Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of Coordination Environment on the Electronic Structure and Properties of Mo6-Based Systems: A Density Functional TreatmentL. M. Robinson, R. L. Bain, D. F. Shriver, and D. E. EllisCite this: Inorg. Chem. 1995, 34, 22, 5588–5596Publication Date (Print):October 1, 1995…
The kinetic mechanism of the oxidative decarboxylation of 2R,3S-isopropylmalate by the NAD-dependent isopropylmalate dehydrogenase of Thermus thermophilus was investigated. Initial rate results typical of random or steady-state ordered sequential mechanisms are obtained for both the wild-type and two mutant enzymes (E…
The effect of nickel film thickness and the thickness of a porous ceramic layer, covering the Ni film, on anode polarization of a solid oxide electrolyte fuel cell was measured at around 1273 K. The electrode impedance was found to be dependent on the thickness of the porous layer but not on that of Ni film. DC polari…
Dental prostheses of Ti are normally cast in pure Ti. Some appliances, however, require higher yield strength. Casting of Ti alloys is of interest in such cases. The objective of the present work was to study the quality of castings made of Ti-6Al-4V compared with those made of pure Ti. Casting was made into a mold ke…
We have investigated both experimentally and theoretically the formation and subsequent growth of surface relief structures on thin diblock copolymer films. The surface pattern appearing upon annealing is characterized by the average domain radius R. Using atomic force microscopy, we have obtained time-dependent topog…
A simple method is presented for the analysis of protein conformational changes based on the comparison of torsion angles defined by four consecutive C alpha atoms. The technique was applied successfully to proteins that undergo hinge motion and shear motion. In the case of both MBP and LAO, which represent examples o…
The effect of Mn on the PTCR characteristics of La‐doped BaTiO 3 ceramics was studied. Acceptor state density was measured from a p‐1/ T graph as a function of Mn concentration. The behavior of room‐temperature resistivity with Mn concentration was explained by compensation of acceptors at grain boundaries. The valenc…
Abstract A novel glycopeptide‐containing block copolymer, poly[ O ‐(tetra‐ O ‐acetyl‐β‐ D ‐glucopyranosyl)‐ L ‐serine]‐ block ‐poly(2‐methyl‐2‐oxazoline) ( 5 ), was synthesized by mutual termination of living polymerizations of a sugar‐substituted α‐amino acid N ‐carboxyanhydride (NCA) ( 1 ) and 2‐methyl‐2‐oxazoline (…
We have developed an in situ TEM/PL apparatus, which enables us to excite PL emissions from a microscopic area of a specimen inside a TEM. The microscopical area of 20 μm can be examined by TEM, PL, and CL methods under the same experimental conditions. The apparatus may be applied to a transmission electron microscop…
The stability of ZrNi and ZrCo to heat cycles in hydrogen atmosphere was studied through changes in absorption-desorption characteristics and in crystallo-graphic structures. ZrCo easily lost its absorption-desorption capacity of hydrogen below 30 heat cycles between room temperature and a given temperature in a range…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReactivity of Copper in Molten Polytelluride Salts. K4Cu8Te11, A3Cu8Te10 (A = Rb, Cs), AA'2Cu8Te10 (A, A' = K, Rb, Cs), and A2BaCu8Te10 (A = K, Rb, Cs): Novel Solids Based on Endohedrally Occupied [Cu8Te12] Dodecahedral Cage-ClustersXiang Zhang, Younbong Park, Tim Hogan, Jon…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-Pressure Effects on the Disordered Phase of Block Copolymer MeltsDamian A. Hajduk, Paul Urayama, Sol M. Gruner, Shyamsunder Erramilli, Richard A. Register, Keith Brister, and Lewis J. FettersCite this: Macromolecules 1995, 28, 21, 7148–7156Publication Date (Print):Octob…
The spectrum of F-center creation has been measured for KBr:Tl by means of synchrotron radiation (12--24 eV). Analysis of the spectrum reveals the decay of cation excitons (19.7--20.3 eV) with the formation of a double amount of electron-hole pairs. The creation efficiency of a stable F center is especially high at 15…
Abstract Homogeneous precursor/precursor solutions with various compositions were obtained with appreciably high solid contents in N ‐methyl‐2‐pyrrolidone from soluble poly(amic diethyl ester) precursors of rodlike poly( p ‐phenylene biphenyltetracarboximide) (BPDA‐PDA) and flexible poly(4,4′‐oxydiphenylene biphenylte…
Indium‐tin‐oxide thin films were deposited by atomic layer epitaxy at 500°C using , , and water as precursors. The films were characterized by means of x‐ray diffraction, scanning electron microscopy, energy dispersive x‐ray analysis, polarography, and by optical and electrical measurements. The films had polycrystall…
The cationic polymerization of a cyclosiloxane mixture (hexamethyl-cyclotrisiloxane-D3, octamethylcyclotetrasiloxane-D4, decamethylcyclopentasiloxane-D5, dodecamethylcyclohexasiloxane-D6 and tetradecamethylcycloheptasiloxane-D7) in the presence of water as adjusting-control agent for molecular weight is studied in het…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChain Length and Temperature Dependence of the Self-Diffusion of Polyisoprene and Polybutadiene in the MeltGerald Fleischer and Matthias AppelCite this: Macromolecules 1995, 28, 21, 7281–7283Publication Date (Print):October 1, 1995Publication History Published online1 May 20…
Sulphate group: baryte celestine gypsum anhydrite. Carbonate group: calcite magnesite rhodochrosite siderite Smithsonite dolomite ankerite aragonite strontianite witherite cerussite Huntite nyerereite malachite and azurite. Phosphate group: apatite monazite. Halides: fluorite halite.
The perturbation of the racemic equilibrium of the D3 complexes of lanthanide (III) ions with 2, 6-pyridinedicarboxylate by a number of sugars is studied by circularly polarized luminescence spectroscopy. Various spectroscopic probes show that the addition of the chiral sugar has no observable effect on the structure…
The high‐frequency magnetic properties of strontium‐partially‐substituted Z‐type magnetoplumbite with the composition 2CoO·3Ba 1‐x .Sr x O.yFe 2 O 3 were studied using a hot‐pressing technique. The best properties were obtained for a sample hot‐pressed in oxygen, having x and y values of 0.5 and 10.8, respectively. Th…