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Changes in microstructure of soils following extraction of organically bonded metals and organic matter

Jacek Wierzchoś、C. ASCASO CIRIA、M. T. García‐González1992-09-01Journal of Soil Science

SUMMARY The influence of selective removal of organically bonded metals and organic matter on soil microstructure was investigated. Two samples of soils with different mineralogical, chemical and mechanical composition were treated with acetylacetone in both polar and non‐polar solvents to dissolve amorphous organic i…

Concrete and Cement Materials ResearchSoil and Unsaturated FlowClay minerals and soil interactions

Nickel by XPS

A. C. Miller、G.W. Simmons1992-09-01Surface Science Spectra

High energy resolution XPS spectra of sputter cleaned Ni (2 keV, Ar+1) are presented. The experimental width (16%–84% measurement) of the Fermi level was 0.32 ± 0.02 eV. The energy scale calibration is based on the Fermi level.

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Copper Removal from Water by Chemical Reduction with Sodium Borohydride

César Gómez-Lahoz、F. García Herruzo、José Miguel Rodríguez‐Maroto 等 4 位作者1992-09-01Separation Science and Technology

The use of NaBH4 as a chemical reductant to precipitate copper from water has been studied. Initial Cu2+ concentrations of 25 and 40 mg/L have been checked, and complete removal can be achieved. When solid NaBH4 is fed, BH4 − to Cu2+ molar ratios higher than 2 were needed. This can be substantially improved by using N…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

The stress dependence of k/sub 33/, d/sub 33/, lambda and mu in Tb/sub 0.3/Dy/sub 0.7/Fe/sub 1.95/

M. Schulze、R.D. Greenough、N. Galloway1992-09-01IEEE Transactions on Magnetics

DC field measurements of lambda , d/sub 33/, k/sub 33/, and mu under uniaxial prestresses up to approximately 20 MPa have made on a 152-mm-long 6-mm-diameter grain-oriented rod of Tb/sub 0.3/Dy/sub 07/Fe/sub 1.95/ prepared by a free float zone technique. The lambda -vs.-H curve shows a negative dip at low fields which…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Development of an Ammonia/SCR NOx Reduction System For A Heavy Duty Natural Gas Engine

John S. Walker、B.K. Speronello1992-09-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">An exhaust gas after-treatment system was developed to reduce oxides of nitrogen (NOx) emissions from a heavy duty diesel derived natural gas engine. The goal of the project was to reduce NOx emissions by 80% with a minimum ammonia slip and without negatively impacting other exhau…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Coincidence lattices and associated shear transformations

M. Duneau、C. Oguey、Abdelmalek Thalal1992-09-01Acta Crystallographica Section A Foundations of Crystallography

A general description of the mutual orientation of two lattices is presented for the cases where the orientation is `rational'. The coincidence site and displacement-shift complete lattices are genuine lattices whose parameters can be explicitly evaluated through a method based on the Smith normal form for integer mat…

Theoretical and Computational PhysicsQuasicrystal Structures and PropertiesMetallurgical and Alloy Processes

Sudoite in some Visean (Lower Carboniferous) K-bentonites from Belgium

Annick Anceau1992-09-01Clay Minerals

Abstract Sudoite occurs as a cryptocrystalline clay in some Visean K-bentonites from Belgium. Usually associated with illite-smectite mixed-layers, this chlorite has been found locally as a monomineralic clay component of a K-bentonite bed. The mineral has a composition close to (Al 3 Mg 2 )(Si 3 Al)O 10 (OH) 8 . The…

Geological and Geochemical AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

Molecular Recognition Using Cyanine-α-Helical Poly(L-Lysine) Complexes in Methanol

Hirotaka Ihara、Masaaki Shibata、Chuichi Hirayama1992-09-01Chemistry Letters

Abstract Cyanine dyes bound to α-helical poly(L-lysine·HBr) (PLL·HBr) in methanol provide extremely strong exciton couplings in CD spectra caused by their R-chiral dimer formation and that dyes-PLL complexes show varying degrees of remarkable strength change in the CD recognizing on their methylene numbers upon additi…

Molecular Sensors and Ion DetectionPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Photoluminescence of Sb3+ Centers in SrS and SrSe

Nobuhiko Yamashita、Y. Sasaki、Kaizo Nakamura1992-09-01Japanese Journal of Applied Physics

Emission and excitation spectra and luminescence decay times of the SrS:Sb 3+ and SrSe:Sb 3+ powder phosphors are studied over the temperature range from 2 to 372 K. The emission band at 293 K is located at 600 nm for SrS:Sb 2 S 3 (0.05 mol%) and at 633 nm for SrSe:Sb 2 S 3 (0.2 mol%). The excitation processes are att…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Anisotropic HDDR epoxy bonded magnets from NdFeBZr

P.J. McGuiness、C. Short、I.R. Harris1992-09-01IEEE Transactions on Magnetics

The hydrogenation disproportionation desorption recombination (HDDR) process has been established as an effective processing route for the production of isotropic NdFeB coercive powder. By the addition of very small amounts of zirconium to the initial composition, it has also been found that anisotropic powder can be…

Magnetic properties of thin filmsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Synthesis and properties of magnetically hard two element Sm/sub 5/Fe/sub 17/ phase in sputtered films

R. Rani、H. Hegde、A. Navarathna 等 5 位作者1992-09-01IEEE Transactions on Magnetics

The magnetic properties and synthesis of the magnetically hard strictly two element Sm/sub 5/Fe/sub 17/ phase were studied for sputtered film samples. Normally, bulk sample synthesis of this phase has required the substitution of at least 10 at.% of a transition metal, such as Ti for the Fe, to stabilize this phase. I…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Applications of FT-NMR to Crosslink Density Determinations in Natural Rubber Blend Vulcanizates

Paul S. Brown、Maya Jacob John、R. Loadman 等 4 位作者1992-09-01Rubber Chemistry and Technology

Abstract Previously 90 MHz CW-NMR spectroscopy has been used to estimate the crosslink density in individual components of elastomer blends. Transfer of the technique to a 300 MHz FT instrument is not straightforward. Chemical shifts of polymer resonances in spectra of single-polymer vulcanizates are dependent on cros…

Polymer Nanocomposites and Properties

Field-induced spirals from a confined cholesteric

Michel Mitov、P. Sixou1992-09-01Journal de Physique II

We have observed birefringent spirals induced by a field in a fingerprint texture of a cholesteric polymer in solution in a nematic low molar weight liquid crystal. This paper describes the conditions of nucleation of these spirals and the part of different parameters which determine their characteristics.

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsOptical Polarization and Ellipsometry

Preferential Exhibition of Smectic A Phase through Intramolecular Hydrogen Bonding in 2-Amino-5-phenyltropone Liquid Crystals

Akira Mori、Kouki Katahira、Katsuhiko Kida 等 4 位作者1992-09-01Chemistry Letters

Abstract Two new types of liquid crystals, 5-(4-alkanoylaminophenyl)-2-alkanoylaminotropones and 5-(4-alkanoylaminophenyl)-2-alkanoyloxytropones, were prepared. The former showed the smectic A phase and the latter did the smectic A and C phases. The 1H NMR spectra indicated the former to be in intramolecularly hydroge…

Liquid Crystal Research AdvancementsMolecular spectroscopy and chiralityAxial and Atropisomeric Chirality Synthesis

Observation of protrusions and ring structures on MoS2 by scanning tunneling microscopy

Haryani Permana、Sangho Lee、Kwok-Wai Ng1992-09-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Natural MoS2 was investigated by scanning tunneling microscopy operated in air. The atomic resolution image yields the hexagonal symmetry of the surface of the crystal with lattice constant of 3.1 Å, in agreement with the reported x-ray crystallographic value. Corrugations along the [110] cell diagonal show major and…

2D Materials and ApplicationsMolecular Junctions and NanostructuresSurface and Thin Film Phenomena

Characteristics of magnetic media models

Ferenc Vajda、E. Della Torre1992-09-01IEEE Transactions on Magnetics

Full characterization of particulate recording media requires the modeling of both the reversible and the irreversible components of the magnetization. Experiments show that the height of minor loops originating from negative saturation is not an even function of the magnetization. A moving Preisach-type model with re…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Sulphate-reducing bacteria associated with biocorrosion: a review

Tânia Cremonini de Araújo-Jorge、Cláudia Mara Lara Melo Coutinho、Luiz Edmundo Vargas de Aguiar1992-09-01Memórias do Instituto Oswaldo Cruz

Biocorrosion means any process of corrosion in wich microorganisms are somehow involved. As far as the petroleum industry is concerned, the anaerobic type is the more important, with Sulphate-Reducing Bacteria (SRB) accouting for half of the described processes. SRB are obligate anaerobs that use sulphur, sulphate or…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Thermodynamic Properties of Alkali Silicates: Heat Capacity of Li 2 SiO 3 and Lithium‐Bearing Melts

Christophe Téqui、Paul Grinspan、Pascal Richet1992-09-01Journal of the American Ceramic Society

The heat capacities of liquid Li 2 SiO 3 and Li 2 Si 3 O 7 have been determined through drop calorimetry measurements to complement available data on lithium, sodium, and potassium silicate melts. The composition and temperature dependences of the heat capacity depends specifically on the nature of the alkali element,…

Glass properties and applicationsClay minerals and soil interactionsMineralogy and Gemology Studies

Complex Impedance Analysis of Nb-Doped (Ba0.6Sr0.4)TiO3 PTC (Positive Temperature Coefficient) Thermistors

Toshishige Yamamoto Takao1992-09-01Japanese Journal of Applied Physics

Frequency-dependent complex impedances were measured in Nb-doped (Ba 0.6 Sr 0.4 )TiO 3 PTC (positive temperature coefficient) ceramics. The complex impedance data were analyzed in Cole-Cole-type equivalent circuits by the computer fitting method in order to determine individual resistance and capacitance values of the…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectrical and Thermal Properties of Materials

In situ Raman spectroscopy of diamond during growth in a hot filament reactor

Luis J. Bernardez、Kevin F. McCarty、Ning Yang1992-09-01Journal of Applied Physics

We report a system capable of obtaining Raman spectra during growth of carbon films in a hot filament reactor. A gated, multichannel detection system was used to discriminate against the high levels of background radiation produced by the hot substrate and the hot filament. The ability to detect and distinguish betwee…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis