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The craze initiation response of a polystyrene and a styrene‐acrylonitrile copolymer during physical aging

Gloria M. Gusler、Gregory B. McKenna1997-09-01Polymer Engineering and Science

Abstract The influence of structural recovery or physical aging on the craze initiation of amorphous polystyrene and a styrene‐acrylonitrile copolymer has been examined in two states of stress/deformation and at different temperatures. Studies of craze initiation in equibiaxial creep were performed using a “bubble” in…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Synthesis of Dichloro(phthalocyaninato)antimony(V) Perchlorate, Tetrafluoroborate, and Hexafluorophosphate and Electrochemical Reinvestigation on the New Complex Salts

Yutaka Kagaya、Hiroaki Isago1997-09-01Bulletin of the Chemical Society of Japan

Abstract The titled new salts were synthesized by exchanging the unknown counter anion of [Sb(pc)Cl2]+ salt (pc2− = phthalocyaninate, C32H16N82−), which was the first product of the reaction of phthalonitrile with antimony(III) trichloride, with perchlorate, tetrafluoroborate, and hexafluorophosphate. Elemental analyt…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry Reactions

Effect of extrusion conditions on rigid PVC foam

Elvira B. Rabinovitch、James D. Isner、James A. Sidor 等 4 位作者1997-09-01Journal of Vinyl and Additive Technology

Abstract There is a growing demand for rigid vinyl foam as a wood replacement in window frames, blinds, trimming and other applications. While rigid vinyl foam has existed for many years, additional understanding of its processability and required conditions for good quality extruded profile would be helpful. This pap…

Pickering emulsions and particle stabilizationPolymer Foaming and CompositesPolymer Science and PVC

Calibration of the monochromator bandpass function for the X-ray Rietveld analysis

Pietro Riello、Patrizia Canton、G. Fagherazzi1997-09-01Powder Diffraction

In this paper we propose a fitting procedure to describe the bandpass effect on all x radiation that passes through a focusing graphite monochromator used on the diffracted beam. The proposed bandpass function is: M (2θ)=1/(1+ K mon 1 s K mon 2 ), with s =(2 sin θ)/λ, where K mon 1 and K mon 2 are constants which have…

X-ray Spectroscopy and Fluorescence AnalysisX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Pressure-induced metallization and structural transition of α-monoclinic and amorphous Se

Yuichi Akahama、Mototada Kobayashi、Haruki Kawamura1997-09-01Physical review. B, Condensed matter

Electrical resistance measurements and x-ray-diffraction experiments have been carried out under high pressure for \ensuremath{\alpha}-monoclinic and amorphous and trigonal Se. \ensuremath{\alpha}-monoclinic Se showed a transition to the metallic state at 12 GPa, which was considerably lower than 23 GPa of trigonal Se…

High-pressure geophysics and materialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Implementation of Parameters in the Expansion Ratio of Mesh Skin Grafts

J Vandeput、Jasmine C. Tanner、John A. Boswick1997-09-01Plastic & Reconstructive Surgery

Expansion of a mesh skin graft depends on factors pertaining to the graft itself as well as on parameters of the meshing device. With regard to the graft, we examine the efficiency of graft handling and thickness of the skin graft. With regard to the parameters of the meshing apparatus, which determine the expansion r…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Raman scattering in silicate garnets: an investigation of their resonance intensities

Boris A. Kolesov、Charles A. Geiger1997-09-01Journal of Raman Spectroscopy

The intensity of Raman modes of four different silicate garnets in the energy range 1.9–2.7 eV was investigated. In the case of almandine (Fe3Al2Si3O12) and pyrope (Mg3Al2Si3O12) no change in intensities was observed in this energy region and in uvarovite (Ca3Cr2Si3O12) a weak resonance maximum was observed between 2.…

Glass properties and applicationsCrystal Structures and PropertiesMineralogy and Gemology Studies

Surface analysis study of the oxidation of organotin films deposited by ArF excimer laser chemical vapor deposition

R. Larciprete、E. Borsella、Paola De Padova 等 5 位作者1997-09-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

ArF excimer laser photolysis of gas phase tetramethyltin was used to deposit thin organotin films on Si. In situ Auger electron spectroscopy and x-ray photoelectron spectroscopy (XPS) film analysis, showed the presence of C and Sn, which, according to C 1s and Sn 3d5/2 peak deconvolution, were organized in highly bran…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsSemiconductor materials and devices

Multislice Method for Large Beam Tilt with Application to HOLZ Effects in Triclinic and Monoclinic Crystals

J. H. Chen、D. Van Dyck、Maarten Op de Beeck1997-09-01Acta Crystallographica Section A Foundations of Crystallography

Three existing multislice formulations (MS) that are claimed to be applicable for large beam tilt are introduced in a unified form and the validity of these formulations for large beam tilt is evaluated. It is shown that one formula, which is called MSSBT (the MS for small beam tilt), is valid only for tilt angles les…

Radiation Detection and Scintillator TechnologiesX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Resilience Properties of Polypropylene Carpets

Hans Vangheluwe、Paul Kiekens1997-09-01Textile Research Journal

This paper deals with the problem of carpet resilience which depends on pile yarn properties and carpet construction characteristics. Up to now, resilience could only be measured on the carpet itself. New methods are being developed to assess the resilience properties of pile yarns directly before carpet manufacturing…

Natural Fiber Reinforced CompositesTextile materials and evaluationsErgonomics and Musculoskeletal Disorders

A comparison of the effectiveness of thermoluminescent crystals LiF:Mg,Ti, and LiF:Mg,Cu,P for clinical dosimetry

Christie K. Harris、Howard R. Elson、Michael Lamba 等 4 位作者1997-09-01Medical Physics

