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Platinum( ii ) cyclometallates featuring broad emission bands and their applications in color-tunable OLEDs and high color-rendering WOLEDs

Guiping Tan、Shuming Chen、Chi‐Ho Siu 等 11 位作者2016-01-01Journal of Materials Chemistry C

Two new phosphorescent platinum( ii ) cyclometallates with flexible phenoxy moieties were prepared whose broad excimeric emissive states in the solid state allow the fabrication of high color-rendering two-emitter WOLEDs.

Organic Light-Emitting Diodes ResearchLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Zinc oxide quantum dots: multifunctional candidates for arresting C2C12 cancer cells and their role towards caspase 3 and 7 genes

Rizwan Wahab、Farheen Khan、You Bing Yang 等 14 位作者2016-01-01RSC Advances

Recently, nanoscale (<100 nm) inorganic materials, especially spherical shaped zinc oxide (ZnO-QDs), have received a lot of attention from the broad community because of their potential utilization in various technologies.

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesPeptidase Inhibition and Analysis

Intrinsic magnetic characteristics-dependent charge transfer and visible photo-catalytic H 2 evolution reaction (HER) properties of a Fe 3 O 4 @PPy@Pt catalyst

Wenyan Zhang、Chao Kong、Wei Gao 等 4 位作者2016-01-01Chemical Communications

A ternary nano-architectural photocatalyst has been designed to investigate whether the intrinsic magnetic property of photo-catalysts has an effect on the charge transfer and its photo-catalytic H2 evolution reaction (HER) properties under visible light irradiation. The electron transfer and visible-light-driven hydr…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Electron Energy Studying of Molecular Structures via Forgotten Topological Index Computation

Wei Gao、Weifan Wang、Muhammad Kamran Jamil 等 4 位作者2016-01-01Journal of Chemistry

It is found from the earlier studies that the structure-dependency of total π -electron energy Eπ heavily relies on the sum of squares of the vertex degrees of the molecular graph. Hence, it provides a measure of the branching of the carbon-atom skeleton. In recent years, the sum of squares of the vertex degrees of th…

Graphene research and applicationsComputational Drug Discovery MethodsGraph theory and applications

Single-molecule devices with graphene electrodes

Stefano Lumetti、Andrea Candini、Clément Godfrin 等 8 位作者2016-01-01Dalton Transactions

magnetic core and the current passing through the molecular system in the Coulomb blockade regime, thus showing that the use of graphene is a promising way forward in addressing single molecules.

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Microsponges: A Pioneering Tool for Biomedical Applications

Amrita Kumari、Ankit Jain、Pooja Hurkat 等 5 位作者2016-01-01Critical Reviews in Therapeutic Drug Carrier Systems

Microparticulate drug delivery systems have been explored across the globe due to their various advantages. In 1987, Won developed microsponge systems (Micsys), also known as solid-phase porous microspheres, having numerous interconnected voids, which serve as non-collapsible residence for bioactive compounds. A Micsy…

Nanoparticle-Based Drug DeliveryAdvancements in Transdermal Drug DeliveryAdvanced Drug Delivery Systems

Extending the environmental lifetime of unpackaged perovskite solar cells through interfacial design

Haiwei Chen、Yi Hou、Christian E. Halbig 等 15 位作者2016-01-01Journal of Materials Chemistry A

Solution-processed oxo-functionalized graphene is used to substitute hydrophilic PEDOT:PSS as an anode interfacial layer for perovskite solar cells. The resulting devices exhibit a reasonable PCE of 15.2% and improved stability.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesConducting polymers and applications

An Improved Empirical Fuel Cell Polarization Curve Model Based on Review Analysis

Dong Hao、Jianping Shen、Yongping Hou 等 5 位作者2016-01-01International Journal of Chemical Engineering

Based on a review analysis of empirical fuel cell polarization curve models in the literature, an improved model that can predict fuel cell performance with only measured current-voltage data is developed. The fitting characteristics of this new model are validated by fitting bench test data and road test data. In the…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Screening procedure for structurally and electronically matched contact layers for high-performance solar cells: hybrid perovskites

Keith T. Butler、Yu Kumagai、Fumiyasu Oba 等 4 位作者2016-01-01Journal of Materials Chemistry C

A screening procedure for identifying eletronically and structurally matched interfaces based on bulk properties is developed and applied to perovskite solar cells.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

A Cd( ii )-based metal–organic framework as a luminance sensor to nitrobenzene and Tb( iii ) ion

Xiang-Long Qu、Di Gui、Xiaoli Zheng 等 7 位作者2016-01-01Dalton Transactions

A Cd(II)-based metal-organic framework, [Cd2(DPDC)2(BTB)]∞ (Cd-MOF, DPDC = 2,2'-diphenyldicarboxylate and BTB = 1,4-bis(1,2,4-triazol-1-yl)butane) was successfully constructed via a hydrothermal reaction. Structural analysis shows that the synthesized Cd-MOF is a three-dimensional (3D) architecture crystallized in the…

Metal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Salicylaldehyde-functionalized block copolymer nano-objects: one-pot synthesis via polymerization-induced self-assembly and their simultaneous cross-linking and fluorescence modification

Jianbing Huang、Hanjun Zhu、Hui Liang 等 4 位作者2016-01-01Polymer Chemistry

Salicylaldehyde-functionalized nano-objects are prepared via RAFT-mediated polymerization-induced self-assembly. Their simultaneous stabilization and fluorescence modification can be achieved by one-step reaction.

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Passivation of surface states by ALD-grown TiO 2 overlayers on Ta 3 N 5 anodes for photoelectrochemical water oxidation

Peng Zhang、Tuo Wang、Jinlong Gong2016-01-01Chemical Communications

This paper describes the fabrication of TiO2 overlayers by atomic layer deposition to passivate the surface states on Ta3N5 thin film anodes for photoelectrochemical water oxidation. The removal of surface states reduces the overpotential and decreases the density of surface recombination centers, resulting in enhance…

Advanced Photocatalysis TechniquesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

High-field dissolution dynamic nuclear polarization of [1- 13 C]pyruvic acid

Hikari A. I. Yoshihara、Emine Can、Magnus Karlsson 等 6 位作者2016-01-01Physical Chemistry Chemical Physics

[1-(13)C]pyruvate is the most widely used hyperpolarized metabolic magnetic resonance imaging agent. Using a custom-built 7.0 T polarizer operating at 1.0 K and trityl radical-doped [1-(13)C]pyruvic acid, unextrapolated solution-state (13)C polarization greater than 60% was measured after dissolution and rapid transfe…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyNMR spectroscopy and applications

A layered 2D triaminoguanidine–glyoxal polymer and its transition metal complexes as novel insensitive energetic nanomaterials

Qi‐Long Yan、Adva Cohen、Ajay Kumar Chinnam 等 7 位作者2016-01-01Journal of Materials Chemistry A

A new member of the 2D carbon–nitrogen-rich family of nanomaterials was synthesized by polycondensation of triaminoguanidine hydrochloride with glyoxal. This new polymer (TAGP) and its transition metal complexes (TAGP–Ms) were found to be energetic and insensitive.

Graphene research and applicationsEnergetic Materials and CombustionThermal and Kinetic Analysis

Novel donor–acceptor polymers containing o-fluoro-p-alkoxyphenyl-substituted benzo[1,2-b:4,5-b′]dithiophene units for polymer solar cells with power conversion efficiency exceeding 9%

Ning Wang、Weichao Chen、Wenfei Shen 等 9 位作者2016-01-01Journal of Materials Chemistry A

A PCE of 9.02% for a two-dimensional polymer as donor applied in solar cells was obtained without any additive treatment.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications