhibit toward their target DNA and RNA sequences. However, their poor pharmacokinetic and pharmacodynamic properties, in conjunction with problems associated with their internalization by cells, necessitates their delivery t…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliverySupramolecular Self-Assembly in Materials

Preparation and characterization of W/O/W type double emulsion containing PGPR–lecithin mixture as lipophilic surfactant

Ozlem Yuce Altuntas、Gülüm Şümnü、Serpil Şahin2016-04-20Journal of Dispersion Science and Technology

The objective of this study is to produce double emulsion by combining polyglycerol polyricinoleate (PGPR) with lecithin as lipophilic surfactant. Although lecithin alone produced only oil-in-water type emulsion, the mixture of lecithin and PGPR could produce water-in-oil type emulsion as well. Moreover, different emu…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Exciton Transport in an Organic Semiconductor Exhibiting Thermally Activated Delayed Fluorescence

S. Matthew Menke、Russell J. Holmes2016-04-20The Journal of Physical Chemistry C

Organic semiconductors characterized by a small singlet–triplet exciton energy splitting exhibit efficient reverse intersystem crossing and thermally activated delayed fluorescence. Consequently, exciton transport may occur along both the singlet and the triplet excited states, each with unique photophysical behavior…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Supercapacitor Sizing for Fast Power Dips in a Hybrid Supercapacitor—PEM Fuel Cell System

Giovanni Dotelli、Roberto Ferrero、Paola Gallo Stampino 等 5 位作者2016-04-20IEEE Transactions on Instrumentation and Measurement

Polymer electrolyte membrane fuel cell (PEM FC) operation is likely to be characterized by voltage dips on timescales shorter than 1 s, arising from temporary flooding of gas channels or porous layers, particularly when the FC is operated at high humidity levels. If supercapacitors are employed in hybrid systems, they…

Supercapacitor Materials and FabricationFuel Cells and Related MaterialsElectric and Hybrid Vehicle Technologies

Incommensurate-commensurate transitions in the monoaxial chiral helimagnet driven by the magnetic field

Víctor Laliena、Javier Campo、Jun‐ichiro Kishine 等 7 位作者2016-04-20Physical review. B./Physical review. B

The zero-temperature phase diagram of the monoaxial chiral helimagnet in the magnetic-field plane formed by the components parallel and perpendicular to the helical axis is thoroughly analyzed. The nature of the transition to the commensurate state depends on the angle between the field and the helical axis. For field…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Electrostatic Repulsion Governs TDP-43 C-terminal Domain Aggregation

Miguel Mompeán、Avijit Chakrabartty、Emanuele Buratti 等 4 位作者2016-04-20PLoS Biology

TDP-43 is a protein that forms aggregates implicated in amyotrophic lateral sclerosis. In response to a recent study, this Formal Comment argues that the pH-dependent solubility of this protein is better explained by the mutual repulsion of charged groups than by the formation of hydrogen bonds.

biodegradable polymer synthesis and propertiesAmyotrophic Lateral Sclerosis ResearchPrion Diseases and Protein Misfolding

Nanodroplet-Vaporization-Assisted Sonoporation for Highly Effective Delivery of Photothermal Treatment

Wei‐Wen Liu、Shu-Wei Liu、Yu-Ren Liou 等 7 位作者2016-04-20Scientific Reports

Sonoporation refers to the use of ultrasound and acoustic cavitation to temporarily enhance the permeability of cellular membranes so as to enhance the delivery efficiency of therapeutic agents into cells. Microbubble-based ultrasound contrast agents are often used to facilitate these cavitation effects. This study us…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Design and Development of Scaffolds for Tissue Engineering Using Three-Dimensional Printing for Bio-Based Applications

Fatah N. Habib、Mostafa Nikzad、Syed H. Masood 等 4 位作者2016-04-203D Printing and Additive Manufacturing

In recent years, tissue engineering (TE) has received more and more attention from scientific and research communities. One of the main requirements of this new approach is the fabrication of biocompatible and biodegradable scaffolds with required geometrical and mechanical properties. In TE, highly porous scaffold st…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Electrochemical Characteristics and Li+ Ion Intercalation Kinetics of Dual-Phase Li4Ti5O12/Li2TiO3 Composite in the Voltage Range 0–3 V

Humaira Safdar Bhatti、Dalaver H. Anjum、Shafiq Ullah 等 7 位作者2016-04-20The Journal of Physical Chemistry C

Li 4 Ti 5 O 12, Li 2 TiO 3, and dual-phase Li 4 Ti 5 O 12 /Li 2 TiO 3 composite were prepared by sol–gel method with average particle size of 1, 0.3, and 0.4 μm, respectively. Though Li 2 TiO 3 is electrochemically inactive, the rate capability of Li 4 Ti 5 O 12 /Li 2 TiO 3 is comparable to that of Li 4 Ti 5 O 12 at d…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Progress and Prospects in Stretchable Electroluminescent Devices

Jiangxin Wang、Pooi See Lee2016-04-20Nanophotonics

Abstract Stretchable electroluminescent (EL) devices are a new form of mechanically deformable electronics that are gaining increasing interests and believed to be one of the essential technologies for next generation lighting and display applications. Apart from the simple bending capability in flexible EL devices, t…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsNanowire Synthesis and Applications

Thermal Lensing and Multiwatt Microchip Laser Operation of Yb:YCOB Crystals

Pavel Loiko、Josep María Serres、Xavier Mateos 等 11 位作者2016-04-20IEEE photonics journal

Thermal lensing is studied in monoclinic Yb:Ca4YO(BO3)3(Yb: YCOB) oxoborate crystals cut along the optical indicatrix axes. For all orientations, the thermal lens is positive. In the Z-cut crystal, the sensitivity factors of the thermal lens are MZ-X= 2.4 and MZ-Y= 2.8 m-1/W (for E∥X), and the astigmatism degree is as…

Luminescence Properties of Advanced MaterialsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies