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Formation of Boron-Carbon Nanosheets and Bilayers in Boron-Doped Diamond: Origin of Metallicity and Superconductivity

S. N. Polyakov、В. Н. Денисов、B. N. Mavrin 等 8 位作者2016-01-12Nanoscale Research Letters

The insufficient data on a structure of the boron-doped diamond (BDD) has frustrated efforts to fully understand the fascinating electronic properties of this material and how they evolve with doping. We have employed X-ray diffraction and Raman scattering for detailed study of the large-sized BDD single crystals. We…

2D Materials and ApplicationsDiamond and Carbon-based Materials ResearchMXene and MAX Phase Materials

Diffusion-trapping modelling of hydrogen recycling in tungsten under ELM-like heat loads

K. Schmid2016-01-12Physica Scripta

The recycling of D ions impinging onto a W divertor surface is a key input parameter into the power and momentum balance at the target boundary during SOL modeling. It is described by the ratio R of the flux of recombining D 2 molecules to the non-reflected incident ion flux. In steady-state plasmas where the surface…

Magnetic confinement fusion researchFusion materials and technologiesNuclear Materials and Properties

Influence of Li+ and H+ Distribution on the Crystal Structure of Li7–xHxLa3Zr2O12 (0 ≤ x ≤ 5) Garnets

Alodia Orera、G. Larraz、J. Alberto Rodríguez‐Velamazán 等 5 位作者2016-01-12Inorganic Chemistry

With appropriate doping or processing, Li7La3Zr2O12 (LLZO) is an excellent candidate to be used in Li batteries either as a solid electrolyte or as a separator between the Li anode and a liquid electrolyte. For both uses, the reactivity with water either from the air or in aqueous media is a matter of interest. We add…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyMicrowave Dielectric Ceramics Synthesis

Seed‐Mediated Growth of Silver Nanocubes in Aqueous Solution with Tunable Size and Their Conversion to Au Nanocages with Efficient Photothermal Property

Zhen‐Wen Lin、Yuchi Tsao、Min‐Yi Yang 等 4 位作者2016-01-12Chemistry - A European Journal

Two seed-mediated approaches for the growth of silver nanocubes in aqueous solution have been developed. Addition of a silver-seed solution to a mixture of cetyltrimethylammonium chloride (CTAC), silver trifluoroacetate, and ascorbic acid and heating the solution at 60 °C for 1.5 h produces uniform Ag nanocubes with t…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesSolar-Powered Water Purification Methods

A 3D platform for the morphology modulation of materials: first principles calculations on the thermodynamic stability and surface structure of metal oxides: Co3O4,α-Fe2O3, and In2O3

Mateus M. Ferrer、Amanda F. Gouveia、Lourdes Gracia 等 5 位作者2016-01-12Modelling and Simulation in Materials Science and Engineering

Essentially, the exposed crystal planes of a given material, which primarily determine their morphology, tremendously affect its behavior. First principle calculations, based on the Wulff construction model and broken bonding density index, have been performed to calculate the equilibrium and their transformations for…

Catalytic Processes in Materials ScienceIron oxide chemistry and applicationsCopper-based nanomaterials and applications

Interactions of metal-based engineered nanoparticles with aquatic higher plants: A review of the state of current knowledge

Melusi Thwala、Stephen J. Klaine、Ndeke Musee2016-01-12Environmental Toxicology and Chemistry

The rising potential for the release of engineered nanoparticles (ENPs) into aquatic environments requires evaluation of risks to protect ecological health. The present review examines knowledge pertaining to the interactions of metal-based ENPs with aquatic higher plants, identifies information gaps, and raises consi…

Nanoparticles: synthesis and applicationsHeavy metals in environment

Tuning thermoelectricity in a Bi2Se3topological insulator via varied film thickness

Minghua Guo、Zhenyu Wang、Yong Xu 等 13 位作者2016-01-12New Journal of Physics

We report thermoelectric transport studies on Bi 2 Se 3 topological insulator thin films with varied thickness grown by molecular beam epitaxy. We find that the Seebeck coefficient and thermoelectric power factor decrease systematically with the reduction of film thickness. These experimental observations can be expla…

Advanced Thermoelectric Materials and DevicesTopological Materials and PhenomenaThermal properties of materials

Large Nonclassical Electrostriction in (Y, Nb)‐Stabilized δ‐Bi2O3

Nimrod Yavo、Alaric Smith、O. Yeheskel 等 8 位作者2016-01-12Advanced Functional Materials

Classical electrostriction, describing a second‐order electromechanical response of insulating solids, scales with elastic compliance, S, and inversely with dielectric susceptibility, ε. This behavior, first noted 20 years ago by Robert Newnham, is shown to apply to a wide range of electrostrictors including polymers,…

Ferroelectric and Piezoelectric MaterialsAdvancements in Solid Oxide Fuel CellsMicrowave Dielectric Ceramics Synthesis

Doping Graphene Transistors Using Vertical Stacked Monolayer WS2 Heterostructures Grown by Chemical Vapor Deposition

Haijie Tan、Ye Fan、Youmin Rong 等 10 位作者2016-01-12ACS Applied Materials & Interfaces

We study the interactions in graphene/WS2 two-dimensional (2D) layered vertical heterostructures with variations in the areal coverage of graphene by the WS2. All 2D materials were grown by chemical vapor deposition and transferred layer by layer. Photoluminescence (PL) spectroscopy of WS2 on graphene showed PL quench…

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

Creation of a Hybrid Scaffold with Dual Configuration of Aligned and Random Electrospun Fibers

Suk-Hee Park、Min Sung Kim、Byungjun Lee 等 8 位作者2016-01-12ACS Applied Materials & Interfaces

A novel hybrid construct was developed by combining aligned fibers (AFs) and random fibers (RFs) to form a scaffolding system. Homogeneous fiber-based structures were fabricated by electrospinning, which produced both random and aligned fiber mats depending on the collection method. The upper part of the scaffold cont…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Silk Fibroin Degradation Related to Rheological and Mechanical Properties

Benjamin P. Partlow、A. Pasha Tabatabai、Gary G. Leisk 等 6 位作者2016-01-12Macromolecular Bioscience

Regenerated silk fibroin has been proposed as a material substrate for biomedical, optical, and electronic applications. Preparation of the silk fibroin solution requires extraction (degumming) to remove contaminants, but results in the degradation of the fibroin protein. Here, a mechanism of fibroin degradation is pr…

Polymer Surface Interaction StudiesSilk-based biomaterials and applicationsBiochemical and Structural Characterization

Two-dimensional honeycomb network through sequence-controlled self-assembly of oligopeptides

Sabine Abb、Ludger Harnau、Rico Gutzler 等 5 位作者2016-01-12Nature Communications

The sequence of a peptide programs its self-assembly and hence the expression of specific properties through non-covalent interactions. A large variety of peptide nanostructures has been designed employing different aspects of these non-covalent interactions, such as dispersive interactions, hydrogen bonding or ionic…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsSurface Chemistry and Catalysis

Origin of the magnetization and compensation temperature in rare-earth orthoferrites and orthochromates

Hong Jian Zhao、Jorge Íñiguez、Xiang Ming Chen 等 4 位作者2016-01-12Physical review. B./Physical review. B

We consider orthoferrite and orthochromite perovskites with the formula $\mathit{RM}{\mathrm{O}}_{3}$, where $R$ is a lanthanide and $M$ is Fe or Cr. We identify an atomistic interaction that couples the magnetic moments of the $R$ and $M$ cations with the oxygen octahedral rotations characterizing these crystals. We…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Thermal shock tests to qualify different tungsten grades as plasma facing material

M. Wirtz、J. Linke、Th. Loewenhoff 等 5 位作者2016-01-12Physica Scripta

The electron beam device JUDITH 1 was used to establish a testing procedure for the qualification of tungsten as plasma facing material. Absorbed power densities of 0.19 and 0.38 GW m −2 for an edge localized mode-like pulse duration of 1 ms were chosen. Furthermore, base temperatures of room temperature, 400 °C and 1…

Metal and Thin Film MechanicsFusion materials and technologiesNuclear Materials and Properties

Optimisation of the ceramic-like body for ceramifiable EVA-based composites

Xinhao Gong、Tingwei Wang2016-01-12Science and Engineering of Composite Materials

Abstract Various ceramifiable ethylene-vinyl acetate copolymer (EVA) composites were prepared by melt blending with two kinds of glass frits, organically modified montmorillonite (OMMT) and whitened and capsulised red phosphorus (WCRP). The influence of different filler components and firing temperatures on the cerami…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSilicone and Siloxane Chemistry

The effect of surface wettability on water vapor condensation in nanoscale

Dong Niu、G.H. Tang2016-01-12Scientific Reports

The effect of surface wettability on condensation heat transfer in a nanochannel is studied with the molecular dynamics simulations. Different from the conventional size, the results show that the filmwise mode leads to more efficient heat transfer than the dropwise mode, which is attributed to a lower interfacial the…

Thermal properties of materialsNanopore and Nanochannel Transport Studiesnanoparticles nucleation surface interactions

Formation, Migration, and Reactivity of Au–CO Complexes on Gold Surfaces

Jun Wang、Monica McEntee、Wenjie Tang 等 7 位作者2016-01-12Journal of the American Chemical Society

We report experimental as well as theoretical evidence that suggests Au-CO complex formation upon the exposure of CO to active sites (step edges and threading dislocations) on a Au(111) surface. Room-temperature scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy, transmission infrared spectroscopy,…

Advanced Chemical Physics StudiesCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Reduction of thermal conductivity by surface scattering of phonons in periodic silicon nanostructures

Roman Anufriev、Jérémie Maire、Masahiro Nomura2016-01-12Physical review. B./Physical review. B

We investigate the impact of various phonon-scattering mechanisms on the in-plane thermal conductivity of suspended silicon thin films with two-dimensional periodic arrays of holes, i.e., phononic crystal (PnC) nanostructures. A large amount of data on the PnC structures with square, hexagonal, and honeycomb lattices…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

A Novel and Facile One-Pot Solvothermal Synthesis of PEDOT–PSS/Ni–Mn–Co–O Hybrid as an Advanced Supercapacitor Electrode Material

Chengjie Yin、Chunming Yang、Min Jiang 等 7 位作者2016-01-12ACS Applied Materials & Interfaces

In this work, a novel and facile one-pot method has been developed for the synthesis of a hybrid consisting of Ni-Mn-Co ternary oxide and poly(3,4-ethylenedioxythiophene)-polystyrenesulfonate (PEDOT-PSS/NMCO) with a hierarchical three-dimensional net structure via a solvothermal-coprecipitation coupled with oxidative…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationConducting polymers and applications

High Efficiency Green Phosphor Ba9Lu2Si6O24:Tb3+: Visible Quantum Cutting via Cross-Relaxation Energy Transfers

Yongfu Liu、Jianxin Zhang、Changhua Zhang 等 5 位作者2016-01-12The Journal of Physical Chemistry C

Tb 3+ -doped phosphors are widely used in fluorescent lamps and plasma display panels (PDP) due to the strong vacuum ultraviolet (VUV)/UV light absorption of Tb 3+ . Most of these phosphors are fluorides. The quantum efficiency (QE) of these phosphors is more than 90%; however, it is still too low. Theoretically, one…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRadiation Detection and Scintillator Technologies