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Electron transport at interface of LaAlO3 and SrTiO3 band insulators

Shanshan Su、Jeong Ho You、Chibum Lee2013-03-06Journal of Applied Physics

Electron transport properties at n-type LaAlO3/SrTiO3 interfaces have been investigated numerically. Carrier distributions, band structures, and sheet density have been calculated by solving Schrödinger equations with Poisson equation in a self-consistent manner for various LaAlO3/SrTiO3 interfaces with and without at…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Isocitrate Dehydrogenase from Streptococcus mutans: Biochemical Properties and Evaluation of a Putative Phosphorylation Site at Ser102

Peng Wang、Ping Song、Mingming Jin 等 4 位作者2013-03-06PLoS ONE

Isocitrate deyhdrogenase (IDH) is a reversible enzyme in the tricarboxylic acid cycle that catalyzes the NAD(P)(+)-dependent oxidative decarboxylation of isocitrate to α-ketoglutarate (αKG) and the NAD(P)H/CO2-dependent reductive carboxylation of αKG to isocitrate. The IDH gene from Streptococcus mutans was fused with…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionBiochemical and Molecular Research

Elastic, double-layered poly (l-lactide-co-ϵ-caprolactone) scaffold for long-term vascular reconstruction

Cho Hae Mun、Sang Hoon Kim、Youngmee Jung 等 7 位作者2013-03-06Journal of Bioactive and Compatible Polymers

Synthetic vessel grafts have been used as vascular substitutes for cardiovascular bypass procedures. In this study, we developed a novel tubular double-layered poly(l-lactide-co-ϵ-caprolactone) scaffold that did not require pretreatment with cell seeding by promoting autologous tissue regeneration by inducing the prol…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Power Transformer Diagnostics Based on Acoustic Emission Method

Wojciech Sikorski、K. Walczak2013-03-06InTech eBooks

Widely applied techniques for the fault location based on AE method are: (i) measurement of the time difference of arrival (TDOA) of the acoustic signals, (ii) measurement of the acoustic signal amplitude in different areas of a transformer tank (standard auscultatory technique, SAT), (iii) advanced auscultatory techn…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationGeophysical Methods and Applications

Methanol synthesis on ZnO from molecular dynamics

Johannes Frenzel、János Kiss、Nisanth N. Nair 等 5 位作者2013-03-06physica status solidi (b)

Abstract This paper reviews our efforts to simulate methanol synthesis from CO and H 2 on defective ZnO surfaces using advanced molecular dynamics techniques. This apparently simple chemical reaction occurring on a seemingly well‐defined surface appears to be astonishingly complex. First of all, the preferred oxidatio…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Luminescence properties of defects in nanocrystalline ZnO

Jeremy G. Smith、Arash Akbari-Sharbaf、Matthew J. Ward 等 6 位作者2013-03-06Journal of Applied Physics

Formation of intrinsic acceptor defects in ZnO is rare due to the low formation energy of donors. Understanding this phenomenon is of interest for the fabrication of high quality light emitting diodes. Herein, we examine the temperature dependent formation of defects in nanocrystalline ZnO through a combination of X-r…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

ABSORPTION EFFICIENCIES OF FORSTERITE. I. DISCRETE DIPOLE APPROXIMATION EXPLORATIONS IN GRAIN SHAPE AND SIZE

Sean S. Lindsay、Diane H. Wooden、David E. Harker 等 6 位作者2013-03-06The Astrophysical Journal

We compute the absorption efficiency ( Q abs ) of forsterite using the discrete dipole approximation in order to identify and describe what characteristics of crystal grain shape and size are important to the shape, peak location, and relative strength of spectral features in the 8–40 μm wavelength range. Using the DD…

Microstructure and Mechanical Properties of SteelsCalcium Carbonate Crystallization and InhibitionX-ray Diffraction in Crystallography

Metal Oxide Nanomaterials, Conducting Polymers and Their Nanocomposites for Solar Energy

Sadia Ameen、M. Shaheer、Minwu Song 等 4 位作者2013-03-06InTech eBooks

The increasing concern on energy and the global warming due to the depletion of fossil fuel demands to search the alternative renewable energy resources for covering the energy crisis in the coming decade. A very popular renewable source called photovoltaic device is antici‐ pated to solve energy problem, which conver…

TiO2 Photocatalysis and Solar CellsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

An Atomic Scale View of Methanol Reactivity at the Cu(1 1 1)/CuOx Interface

Timothy J. Lawton、Georgios Kyriakou、Ashleigh E. Baber 等 4 位作者2013-03-06ChemCatChem

Abstract The interaction and reaction of MeOH with Cu is of foremost importance in a range of heterogeneously catalyzed processes. A critical intermediate in the molecular transformation of MeOH on Cu‐based catalysts is the methoxy species, the formation of which comprises the first elementary step in the MeOH steam r…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Properties of manganite/ruthenate superlattices with ultrathin layers

M. Ziese、I. Vrejoiu2013-03-06physica status solidi (RRL) - Rapid Research Letters

Abstract The properties of manganite/ruthenate superlattices are reviewed with a specific focus on the manganite/ruthenate interface. La 0.7 Sr 0.3 MnO 3 /SrRuO 3 and Pr 0.7 Ca 0.3 MnO 3 /SrRuO 3 superlattices grow with a high crystalline perfection as illustrated in the figure to the right: at the interface the indiv…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Effect of crystallographic alignment on the magnetocaloric effect in alloys near the Ni2MnGa stoichiometry

Anit K. Giri、Brigitte A. Paterson、Michael V. McLeod 等 7 位作者2013-03-06Journal of Applied Physics

Prior to the development of commercial applications of magnetic refrigerator technology, a large magnetocaloric effect (MCE) in polycrystalline materials must be realized for relatively low magnetic field changes. To increase the MCE, a crystallographic alignment technique, consisting of thermal cycling about the mart…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsHeusler alloys: electronic and magnetic properties

Metabolic effect of short term administration of Hoodia gordonii, an herbal appetite suppressant

Swati Jain、Som Nath Singh2013-03-06South African Journal of Botany

Hoodia gordonii (family: Apocynaceae) is used traditionally by the Khoi-San tribes to control hunger. It has become extremely popular and has triggered commercial interest due to its appetite suppressant property. The present study was undertaken to investigate the appetite regulatory mechanism and associated metaboli…

Phytochemistry and Bioactive CompoundsPhytochemistry and biological activities of Ficus speciesMorinda citrifolia extract uses

SERS investigation on the adsorption and photoreaction of 4‐nitroanisole in Ag hydrosols

Maurizio Muniz‐Miranda2013-03-06Journal of Raman Spectroscopy

The adsorption of 4‐nitroanisole on silver colloidal nanoparticles was investigated by surface‐enhanced Raman spectroscopy (SERS). Actually, the chemical binding with a metal substrate may play a role in changing the electronic structure of this molecule, which can be considered a push–pull chromophore, because an int…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Colloidal deposition as method to study the influence of the support on the activity of gold catalysts in CO‐oxidation

Ferdi Schüth2013-03-06physica status solidi (b)

Abstract The strong influence of the support properties on the activity of gold catalysts has been observed in many publications. The most studied reaction in this respect seems to be CO‐oxidation, for which gold catalysts have outstanding activity. However, since in most studies the support properties are also import…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Cationic Twin Polymerization Versus Simultaneous Polymerization of Titanium Compounds to Fabricate Nanostructured Organic Polymer/TiO2 Hybrid Materials

Alexander Mehner、Andreas Pohlers、W. Hoyer 等 5 位作者2013-03-06Macromolecular Chemistry and Physics

Abstract The formation of related polymer/TiO 2 nanocomposites is studied using two alternative synthetic procedures. The triflic acid anhydride‐catalyzed twin‐polymerization (TP) of (μ 4 ‐oxido)‐hexakis(μ‐furan‐2‐methoxo)‐octakis(furan‐2‐methoxo)‐tetratitanium ( 1) and (μ 4 ‐oxido)‐hexakis(μ‐thiophene‐2‐methoxo)‐octa…

Polymer Nanocomposites and PropertiesPolyoxometalates: Synthesis and ApplicationsSilicone and Siloxane Chemistry

Optimization of silane sol–gel coatings for the protection of aluminium components of heat exchangers

Reza Naderi、Michele Fedel、T. Urios 等 6 位作者2013-03-06Surface and Interface Analysis

Despite the relatively low mechanical properties respect to the aluminium alloys but due to high thermal exchange capacity, pure aluminium (AA1XXX series) is widespread for industrial applications for heat exchanger components or cooling systems (like refrigerator systems). The corrosion protection properties of alumi…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Synthesis and Electrochemical and Computational Analysis of Two New Families of Thiophene-Carbonyl Molecules

Weidong Zhou、Kenneth Hernández‐Burgos、Stephen E. Burkhardt 等 5 位作者2013-03-06The Journal of Physical Chemistry C

Two oligomeric families of materials containing thiophene-carbonyl and thiophene-dicarbonyl units have been synthesized and characterized with emphasis on structural, electrochemical, and electronic properties. Three thiophene-carbonyl derivatives containing 1, 2, and 3 carbonyl groups exhibited one, two, and three on…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic and Molecular Conductors Research

Low-Field Superconducting Phase of(TMTSF)2ClO4

F. L. Pratt、Tom Lancaster、Stephen J. Blundell 等 4 位作者2013-03-06Physical Review Letters

The low-field phase of the organic superconductor (TMTSF)(2)ClO(4) is studied by muon-spin rotation. The zero temperature limit of the magnetic penetration depth within the TMTSF layers is obtained to be λ(ab)(0) = 0.86(2) μm. Temperature dependence of the muon-spin relaxation shows no indication of gap nodes on the F…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Lyophilic Nonwettable Surface Based on an Oil/Water/Air/Solid Four‐Phase System

Jun Gao、Xi Yao、Yong Zhao 等 4 位作者2013-03-06Small

Lyophilic but not sticky! A lyophilic yet nonwettable surface seems self-contradictory, however, a nanostructured super-lyorepellent surface is used to reveal that a lyophilic nonwettable state is theoretically feasible in an oil/water/air/solid four-phase system. This finding may throw light on multiphase interface b…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Selective Reduction of PHA Biopolyesters and Their Synthetic Analogues to Corresponding PHA Oligodiols Proved by Structural Studies

Michał Kwiecień、Grażyna Adamus、Marek Kowalczuk2013-03-06Biomacromolecules

A highly selective method is described for controlling the degradation of polyhydroxyalkanoates, PHA, via a reduction reaction that uses lithium borohydride. Using this method, oligo(hydroxyalkanoate)diols derived from a poly(3-hydroxybutyrate-co-4-hydroxybutyrate) biopolyester [poly(3HB-co-4HB)] and from synthetic at…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis