Materials Literature
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The CISSY end station combines thin film deposition (sputtering, molecular beam epitaxy ambient-pressure methods) with surface and bulk-sensitive analysis (photo emission, x-ray emission, x-ray absorption) in the same UHV system, allowing fast and contamination–free transfer between deposition and analysis. It is main…
Stimuli-responsive polymers have been widely used for controlled release of several biomolecules. In general, a single stimulus among various stimuli, for instance, temperature, pH, or light, has been used for these polymers. Although some stimuli are applied together, one cannot control each stimulus independently at…
Mesoporous iron phosphate (FePO4 ) was synthesized through assembly of polymeric micelles made of asymmetric triblock co-polymer (polystyrene-b-poly-2-vinylpyridine-b-ethylene oxide; PS-PVP-PEO). The phosphoric acid solution stimulates the formation of micelles with core-shell-corona architecture. The negatively charg…
With their unique optical properties and distinct Raman signatures, graphitic nanomaterials can serve as substrates for surface-enhanced Raman spectroscopy (SERS) or provide signal amplification for bioanalysis and detection. However, a relatively weak Raman signal has limited further biomedical applications. This has…
We chose a Sm-containing sandwich-type tungstophosphate K3Cs8[Sm(PW11O39)2]·10H2O (SmPW11) as a molecular dyad, which contains photoluminescence and electrochromism components in a skeletal structure, and investigated its electrofluorochromic performance both in solution and in composite films. First, the electrochemi…
We report the fabrication and device characteristics of exfoliated, few-layer, ReSe2 field effect transistors (FET) and a method to improve contact resistance by up to three orders of magnitude using ultra-high-vacuum annealing (UHV). Many devices were studied in the absence of light and we found an average contact of…
Mg–Fe layered double hydroxides had their electronic structures calculated by ab initio density-functional theory with GGA, GGA spin polarized, and GGA+U with periodic boundary conditions in order to study some of their properties, such as the anion release to use these compounds as fertilizers. The proposed fertilize…
The heterogeneous Fenton-like catalysts based on CuFe2O4 were prepared by polymeric precursor method at several annealing temperatures. The obtained catalysts were respectively characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, point of zero charge measurement, a…
Catalytic and optical properties can be coupled by combining different metals into nanoscale architectures in which both the shape and the composition provide fine-tuning of functionality. Here, discrete, small Pt nanoparticles (diameter = 3-6 nm) were grown in linear arrays on Au nanoprisms, and the resulting structu…
We demonstrate significantly improved photovoltaic response of monolayer molybdenum disulfide (MoS2)/indium phosphide (InP) van der Waals heterostructure induced by graphene quantum dots (GQDs). Raman and photoluminescence measurements indicate that effective charge transfer takes place between GQDs and MoS2, which re…
Equilibrated systems of entangled polymer melts cannot be produced using direct brute force equilibration due to the slow reptationdynamics exhibited by high molecular weight chains. Instead, these dense systems are produced using computational techniques such as Monte Carlo-Molecular Dynamics hybrid algorithms, thoug…
We provide theoretical and experimental evidence that introducing metallic rings and sub-rings in mesh unit cells significantly decreases the high-order diffraction energy. Moreover, rotating the sub-rings results in increased uniformity in the diffraction distribution without affecting the transmittance. Experiments…
In most iron-based superconductors, the transition to the magnetically ordered state is closely linked to a lowering of structural symmetry from tetragonal $({C}_{4})$ to orthorhombic $({C}_{2})$. However, recently, a regime of ${C}_{4}$-symmetric magnetic order has been reported in certain hole-doped iron-based super…
The corrosion inhibition efficiency of 2-amino-4-(2,4-dihydroxyphenyl) quinoline-3-carbonitrile (ADQC) on SAE 1006 steel has been investigated using electrochemical (EIS and Polarization), surface (SEM, EDX and AFM) and quantum chemical calculation methods. Results showed that inhibition efficiency increases with incr…
Intracellular compartments make up roughly two-thirds of the body, but delivery of molecular imaging probes to these spaces can be challenging. This situation is particularly true for probes designed for detection by magnetic resonance imaging (MRI), a high-resolution but relatively insensitive modality. Most MRI cont…
In this study, a facial method of fabricating hexagonal boron nitride nanosheet (BNNS) was proposed. Isopropyl alcohol was employed as the solvent to obtain the BNNS via exfoliation of the pristine hexagonal boron nitride. The yield of the exfoliated BNNS with thickness less than 20 nm was as high as 0.17–0.2 mg mL −1…
Homovalent [2 × 2] Co4 grid complexes [Co(II)4L(H)4](BF4)4 (1) and [Co(II)4L(Me)4](BF4)4 (2) with two new bis(terdentate) pyrazolate-bridged ligands, HL(H) = 3,5-bis(6-(1H-pyrazol-1-yl)pyrid-2-yl)pyrazole and HL(Me) = 4-methyl-3,5-bis(6-(1H-pyrazol-1-yl)pyrid-2-yl)pyrazole, were synthesized and comprehensively charact…
In light-activated liposomal drug delivery systems (DDSs), the light sensitivity can be obtained by a photothermal agent that converts light energy into heat. Excess heat increases the drug permeability of the lipid bilayer, and drug is released as a result. In this work, two near-IR responsive photothermal agents in…
Abstract The effect of air plasma treatment on wetting and energy properties, surface composition and morphology of polyether ether ketone ( PEEK ) was investigated. The influence of the storage time on the surface properties of plasma‐treated polymer plate was also examined. The properties were determined by advancin…
Effect of crystallographic texture on uniaxial tensile deformation of commercially pure titanium was studied using in situ as well as post-mortem electron backscatter diffraction and elastoplastic self-consistent simulations. Correlation of mechanical properties and strain hardening response with deformation micromech…