This study compared the relative effectiveness of TLD crystals LiF:Mg,Ti (TLD-100) and LiF:Mg,Cu,P (TLD-700H) for clinical dosimetry, focusing on reproducibility, linearity, and energy response. Experimental results indicated that TLD-700H was superior to TLD-100 with regard to reproducibility, lack of supralinearity,…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear Physics and Applications

Classification of the Pore Structure of n‐Type Silicon and Its Microstructure

Tetsuya Ōsaka、Kako Ogasawara、S. Nakahara1997-09-01Journal of The Electrochemical Society

Porous silicon samples were grown under various anodization conditions on {100} oriented n‐silicon substrates. Scanning and transmission electron microscope observations have shown that the microstructure of porous silicon primarily falls into three categories, which can be classified as single layer, double layer, an…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnodic Oxide Films and Nanostructures

Influence of soil solution Ca concentration on short‐term K release and fixation of a loamy soil

A. Schneider1997-09-01European Journal of Soil Science

Summary The Ca concentration of the soil solution influences K plant nutrition by its influence on K concentration of the soil solution and on soil buffer power through ion exchange and K release or fixation. The effects of the imposed solution Ca concentration on the estimates of these parameters and on these two phe…

Plant nutrient uptake and metabolismPlant Micronutrient Interactions and EffectsClay minerals and soil interactions

Electrical Properties of Pineapple Fibre Reinforced Polyethylene Composites

G. Jayamol、S. S. Bhagawan、Sabu Thomas1997-09-01Journal of Polymer Engineering

Pineapple-fibre-reinforced, low-density polyethylene (LDPE) composites were prepared by a solution mixing-technique. The dielectric constant, volume resistivity, and dielectric loss factor of the composites were evaluated as a function of frequency, fibre content, and fibre length. The dielectric constant values were…

Advanced Sensor and Energy Harvesting MaterialsNatural Fiber Reinforced CompositesMaterial Properties and Processing

Electrochemical Polymerization and Depolymerization of 2,5-Dimercapto-1,3,4-thiadiazole. QCM and Spectroscopic Analysis

Tetsu Tatsuma、Y. Yokoyama、Daniel A. Buttry 等 4 位作者1997-09-01The Journal of Physical Chemistry B

Electrochemical oxidation of a dimercaptan, 2,5-dimercapto-1,3,4-thiadiazole (DMcT), to a polydisulfide (DMcT polymer) and electrochemical reduction of the polydisulfide at a carbon electrode and an indium−tin oxide electrode have been studied in 0.1 M LiClO 4 −acetonitrile by means of an in situ electrochemical quart…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

Organo-Soluble Polyimides: Synthesis and Characterization of Polyimides Containing Phenylated p-Biphenyl and p-Terphenyl Units

Frank W. Harris、Yoshimitsu Sakaguchi、Mitsuhiro Shibata 等 4 位作者1997-09-01High Performance Polymers

4, 4′-diamino-2, 2′-diphenylbiphenyl (1), 4,4″-diamino-2′, 3′, 5′-triphenyl- p-terphenyl (2a) and 4,4″-diamino-2′, 3′, 5′, 6′-tetraphenyl- p-terphenyl (2b) have been polymerized with several aromatic dianhydrides in refluxing m-cresol containing isoquinoline to afford a series of phenylated polyimides. The polymerizat…

Synthetic Organic Chemistry MethodsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Structural control of TiO2 film grown on MgO(001) substrate by Ar-ion beam sputtering

Toshihiko Aoki、Kunisuke Maki、Qi Tang 等 5 位作者1997-09-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The structure of a 50-nm-thick TiO2 film grown on MgO(001) substrate maintained at 630 °C was studied by x-ray diffraction. Each film was fabricated by varying both the deposition rate of Ti atoms, which are produced by Ar-ion beam sputtering onto a Ti target, and the partial pressure of O2 gas (PO2). When Ti atoms ar…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Cloning and Expression of the fadH Gene and Characterization of the Gene Product 2,4‐Dienoyl Coenzyme A Reductase from Escherichia Coli

Xue‐Ying He、Song‐Yu Yang、Horst Schulz1997-09-01European Journal of Biochemistry

The fadH gene coding for an NADPH-dependent 2.4-dienoyl-CoA reductase from Escherichia coli has been cloned by the polymerase chain reaction. This gene is located at 67.65 min on the E. coli chromosome. The complete open reading frame contains 2019 bp coding for the processed protein of 671 amino acid residues, with a…

Bacterial Genetics and BiotechnologyMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

Adsorption of acid dye from aqueous solution by chitin: Equilibrium studies

G. Annadurai、M. R. V. Krishnan1997-09-01Indian Journal of Chemical Technology

Chitin has the ability to adsorb substantial quantities of dyestuff from aqueous solutions. The design procedures for batch kinetic study have been investigated for an acid dye, Lansayin brown grl. The effect of several factors governing the dye adsorption such as the adsorbent concentration, adsorbent size, temperatu…

Adsorption and biosorption for pollutant removalNanocomposite Films for Food PackagingWater Quality Monitoring and Analysis

Deactivation of Pyrophoric Iron Sulfides

Robert A. Walker、Alan D. Steele、David T. B. Morgan1997-09-01Industrial & Engineering Chemistry Research

Rust formed by corrosion on the inner surfaces of oil tanks may react with hydrogen sulfide gas in the vapor above crude oil. This reaction produces mixtures of iron sulfides which are pyrophoric, and they cause explosions when they are exposed to air during the unloading of the tankers. This paper shows that it is po…

Hydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure MechanismsOil, Gas, and Environmental Issues