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Anisotropy study of multiferroicity in the pyroxene NaFeGe2O6

Matthias Ackermann、Lionel Andersen、T. Lorenz 等 5 位作者2015-01-20New Journal of Physics

We present a study of the anisotropy of the dielectric, magnetic and magnetoelastic properties of the multiferroic clinopyroxene NaFeGe 2 O 6 . Pyroelectric currents, dielectric constants and magnetic susceptibilities as well as the thermal expansion and the magnetostriction were examined on large synthetic single cry…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

B═N Bond Cleavage and BN Ring Expansion at the Surface of Boron Nitride Nanotubes by Iminoborane

Rajashabala Sundaram、Steve Scheiner、Ajit K. Roy 等 4 位作者2015-01-20The Journal of Physical Chemistry C

A new feature of reactivity of iminoborane (HBNH) at the surface of boron nitride nanotube has been revealed by this theoretical study. The HBNH molecule not only selectively breaks the B═N double bond of the BN nanotubes (BNNTs) but also expands the hexagonal network of the tube to larger cages at the surface. Such e…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Effect of Oil Palm Ash on the Properties of Polypropylene/Recycled Natural Rubber Gloves/Oil Palm Ash Composites

Hanafi Ismail、Tan Boon Khoon、Nabil Hayeemasae 等 4 位作者2015-01-20BioResources

In the present study, polypropylene, recycled natural rubber gloves, and oil palm ash composites (PP/rNRg/OPA) were prepared using an internal mixer. The effects that OPA loading had on the processability, tensile properties, morphology, and thermal stability of the PP/rNRg/OPA composites were investigated. The stabil…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Residence time distributions in a co‐kneader: A chemical engineering approach

Benjamin Monchatre、Claude Raveyre、Christian Carrot2015-01-20Polymer Engineering and Science

In this article, we have studied the residence time distributions (RTD) in a modular co‐kneader. Several papers have already addressed the co‐kneader modeling and operating mode but there is still a lack of experimental data on RTD. To investigate the RTD, we have used a colored tracer dispersed in polypropylene (PP)…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesInjection Molding Process and Properties

Effect of Fe on the structure of potassium borosilicate glasses

V. E. Eremyashev、A. B. Mironov2015-01-20Inorganic Materials

The behavior of Fe in the structure of Fe-containing potassium borosilicate glasses with different relationships between network-forming and modifier cations has been studied by Mössbauer and vibrational spectroscopies. The results demonstrate that the Fe-free and Fe-containing potassium borosilicate glasses differ in…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMineralogy and Gemology Studies

Convergent Strategy for the Regioselective Synthesis of Nonaggregated α-Triaryl-β-carboxy Zinc Phthalocyanines

Lara Tejerina、M. Victoria Martínez‐Díaz、Tomás Torres⊗2015-01-20Organic Letters

A new design of nonaggregated zinc(II) carboxyphthalocyanines with potential application in dye-sensitized solar cells has been developed. It is based on the introduction of bulky and rigid aryl groups at three α positions of the macrocycle. The synthesis has been carried out following a convergent route in which the…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesPorphyrin and Phthalocyanine Chemistry

UV cathodoluminescence of Gd3+doped and Gd3+Pr3+co-doped YAlO3epitaxial thin films

Yuhei Shimizu、Kazushige Ueda、Hiroshi Takashima 等 4 位作者2015-01-20physica status solidi (a)

Thin films of YAlO3:Gd3+ and YAlO3:Gd3+Pr3+ were prepared on LaAlO3 (001) single crystal substrates by pulsed laser deposition (PLD). Both films were grown epitaxially and their surfaces were uniformly smooth. Under UV excitation at 216 nm, YAlO3:Gd3+ film did not show any intense photoluminescence (PL); on the other…

Luminescence Properties of Advanced MaterialsSemiconductor materials and devicesGa2O3 and related materials

Effects of the hydrophilicity or hydrophobicity of the neutral block on the structural formation of a block polyelectrolyte/surfactant complex: A molecular dynamics simulation study

Z.H. Liu、Wenjuan Lv、Shanlin Zhao 等 7 位作者2015-01-20Computational Condensed Matter

The mechanism of how the neutral block in polyelectrolyte (PE) affects the interaction between PE and surfactants is investigated through coarse-grained simulations. We show that the neutral block plays profound roles on the structural formation of the PE/surfactant complex by assessing the adsorption of surfactants o…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions

Electronic structure and mechanical properties of X2MnSn (X = Cu, Ni, Pd) under hydrostatic pressure: GGA + U calculations

B. Hamri、B. Abbar、A. Hamri 等 6 位作者2015-01-20Computational Condensed Matter

We investigate the mechanical, electronic and magnetic properties of the full Heusler compounds X2MnSn (X = Cu, Ni, Pd) under hydrostatic pressure using the generalized gradient approximation + U method. We present also a comparison between the electronic and magnetic properties provided by DFT and those computed by D…

Intermetallics and Advanced Alloy PropertiesBoron and Carbon Nanomaterials ResearchHeusler alloys: electronic and magnetic properties

Interaction of a Patterned Amphiphilic Polyphenylene Dendrimer with a Lipid Monolayer: Electrostatic Interactions Dominate

Masanari Okuno、Markus Mezger、René Stangenberg 等 7 位作者2015-01-20Langmuir

Dendrimeric macromolecules with defined shape and size are promising candidates for delivering drug or DNA molecules into cells. In this work we study the influence of an amphiphilic polyphenylene dendrimer on a model cell membrane consisting of a condensed 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) lipid mono…

Lipid Membrane Structure and BehaviorSpectroscopy and Quantum Chemical StudiesDendrimers and Hyperbranched Polymers

Squid Pen Chitin Chitooligomers as Food Colorants Absorbers

Tzu‐Wen Liang、Chih-Ting Huang、Anh Dzung Nguyen 等 4 位作者2015-01-20Marine Drugs

One of the most promising applications of chitosanase is the conversion of chitinous biowaste into bioactive chitooligomers (COS). TKU033 chitosanase was induced from squid pen powder (SPP)-containing Bacillus cereus TKU033 medium and purified by ammonium sulfate precipitation and column chromatography. The enzyme was…

Nanocomposite Films for Food PackagingStudies on Chitinases and ChitosanasesPineapple and bromelain studies

K5Mn3O6and Rb8Mn5O10, New Charge OrderedQuasiOne‐Dimensional Oxomanganates (II, III)

Jürgen Nuß、Prasad L. V. K. Dasari、Martin Jansen2015-01-20Zeitschrift für anorganische und allgemeine Chemie

Abstract K 5 Mn 3 O 6 and Rb 8 Mn 5 O 10 have been synthesized via the azide/nitrate route from stoichiometric mixtures of MnO and KNO 3 /KN 3 , or RbNO 3 /RbN 3 , respectively. The two new members of manganese (II/III) mixed‐valent oxides have been studied by single‐crystal X‐ray diffraction, magnetic susceptibility…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsInorganic Chemistry and Materials

Chemical tuning of electrical transport in Ti 1 − x Pt x Se 2 − y

Justin S. Chen、Jiakui K. Wang、Scott Carr 等 7 位作者2015-01-20Physical Review B

The structural and transport properties of polycrystalline ${\mathrm{Ti}}_{1\text{\ensuremath{-}}x}{\mathrm{Pt}}_{x}{\mathrm{Se}}_{2\text{\ensuremath{-}}y}\phantom{\rule{0.28em}{0ex}}(x\ensuremath{\le}0.13,\phantom{\rule{0.28em}{0ex}}y\ensuremath{\le}0.2)$ are studied, revealing highly tunable electrical properties, s…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesMXene and MAX Phase Materials

Phase relations in the Nd2S3-SnS system and properties of the γ-Nd9.5Sn1.8S16 solid solution

R. E. Nikolaev、A. M. Chernovol、Alphiya R. Tsygankova2015-01-20Inorganic Materials

The Nd 2 S 3 -SnS system has been studied at a temperature of 1100°C. The Nd 2 S 3 solubility in molten SnS at this temperature is determined to be 4.4 mol %. The neodymium is present in the SnS melt in the form of Nd 3+ ions. Its diffusion coefficient in molten SnS is estimated at 1.2 × 10 −8 m 2 /s. Nd 2 S 3 dissolu…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Calculation of current density for graphene superlattice in a constant electric field

Farhad Sattari2015-01-20Journal of theoretical and applied physics

Based on the transfer-matrix method, this paper has investigated the electrical transport properties in monolayer and bilayer graphene superlattices modulated by a homogeneous electric field. It is found that the angular range of the transmission probability can be efficiently controlled by the number of barriers. In…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

The bonding characteristics and electronic and magnetic properties of organometallic sandwich clusters and nanowires

Xiaojing Yao、Xiuyun Zhang、Jinlan Wang2015-01-20International Journal of Quantum Chemistry

Metal‐ligand sandwich clusters and molecular wires, which are constituted by metal atoms and organic/inorganic ligands, show potential applications in molecular recognition, catalysis, nanocomposites, optoelectronic, and biological sensors due to their unique structure, electronic, magnetic, and optical properties. Th…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesNanocluster Synthesis and Applications

Dolomite magnesium oxychloride cement properties control method during its production

Т Н Черных、А. В. Носов、L Kramar2015-01-20IOP Conference Series Materials Science and Engineering

The work considers the possibility of reducing the decomposition temperature of MgCO 3 in dolomite rock, provides the results of studies of the effect of various additives and enhancers on the decomposition of magnesium and calcium components of dolomite. Chlorides additives are the most promising for dolomite rocks r…

Magnesium Oxide Properties and ApplicationsIndustrial Engineering and Technologies

Films made from polyethylene‐co‐acrylic acid and soluble biopolymers sourced from agricultural and municipal biowaste

Flavia Franzoso、Damiano Causone、Silvia Tabasso 等 9 位作者2015-01-20Journal of Applied Polymer Science

ABSTRACT Blends were obtained from polyethylene‐ co ‐acrylic acid (PEAA) with 248 kDa molecular weight and two water soluble biopolymers isolated from the hydrolysate of postharvest tomato plant and urban biowaste compost. The two hydrolysates were constituted respectively from a polysaccharide (SP) with 27 kDa molecu…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Relationship between Molecular Association and Re-entrant Phenomena in Polar Calamitic Liquid Crystals

Richard J. Mandle、Stephen J. Cowling、I. Sage 等 5 位作者2015-01-20The Journal of Physical Chemistry B

The relationship between molecular association and re-entrant phase behavior in polar calamitic liquid crystals has been explored in two families of materials: the 4'-alkoxy-4-cyanobiphenyls (6OCB and 8OCB) and the 4'-alkoxy-4-nitrobiphenyls. Although re-entrant nematic phase behavior has previously been observed in t…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation