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High-temperature nuclear magnetic resonance study of phase transition kinetics in LiNaSO4

Roman Shakhovoy、Vincent Sarou‐Kanian、Aydar Rakhmatullin 等 5 位作者2015-12-28Journal of Applied Physics

A new high-temperature NMR technique for measurements of the phase transition kinetics in solids has been developed. The technique allows measuring the time evolution of the volume of the appearing phase at controlled cooling rates. Developed method was applied to study the phase transition kinetics in the superionic…

Advanced Battery Materials and TechnologiesSolid-state spectroscopy and crystallographyMolten salt chemistry and electrochemical processes

Recasting a model atomistic glassformer as a system of icosahedra

Rhiannon Pinney、Tanniemola B. Liverpool、C. Patrick Royall2015-12-28The Journal of Chemical Physics

We consider a binary Lennard-Jones glassformer whose super-Arrhenius dynamics are correlated with the formation of icosahedral structures. Upon cooling, these icosahedra organize into mesoclusters. We recast this glassformer as an effective system of icosahedra which we describe with a population dynamics model. This…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesAdvanced Physical and Chemical Molecular Interactions

Photochemical Regulation of Gene Expression Using Caged siRNAs with Single Terminal Vitamin E Modification

Yuzhuo Ji、Jiali Yang、Li Wu 等 5 位作者2015-12-28Angewandte Chemie

Abstract Caged siRNAs with a single photolabile linker and/or vitamin E (vitE) modification at the 5′ terminal were rationally designed and synthesized. These virtually inactive caged siRNAs were successfully used to photoregulate both firefly luciferase and GFP gene expression in cells with up to an 18.6‐fold enhance…

RNA Interference and Gene DeliveryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Effect of long fiber thermoplastic extrusion process on fiber dispersion and mechanical properties of viscose fiber/polypropylene composites

Nalini Ranganathan、Kristiina Oksman、Sanjay K. Nayak 等 4 位作者2015-12-28Polymers for Advanced Technologies

Viscose fiber reinforced polypropylene (PP/VF) composites were manufactured using long fiber thermoplastic (LFT) extrusion techniques with two different methods namely LFT-l and LFT-2. The compatibilizer [maleated polypropylene (MAPP)] and dispersing agent [stearic acid (SA)] were added to the PP/VF in order to improv…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Synthesis of amphiphilic block-type macromolecular brushes with cleavable pendant chains and fabrication of micelle-templated polymer nanocapsules

Guangda Han、Yuanyuan Ju、Hanying Zhao2015-12-28Polymer Chemistry

Macromolecular brushes with cleavable pendant chains were synthesized by controlled free radical polymerizations and functional nanocapsules were fabricated on the basis of the brush polymers.

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

Liquid crystal free energy relaxation by a theoretically informed Monte Carlo method using a finite element quadrature approach

Julio C. Armas-Pérez、Juan P. Hernández-Ortíz、Juan Pablo2015-12-28The Journal of Chemical Physics

A theoretically informed Monte Carlo method is proposed for Monte Carlo simulation of liquid crystals on the basis of theoretical representations in terms of coarse-grained free energy functionals. The free energy functional is described in the framework of the Landau-de Gennes formalism. A piecewise finite element di…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Dielectric and specific heat relaxations in vapor deposited glycerol

Angeline Kasina、Tristan Putzeys、Michael Wübbenhorst2015-12-28The Journal of Chemical Physics

Recently [S. Capponi, S. Napolitano, and M. Wübbenhorst, Nat. Commun. 3, 1233 (2012)], vapor deposited glasses of glycerol have been found to recover their super-cooled liquid state via a metastable, ordered liquid (MROL) state characterized by a tremendously enhanced dielectric strength along with a slow-down of the…

Material Dynamics and PropertiesIonic liquids properties and applicationsThermodynamic properties of mixtures

Fabrication and potential application of a di-functional magnetic system: magnetic hyperthermia therapy and drug delivery

Binqing Shen、Xuechuan Gao、Shiyong Yu 等 5 位作者2015-12-28CrystEngComm

A novel di-functional system was synthesized by encapsulation of superparamagnetic Fe3O4 and a therapeutic agent 5-fluorouracil (5-Fu) with the thermo-responsive poly(N-isopropylacrylamide) (PNIPAM), which was coated with mesoporous SiO2 nanoparticles in a mesoporous core–shell structure. The system featured functiona…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsCharacterization and Applications of Magnetic Nanoparticles

Electrochemical Behavior of Silver Electrode in Sulphuric Acidic Solution During Anodic Polarization

A Bayesov、E. Zh. Tuleshova、Ainur Tukibayeva 等 5 位作者2015-12-28Oriental Journal Of Chemistry

Oriental Journal of Chemistry is a peer reviewed quarterly research journal of pure and applied chemistry. It publishes standard research papers in almost all thrust areas of current chemistry of academic and commercial importance. It provides a platform for rapid publication of quality research papers, reviews and ch…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnodic Oxide Films and Nanostructures

Structure and Thermoelectric Properties of Te-Ag-Ge-Sb (TAGS) Materials Obtained by Reduction of Melted Oxide Substrates

B. Kusz、Tadeusz Miruszewski、Beata Bochentyn 等 5 位作者2015-12-28Journal of Electronic Materials

Ge 0.77 Ag 0.1 Sb 0.13 Te 1 alloy was fabricated by a novel two-step route. Firstly, oxide reagents were melted at high temperature and quenched into pellets. The pellets were milled to powder and then reduced in hydrogen at various temperatures for various periods of time. Energy-dispersive x-ray analysis indicated t…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Green corrosion inhibitors for carbon steel by green leafy vegetables extracts in 1 M HCl

Ghadah M. Al‐Senani、Sameerah I. Al‐Saeedi、Rasmiah S. Almufarij2015-12-28Oriental Journal Of Chemistry

Oriental Journal of Chemistry is a peer reviewed quarterly research journal of pure and applied chemistry. It publishes standard research papers in almost all thrust areas of current chemistry of academic and commercial importance. It provides a platform for rapid publication of quality research papers, reviews and ch…

Corrosion Behavior and Inhibition

Sub-barrier radioactive ion beam investigations using a new methodology and analysis for the stacked target technique

M. Fisichella、A.C. Shotter、A. Di Pietro 等 10 位作者2015-12-28Physical Review C

For low energy reaction studies involving radioactive ion beams, the experimental reaction yields are generally small due to the low intensity of the beams. For this reason, the stacked target technique has been often used to measure excitation functions. This technique offers considerable advantages since the reactio…

Nuclear physics research studiesFusion materials and technologiesNuclear Materials and Properties

Effect of Oscillatory Flow on Nucleation Kinetics of Butyl Paraben

Huaiyu Yang、Xi Yu、Vishal Raval 等 5 位作者2015-12-28Crystal Growth & Design

More than 165 induction times of butyl paraben–ethanol solution in a batch moving fluid oscillation baffled crystallizer with various amplitudes (1–9 mm) and frequencies (1.0–9.0 Hz) have been determined to study the effect of COBR operating conditions on nucleation. The induction time decreases with increasing amplit…

Crystallization and Solubility Studiesnanoparticles nucleation surface interactionsFreezing and Crystallization Processes

Low temperature magnetic properties and spin dynamics in single crystals of Cr8Zn antiferromagnetic molecular rings

Fatemeh Adelnia、Alessandro Chiesa、S. Bordignon 等 14 位作者2015-12-28The Journal of Chemical Physics

A detailed experimental investigation of the effects giving rise to the magnetic energy level structure in the vicinity of the level crossing (LC) at low temperature is reported for the open antiferromagnetic molecular ring Cr8Zn. The study is conducted by means of thermodynamic techniques (torque magnetometry, magnet…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchInorganic Chemistry and Materials

Dissociation of O 2 and its reactivity on O/S doped graphene

Meiling Hou、Wanglai Cen、Nan Fang 等 6 位作者2015-12-28RSC Advances

O/S doping promotes the dissociation of O <sub>2</sub> , which forming epoxy and/or carbonyl groups on the doped-GP surfaces. The catalytic loop for the oxidation of SO <sub>2</sub> is terminated because of high oxidation barrier due to the formation of the carbonyl group.

Electrocatalysts for Energy ConversionGraphene research and applicationsCatalytic Processes in Materials Science

Light absorption and plasmon – exciton interaction in three-layer nanorods with a gold core and outer shell composed of molecular J- and H-aggregates of dyes

B. I. Shapiro、E S Tyshkunova、A. D. Kondorskiy 等 4 位作者2015-12-28Quantum Electronics

Light absorption and plasmon – exciton interaction in three-layer nanorods with a gold core and outer shell composed of molecular J- and H-aggregates of dyes, Shapiro, B.I., Tyshkunova, E.S., Kondorskiy, A.D., Lebedev, V.S.

Gold and Silver Nanoparticles Synthesis and ApplicationsLuminescence and Fluorescent MaterialsNonlinear Optical Materials Studies

Additive effects of electronic and nuclear energy losses in irradiation-induced amorphization of zircon

Eva Zarkadoula、M. Toulemonde、William J. Weber2015-12-28Applied Physics Letters

We used a combination of ion cascades and the unified thermal spike model to study the electronic effects from 800 keV Kr and Xe ion irradiation in zircon. We compared the damage production for four cases: (a) due to ion cascades alone, (b) due to ion cascades with the electronic energy loss activated as a friction te…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsNuclear materials and radiation effects

Probing single molecules and molecular aggregates: Raman spectroscopic advances

Jing Chen、Weihua Ding、Zhixun Luo 等 5 位作者2015-12-28Journal of Raman Spectroscopy

Development of Raman spectroscopy, profiting from surface‐enhanced Raman scattering and tip‐enhanced Raman scattering techniques, has inspired extensive research interest for trace analysis and dynamic measurements up to single‐molecule level. For another, Raman spectroscopy has also been recognized of significance in…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchProtein Interaction Studies and Fluorescence Analysis

Poly(2-cycloalkyl-2-oxazoline)s: high melting temperature polymers solely based on Debye and Keesom van der Waals interactions

Valentin Victor Jerca、Kathleen Lava、Bart Verbraeken 等 4 位作者2015-12-28Polymer Chemistry

The synthesis of new 2-cycloalkyl-2-oxazoline monomers, namely 2-cyclobutyl (cBuOx), 2-cyclopentyl (cPentOx) and 2-cyclohexyl-2-oxazoline (cHexOx) is described. Polymers thereof are semi-crystalline and reveal unexpectedly high melting transitions.

Synthetic Organic Chemistry MethodsCarbon dioxide utilization in catalysisSynthesis and properties of polymers

Preparation, characterization and biocompatible properties of β-chitin/silk fibroin/nanohydroxyapatite composite scaffolds prepared using a freeze-drying method

Mohammad Azadi、Abbas Teimouri、Ghasem Mehranzadeh2015-12-28RSC Advances

β-Chitin/silk fibroin/nanohydroxyapatite (CT/SF/nHAp) composite scaffolds were synthesized using a freeze-drying method by blending β-chitin hydrogel, silk fibroin and nHAp at different inorganic/organic weight ratios.

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesSilk-based biomaterials and applications