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ChemInform Abstract: Crystal Structure of Double Oxoborates LnCa4O(BO3)3 (I) (Ln: Gd, Tb, Lu) and Eu2CaO(BO3)2 (II).

Andrey B. Ilyukhin、B. F. Dzhurinskii1993-12-28ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsInorganic Chemistry and Materials

Rigorous coupled-wave analysis and applications of grating diffraction

Elias N. Glytsis、Thomas K. Gaylord、David L. Brundrett1993-12-28Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

A review of the rigorous coupled-wave analysis (RCWA) as applied to the diffraction of electromagnetic waves by gratings is presented. The analysis is valid for any polarization, angle of incidence, and for conical diffraction. Cascaded and/or multiplexed gratings as well as material anisotropy and loss can be incorpo…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Molecular tilt direction in a slightly tilted homeotropic aligned liquid crystal cell

Hitoshi Hatoh、Kiyoshi Shohara、Yoshihiro Kinoshita 等 4 位作者1993-12-27Applied Physics Letters

The influence of hardness and topology of substrate surface on the pretilt angle were investigated for a slightly tilted homeotropic alignment achieved by the rubbing technique. On a soft surface, the grooves are produced which align in the same direction as the rubbing direction while the liquid crystal molecules til…

Liquid Crystal Research AdvancementsAdhesion, Friction, and Surface Interactions

Very low friction for diamond sliding on diamond in water

Yonhua Tzeng1993-12-27Applied Physics Letters

This letter reports the lowest coefficient of friction measured for diamond sliding on diamond. When a natural diamond stylus with a spherical tip about 50 μm in diameter slides on a polished polycrystalline chemically vapor deposited diamond film in water at a speed of 0.05 mm/s under a load of 50 g, the coefficient…

Diamond and Carbon-based Materials ResearchAdhesion, Friction, and Surface InteractionsTunneling and Rock Mechanics

Nonequilibrium dynamics of discrete fluctuators in charge-density waves inNbSe3

I. Bloom、A. C. Marley、M. B. Weissman1993-12-27Physical Review Letters

Individual two-state and multistate fluctuators were found in the broadband noise in the sliding charge-density--wave (CDW) state of small samples of ${\mathrm{NbSe}}_{3}$. In the presence of dc currents, some multistate fluctuators violate detailed balance. Fluctuator properties show strong dependences on bias. As th…

Physics of Superconductivity and MagnetismMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Steric variation of the cerium valence in Ce2Fe14B and related compounds

T. W. Capehart、R. K. Mishra、G. P. Meisner 等 5 位作者1993-12-27Applied Physics Letters

Through measurements of the near-edge Ce L3 x-ray absorption structure we have investigated the influence of site volume on the cerium valence in Ce2Fe14B, Ce2Fe14BHx, and Ce2Fe17. The crystal structures of these compounds are isomorphic with those of technologically important permanent magnet materials. Confirming ot…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Interaction of C with Ni(100): Atom-resolved studies of the ‘‘clock’’ reconstruction

C. Klink、Laurits Højgaard Olesen、Flemming Besenbacher 等 6 位作者1993-12-27Physical Review Letters

The interaction of C with Ni(100) has been studied by scanning tunneling microscopy (STM). The C atoms, imaged as \ensuremath{\approxeq}0.3 \AA{} deep depressions consistent with theoretical predictions, are at low C coverages located in the fourfold hollow sites, causing a small radial displacement of the surrounding…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsAdvanced Materials Characterization Techniques

Ferroelectric La-Sr-Co-O/Pb-Zr-Ti-O/La-Sr-Co-O heterostructures on silicon via template growth

R. Ramesh、H. L. Gilchrist、T. Sands 等 6 位作者1993-12-27Applied Physics Letters

Ferroelectric Pb0.9La0.1Zr0.2Ti0.8O3 thin film capacitors with a symmetrical La-Sr-Co-O top and bottom electrodes have been grown on [001] Si with yttria stabilized zirconia (YSZ) buffer layer. A layered perovskite ‘‘template’’ layer (200–300 Å thick), grown between the YSZ buffer layer and the bottom La-Sr-Co-O elect…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Electronic structure of super-honeycomb systems: A peculiar realization of semimetal/semiconductor classes and ferromagnetism

Nobuyuki Shima、Hideo Aoki1993-12-27Physical Review Letters

Lateral superstructures with honeycomb symmetry are shown to be classified, with a simple criterion, into semimetals with gapless k-linear dispersions, semiconductors, and metals. In some of the classes, the symmetry enforces flat bands to exist, which implies the occurrence of ferromagnetism when the electron correla…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Fabrication of Conducting Polymer Interconnects

Corrine L. Curtis、Jason E. Ritchie、Michael J. Sailor1993-12-24Science

A nonmechanical approach to the construction of complex three-dimensional interconnect arrays has been developed with the use of conducting polymer dendrites. Electrically independent connections between pairs of wires in an array were successfully grown through alternating-current electrochemical polymerization of po…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

Molecular Light Emission Induced by Inelastic Electron Tunneling

Eli Flaxer、Ofer Sneh、Ori Cheshnovsky1993-12-24Science

Light emission from molecular layers has been induced by inelastically tunneling electrons in a tunneling junction. The fast quenching of molecular emission on metal surfaces was suppressed by use of the "transparent conductor" indium-tin-oxide for the junction electrodes. The emission measurements have been made in s…

Molecular Junctions and NanostructuresElectrochemical Analysis and ApplicationsElectronic and Structural Properties of Oxides

A Simple Kinetic Model of Polymer Adsorption and Desorption

Jack F. Douglas、Harry E. Johnson、Steve Granick1993-12-24Science

A model of the desorption and adsorption of a polymer layer at a planar surface indicates a transition from exponential kinetics at high temperatures to nonexponential kinetics (stretched exponential with index one-half) at lower temperatures where these processes are diffusion-limited. Measurements of polystyrene des…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Photosensitivity of rare-earth-doped glasses

Glen M. Williams、David A. Dutt、Jacqueline A. Ruller 等 7 位作者1993-12-22Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Rare earth-doped glasses exhibit high initial photosensitivity but their response saturates at relatively modest values of (Delta) n (approximately 5 X 10<SUP>-7</SUP>), which greatly limits their usefulness for device applications. In the context of our model, saturation results from either exhaustion of photosensiti…

Advanced Fiber Optic SensorsGlass properties and applicationsPhotonic Crystals and Applications

Sequential‐interpenetrating polymer networks from castor oil‐based polyesters. XXVI.

Bhikhu Suthar、Mayank Dave、Kanak Jadav1993-12-20Journal of Applied Polymer Science

Abstract Polyesters were obtained from castor oil and dibasic acids for example, malonic, succinic, glutaric, adipic, suberic, and sebacic acids. These prepolyesters were characterized by infrared spectrometry, viscosimetric measurements, and molecular weight determinations (GPC). These prepolyesters were mixed with m…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Stress relaxation behavior of polyacetal–thermoplastic polyurethane elastomer blends

Gurunathan Saravana Kumar、Mr. Arindam、N. R. Neelakantan 等 4 位作者1993-12-20Journal of Applied Polymer Science

Abstract The yield stress of polyacetal (POM) decreases monotonically with the incorporation of thermoplastic polyurethane (TPU) elastomer in POM/TPU blends as would be anticipated. However, the impact strength of the resultant POM/TPU blends increases initially up to 30% TPU and thereafter decreases with the addition…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Photodegradation of polymer materials containing flame‐cut agents

Ayako Torikai、Hitoshi Kato、Kenji Fueki 等 6 位作者1993-12-20Journal of Applied Polymer Science

Abstract Photodegradation of incombustible materials [polystyrene (PSt) and polypropyrene (PP) containing 2 wt% of decabromodiphenyl oxide (DBDE) or tetrabromobisphenol‐A (TBA) as a flame‐cut agent] were studied using Okazaki Large Spectrograph (OLS). Samples were irradiated in air at 23°C with monochromatic light of…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Observation of anomalously enhanced satellite in metastable atom electron spectrum ofLaCoO3

S. Masuda、Masaru Aoki、Yoshihisa Harada 等 7 位作者1993-12-20Physical Review Letters

The electron emission spectrum resulting from thermal collisions of ${\mathrm{He}}^{\mathrm{*}}$(${2}^{3}$S) atoms with ${\mathrm{LaCoO}}_{3}$ was measured as well as the h\ensuremath{\nu}-dependent photoemission spectra. The ${\mathrm{He}}^{\mathrm{*}}$ spectrum shows that the lower-lying Co 3d derived (main) bands a…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceMagnetic and transport properties of perovskites and related materials

Infrared spectroscopy studies of the effects of the catalyst on the ester cross‐linking of cellulose by poly(carboxylic acids)

Charles Q. Yang1993-12-20Journal of Applied Polymer Science

Abstract The esterification of cellulose by a poly(carboxylic acid) proceeds in two steps: the formation of a 5‐membered cyclic anhydride intermediate by the dehydration of two carboxyls, and the reaction between cellulose and the anhydride intermediate to form an ester. Sodium hypophosphite is the most effective cata…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Reactive processing of rubber–plastic blends: Role of chemical compatibilizer

Anil K. Bhowmick、Tsuneu Chiba、Takashi Inoue1993-12-20Journal of Applied Polymer Science

Abstract The present investigation was aimed at understanding the role of chemical compatibilizers like carboxy‐terminated nitrile rubber, amine‐terminated nitrile rubber, liquid carboxylated nitrile rubber, etc. in the reactive processing of a dynamically vulcanized 50 : 50 nylon/ HNBR blend. The interfacial paramete…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Eddy current damping of planar domain wall in bistable amorphous wires

R. P. del Real、C. Prados、D.-X. Chen 等 5 位作者1993-12-20Applied Physics Letters

An exact formula for the field produced by the eddy currents induced by transverse movements of a longitudinal planar domain wall in a magnetic cylinder is obtained. The result has been extended to satisfy the situation of bistable iron-rich amorphous wires and compared with the dMav/dt pulse of such wires during magn…

Metallic Glasses and Amorphous AlloysMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications